Preparation method of polypeptide soybean protein complex fiber

A technology of soybean protein and composite fiber, applied in the direction of chemical characteristics of fiber, cellulose/protein conjugated rayon, rayon manufacturing, etc., can solve the problem of lack of low molecular protein activity, penetration, specificity and regulation , low biological activity of high molecular weight proteins, functional effects of finished fibers, etc., to achieve the effects of improving binding stability, simplifying production steps, and low production costs

Active Publication Date: 2015-04-08
湖州珠力纳米材料科技开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Based on the currently disclosed protein fiber production technologies at home and abroad, the protein is basically dissolved, and then added to the traditional fiber production process for wet spinning. On the one hand, the dissolution of the protein will inevitably affect the inherent space of the protein. The structure of the cavity will affect the functionality of the finished fiber. On the other hand, the solidification process of the protein will introduce toxic and harmful substances such as formaldehyde or chromium salts, which will inevitably cause environmental pollution.
Furthermore, in the prior art, proteins with higher molecular weight are used. High molecular weight proteins have low biological activity and do not possess the unique activity, penetrating power, specificity and various physiological functions of regulating the human body. function of

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1 prepares 1.67dtex * 38mm polypeptide soybean protein composite fiber

[0027] Soak the soybean protein in a sodium hydroxide solution with a concentration of 20wt%, stir at a high speed to obtain a soybean protein solution, filter the soybean protein solution to remove impurities, and then add 2.5wt% of a dispersant in the soybean protein solution, The pH value of the soybean protein solution is adjusted to 6.5, and then an ultrafiltration membrane with an average molecular weight of 8000-10000 is used for ultrafiltration dialysis to obtain a polypeptide soybean protein mother liquor with an average molecular weight of 1800.

[0028] Soaking polyvinyl alcohol in water, dissolving, and filtering to obtain a polyvinyl alcohol solution, adding the polypeptide soybean protein mother liquor to the polyvinyl alcohol solution according to the ratio of the protein content in the polyvinyl alcohol to 20 wt%, and then Adding acrylic acid as a crosslinking agent accou...

Embodiment 2

[0031] Example 2 Preparation of 1.67dtex × 38mm Polypeptide Soybean Protein Composite Fiber

[0032]Soak the soybean protein in the dilute alkali solution and react for 4 hours at a temperature of 80°C. The bath ratio of the soybean protein to the dilute alkali solution is 20:60. After stirring at a speed of 100 rpm for 0.5 to 1 hour The soybean protein solution is obtained. After filtering the soybean protein solution to remove impurities, add a dispersant with a concentration of 1.5wt% in the soybean protein solution, adjust the pH value of the soybean protein solution to 7.0, and then use an ultra- The filter membrane is subjected to ultrafiltration and dialysis to obtain a polypeptide soybean protein mother liquor with an average protein molecular weight of 2000.

[0033] Soaking polyvinyl alcohol in water, dissolving, and filtering to obtain a polyvinyl alcohol solution, adding the polypeptide soybean protein mother liquor to the polyvinyl alcohol solution according to t...

Embodiment 3

[0036] Example 3 Preparation of 1.33dtex × 38mm Polypeptide Soybean Protein Composite Fiber

[0037] Soak the soybean protein in the dilute alkali solution and react for 3 hours at a temperature of 100°C. The bath ratio of the soybean protein to the dilute alkali solution is 30:70. After stirring at a speed of 150 rpm for 0.5 hours, the obtained The soy protein solution described above. After filtering the soybean protein solution to remove impurities, add a dispersant with a concentration of 5wt% in the soybean protein solution, adjust the pH value of the soybean protein solution to 6.8, and then use an ultrafiltration filter with an average molecular weight of 8000 The membrane is subjected to ultrafiltration and dialysis to obtain a polypeptide soybean protein mother liquor with an average protein molecular weight of 500.

[0038] The polyvinyl alcohol is soaked, dissolved, and filtered to obtain a polyvinyl alcohol solution, and the polypeptide soybean protein mother liqu...

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PUM

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Abstract

The invention discloses a preparation method of a polypeptide soybean protein complex fiber, which comprises the following steps that (1), soybean protein is soaked in a diluted alkali solution, and stirred at a high speed, then a soybean protein solution is obtained, and subjected to ultrafiltration dialysis by an ultrafiltration membrane, and a polypeptide soybean protein mother solution with protein molecular weight of 300-2000 is prepared; (2), the polypeptide soybean protein mother solution is added to a polyvinyl alcohol solution, a cross-linking agent accounting for 1.0-2.0wt% of polyvinyl alcohol is then added, and mixed uniformly by high-speed stirring, and a polypeptide soybean protein and polyvinyl alcohol blended solution is prepared; and (3), the polypeptide soybean protein and polyvinyl alcohol blended solution is filtered, defoamed, and then subjected to spinning forming, strand drafting and aftertreatment to form the polypeptide soybean protein complex fiber. According to the preparation method, production steps are simplified; the manufacturing cost is low; no aldehyde pollution exists; industrial production is facilitated; the protein molecular weight is low; the loss amount of the protein is low; and maintaining of excellent performance of the protein fiber is facilitated.

Description

technical field [0001] The invention relates to the technical field of functional cellulose fibers, in particular to the preparation of a polypeptide soybean protein composite fiber. Background technique [0002] Protein fibers are divided into natural protein fibers (such as wool, silk, etc.) and regenerated protein fibers. According to the source of raw materials, regenerated protein fiber can be divided into regenerated animal protein fiber and regenerated plant protein fiber. Regenerated animal protein fiber mainly refers to fiber spun from protein extracted from milk, wool, pig hair, etc. Regenerated plant protein mainly refers to fiber spun from protein extracted from corn, soybean, peanut, rapeseed, etc. [0003] At present, domestic and foreign studies have disclosed a lot of production processes about protein fibers, but most of them remain in theoretical discussions, and no products have been seen, and industrial production has not been realized. Such as the Chin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/02D01F8/10D01F1/10
Inventor 孙力
Owner 湖州珠力纳米材料科技开发有限公司
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