Preparation method of humidity sensitive grating and fiber grating temperature and humidity sensor
A grating and humidity-sensitive technology, applied in the field of intelligent detection, can solve the problems that the process is affected by the environment, the performance distribution of finished products is stray, and the fiber grating cannot be used to detect relative humidity, etc.
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Embodiment 1
[0034] The invention provides a method for preparing a moisture-sensitive grating, comprising the following steps:
[0035] a, put the plant fiber into [AMIM] cl (1-allyl-3-methylimidazolium chloride) solution for hydrolysis, filter out the impurities in the solution to obtain a clean solution;
[0036] b. Desugaring the cleaning solution with a certain amount of enone, adding the product after desugaring to acetic acid solution to esterify the hydroxyl functional groups of cellulose to form acetyl functional groups;
[0037] c. Put the grating into a solution made of 3-ATPS (trisilane coupling agent), ethanol and water. The hydroxyl groups on the surface of the grating bond with 3-ATPS to form silane-containing amine groups that are easy to bond with acetyl groups ;
[0038] d, washing and drying the grating with silane-containing amine groups, soaking it in the solution of acetyl-containing cellulose in step b, to form a moisture-sensitive grating grafted with cellulose;
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Embodiment 2
[0041] f, selecting discarded short cotton fibers as fiber raw materials, washing the short cotton fibers, drying them in the air, removing silt and large particles of cotton impurities, then combing and beating at the same time to obtain relatively clean plant fibers;
[0042] a, put the obtained relatively clean plant fibers into [BMIM]cl (1-butyl-3-methylimidazole oxide) solution for hydrolysis, and obtain a clean solution after filtering out impurities in the solution;
[0043] b. Desugaring the cleaning solution with a certain amount of enone, adding the product after desugaring to acetic anhydride solution to esterify the hydroxyl functional groups of cellulose to form acetyl functional groups;
[0044] c. Put the grating into a solution made of 3-ATPS (trisilane coupling agent), ethanol and water. The hydroxyl groups on the surface of the grating bond with 3-ATPS to form silane-containing amine groups that are easy to bond with acetyl groups ;
[0045] d, washing and d...
Embodiment 3
[0048] f, selecting discarded short cotton fibers as fiber raw materials, washing the short cotton fibers, drying them in the air, removing silt and large particles of cotton impurities, then combing and beating at the same time to obtain relatively clean plant fibers;
[0049]a, putting the obtained relatively clean plant fibers into [AMIM]cl (1-allyl-3-methylimidazolium chloride salt) solution for hydrolysis, and obtaining a cleaning solution after filtering out impurities in the solution;
[0050] b. Desugaring the cleaning solution with a certain amount of enone, adding the product after desugaring to nitric acid solution to esterify the hydroxyl functional groups of cellulose to form acetyl functional groups;
[0051] c. Put the grating into a solution made of KH570, ethanol and water, and the hydroxyl groups on the surface of the grating bond with KH570 to form silane-containing amine groups that are easy to bond with acetyl groups;
[0052] d, washing and drying the gra...
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