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Silumin alloy melt alterant and silumin alloy preparation method using alterant

A silicon-aluminum alloy and modifying agent technology, applied in the field of alloys, can solve the problems of inability to modify the silicon-aluminum alloy, incapable of engineering application, small size of ingots, etc., and achieve the effect of fine alloy structure, good metamorphic function, and alloy structure improvement.

Active Publication Date: 2013-12-11
CHINA WEAPON SCI ACADEMY NINGBO BRANCH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The prepared spindle is small in size and can only be used for testing, not for engineering application
From the published literature and patents, Al-P intermediate alloys, Al-Ti-B alloys, Al-Sb alloys, and some rare earth-containing alloys are used for the modification of silicon-aluminum alloys. The patent literature can refer to the application number 200910087743.6 The Chinese invention patent application publication "a phosphating modifier" (publication number is CN101580908A), the application number is 201210502460.5 Chinese invention patent application publication "a kind of aluminum-phosphorus-strontium-rare earth alloy modifier and its preparation process" ( The publication number is CN102925765A), the silicon-aluminum alloy structure obtained in the above-mentioned literature, especially the structure with a Si content of more than 40%, is coarse, and the size of the coarse-crystalline silicon is more than 30um, which is blocky and has sharp edges and corners, which seriously affects Compared with the alloys of foreign materials, there is a big difference in the performance of the alloy.
It can be seen from the structure that there are serious problems in the modification process of silicon-aluminum alloys with a silicon content of more than 40%, and the existing modifiers cannot effectively modify silicon-aluminum alloys.

Method used

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  • Silumin alloy melt alterant and silumin alloy preparation method using alterant
  • Silumin alloy melt alterant and silumin alloy preparation method using alterant
  • Silumin alloy melt alterant and silumin alloy preparation method using alterant

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Weigh 40kg of pure silicon and 60kg of pure aluminum respectively, put the pure aluminum into the bottom of the intermediate frequency furnace, put silicon into the top, and heat with electricity until the aluminum and silicon are all melted into a melt, and the temperature of the melt is raised to 1100°C, and fully stirred , turn off the power and let it cool down to 1000°C, add 0.6% modifier by weight (modifier content and weight ratio are Na 2 SO 4 8%, NaCl8%, K 2 ZrF 6 16%; Na 3 PO 4 68%). After the end of metamorphism and standing for 10 minutes, use C 2 Cl 6 Degassing and refining the silicon-aluminum melt with the Hongguang refining agent HGJ-1A purchased on the market, and deslagging off the melt after the end. Heat the melt to 1150°C, pour it into the diversion tank for spray deposition process, the atomization pressure is 0.6-0.8MPa, the atomization gas is nitrogen, the deposition distance is 680-710mm, and the melt is sprayed into a diameter of 220mm....

Embodiment 2

[0037] Weigh 50kg of pure silicon and 50kg of pure aluminum respectively, and complete the melt treatment according to the steps of Example 1, wherein the temperature of adding the modifier is 1100°C, (the content of the modifier is 0.6%, and its components and weight ratio are, Na 2 SO 4 10%, NaCl10%, K 2 ZrF 6 20%;Na 3 PO 4 60%). The melt temperature during the spray deposition process is 1200°C, and the other parameters remain unchanged.

[0038] The microstructures of spray-deposited 50Si50Al alloy treated with modifier and conventional modifier (Al-P alloy) after hot isostatic pressing are as follows: image 3 and Figure 4 shown. It can be seen from the figure that the silicon-aluminum alloy modified by conventional modifiers has a very uneven primary silicon structure, the smallest is 5um, and the largest is 45um, and the shape of the primary silicon is very irregular, with sharp edges and corners. The primary silicon with this shape tends to generate microc...

Embodiment 3

[0041] Weigh 70kg of pure silicon and 30kg of pure aluminum respectively, and complete the melt treatment according to the steps of Example 1, wherein the temperature of adding the modifier is 1300°C, (the content of the modifier is 0.6%, and its components and weight ratio are Na 2 SO 4 12%, NaCl12%, K 2 ZrF 6 24%; Na 3 PO 4 52%) for the spray deposition process, the melt temperature was 1450°C, and the other parameters remained unchanged.

[0042] Spray-deposited 70Si30Al alloy treated with modifiers after hot isostatic pressing, such as Figure 5 shown. It can be seen from the figure that after the modification and hot isostatic pressing of the 70Si30Al alloy, there are no micropores in the structure, and the structure is relatively uniform, round, and the amount of primary silicon is large.

[0043] The physical properties of the 70Si30Al alloy after hot isostatic pressing with a modifier were tested. The test results show that the thermal expansion coefficient of...

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Abstract

A silumin alloy melt alterant is characterized by comprising the following components in percentage by weight: 8-12% of Na2SO4, 8-12% of NaCl, 16-24% of K2ZrF6, and 48-72% of Na3PO4. The invention further discloses a silumin alloy melt preparation method. Compared with the prior art, the silumin alloy melt alterant has the advantages that the alterant provided by the invention has a better alteration function, so that an alloy structure is remarkably improved, the result obtained through structure observation and analysis shows that the alloy structure is thin and tiny, the size of primary silicon is 5-25 micrometers, and the primary silicon is round and smooth in edges and has no cuspidal edge or sharp corner.

Description

technical field [0001] The invention relates to a modification agent, which is applied to the modification process of silicon-aluminum alloy, and also relates to a preparation method of silicon-aluminum alloy, which belongs to the field of alloy technology. Background technique [0002] With the continuous advancement of science and technology, the integration of electronic devices is getting higher and higher, which leads to an increase in the heating rate of electronic devices, which makes the operating temperature of the circuit continue to rise, resulting in an increase in the failure rate of components. Some electronic devices, especially those used in high-precision electronic devices, are very expensive. If they fail due to an increase in operating temperature, a material will often be prohibited from being used in this field. Therefore, the development of materials with low density, low expansion coefficient and high thermal conductivity New packaging materials with ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/04
Inventor 陈伟章国伟辛海鹰陈刚翟景马力郭安振
Owner CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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