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Method of treating traditional Chinese medicine wastewater by utilizing modified fly ashes and photocatalyst

A technology of photocatalyst and fly ash, which is applied in chemical instruments and methods, energy wastewater treatment, water/sewage multi-stage treatment, etc., can solve the problems of long time consumption, large floor area, unfavorable bacterial group survival, etc., and achieve convenience Storage and transportation, realizing recycling and shortening the treatment cycle

Inactive Publication Date: 2014-03-05
INNER MONGOLIA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the above application is used for the treatment of traditional Chinese medicine wastewater, although this process can separate and dispose of pollutants and convert and decompose harmful substances, this process requires long-term exposure to the air for microbial decomposition, which occupies a large area and takes a long time , the efficiency of wastewater treatment is low, and a large amount of organic matter is exposed to the air for a long time, and even produces secondary pollution to the surrounding environment
Usually, in the processing of traditional Chinese medicine, the organic acid enters the wastewater, which will make the wastewater present an acidic buffer system, which is not conducive to the survival of the bacteria in the biodegradation, and even leads to the death of a large number of microorganisms, resulting in an unsatisfactory wastewater treatment effect.

Method used

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  • Method of treating traditional Chinese medicine wastewater by utilizing modified fly ashes and photocatalyst

Examples

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Effect test

Embodiment 1

[0020]The mixed production wastewater of a traditional Chinese medicine pharmaceutical factory in Inner Mongolia is used. During the production of traditional Chinese medicine in this pharmaceutical factory, the mixed production wastewater is mainly composed of traditional Chinese medicine production wastewater, bottle washing, rubber stopper washing wastewater, resin regeneration wastewater, machine repair wastewater, domestic wastewater, quality inspection wastewater, It consists of seven types of wastewater, including the raffinate recovered by ethanol distillation. Wastewater is yellowish brown, COD Cr (Chemical oxygen demand measured by potassium dichromate method) average value is 14200mg / L, SS (represents suspended solid particles) average value is 3620mg / L, average pH value is 4.5, and the absorbance of wastewater at 340nm is 0.523. The main chemical composition of the fly ash used is SiO 2 、Al 2 o 3 , Fe 2 o 3 , CaO, MgO, NaO, and unburned carbon, etc., where the...

Embodiment 2

[0027] The waste water produced in the processing of traditional Chinese medicine in a hospital of traditional Chinese medicine in Inner Mongolia is mainly used for washing and irrigation. Wastewater is yellowish brown, COD Cr (Chemical oxygen demand measured by potassium dichromate method) average value is 6800mg / L, SS (represents suspended solid particles) average value is 3250mg / L, average pH value is 5.1, and the absorbance of wastewater at 340nm is 0.535. The powder used The main chemical composition of coal ash is SiO 2 、Al 2 o 3 , Fe 2 o 3 , CaO, MgO, NaO, and unburned carbon, etc., where the mass fractions of active ingredients are SiO 2 40%, Al 2 o 3 17%, and Fe 2 o 3 15%.

[0028] Using the method of the present invention, the traditional Chinese medicine wastewater is sequentially subjected to stock solution pretreatment, photocatalytic degradation, and flocculation and sedimentation treatment. The detailed process is as follows:

[0029] (1) Stock soluti...

Embodiment 3

[0034] The waste water produced in the processing of traditional Chinese medicine in a pharmacy in Baotou, Inner Mongolia is used, including washing liquid and washing water. Wastewater is yellowish brown, COD Cr (Chemical oxygen demand measured by potassium dichromate method) average value is 2289mg / L, SS (represents suspended solid particles) average value is 528mg / L, average pH value is 5, and the absorbance of wastewater at 340nm is 0.559. The powder used The main chemical composition of coal ash is SiO 2 、Al 2 o 3 , Fe 2 o 3 , CaO, MgO, NaO, and unburned carbon, etc., where the mass fractions of active ingredients are SiO 2 55%, Al 2 o 3 30%, and Fe 2 o 3 6%.

[0035] Using the method of the present invention, the traditional Chinese medicine wastewater is sequentially subjected to stock solution pretreatment, photocatalytic degradation, and flocculation and sedimentation treatment. The detailed process is as follows:

[0036] (1) Stock solution pretreatment: T...

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Abstract

The invention relates to a method of treating traditional Chinese medicine wastewater by utilizing modified fly ashes and a photocatalyst. The method specifically comprises the following steps of: modifying fly ashes by utilizing an activator, roasting, and the like, wherein each modified fly ash is used for carrying out original fluid pre-treatment onto the traditional Chinese medicine wastewater in sequence; carrying out photocatalytic degradation onto the pre-treated traditional Chinese medicine wastewater under radiation of sunlight, wherein the used photocatalyst is obtained by loading TiO2 / Cu2O with the fly ashes; finally, carrying out flocculating settling onto the catalyzed water by a flocculating agent prepared by fly ashes. Fly ashes, waste scrap iron, industrial waste acid, and the like, are used as main materials, so that treatment cost of the traditional Chinese medicine wastewater can be effectively lowered, and secondary pollution can also be avoided; during treatment, the composite photocatalyst with efficient catalytic degradation ability in the sun is used, so that decomposition time of organic pollutants is effectively shortened, and the photocatalyst can be recycled for repeated catalysis by loading the photocatalyst with the fly ashes; wastewater treatment scale can be large and small, and ferric aluminum polysilicate can be prepared on the scene according to actually generated wastewater amount and characteristics of the wastewater.

Description

technical field [0001] The invention relates to a pharmaceutical wastewater treatment process, in particular to a method for treating traditional Chinese medicine wastewater by using modified fly ash and a photocatalyst. Background technique [0002] Traditional Chinese medicine wastewater mainly comes from production workshops, major Chinese medicine hospitals and traditional Chinese medicine dispensaries, and is produced in the process of washing and cooking medicinal materials, washing, preparations, etc. Traditional Chinese medicine wastewater includes raw drug washing water in the production process, raw drug juice residue, sewage generated in unit operations such as filtration, distillation, and extraction, production equipment washing, floor flushing water, steam condensate water, and ion exchange resin acid-base solution neutralized water, etc. [0003] Pollutants in traditional Chinese medicine wastewater can be roughly divided into two categories: one is water-sol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08C02F1/52
CPCY02W10/37
Inventor 袁春华杨德桥王超安胜利
Owner INNER MONGOLIA UNIV OF SCI & TECH
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