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Bio-based methanol gasoline detergent and dispersant and preparation method thereof

A clean dispersant, methanol gasoline technology, applied in the petroleum industry, liquid carbon-containing fuels, fuels, etc., can solve the problems of affecting the charging efficiency of the cold-start combustible mixture, the effect is not ideal, the valve action is slow, etc., to eliminate idle speed. Instability, reduce high temperature and paint film formation, eliminate the effect of sulfide

Active Publication Date: 2015-12-09
NORTHWEST UNIVERSITY FOR NATIONALITIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It will directly affect the cold start of the car and the charging efficiency of the combustible mixture entering the combustion chamber. In severe cases, it will cause the valve to move slowly and not close tightly
Therefore, methanol gasoline must use a detergent dispersant compared with unleaded gasoline, and the dispersant described in CN101705122A is calcium petroleum sulfonate and magnesium stearate, magnesium isostearate with metal ions; in CN102604692A, Be to use environmental pollution benzene, xylene as the effect of clean and dispersed; In CN1840620B, a large amount of metal salts have been used: polyisobutylene phosphobarium, zinc dialkyldithiophosphate, in CN101285010A, the clean and dispersed components are Propanol, dipentene; in CN102161919A, the cleaning and dispersing components are n-isopropanol, limonene, and cyclohexane, and these components all have certain cleaning and dispersing effects, but the effects are not ideal

Method used

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  • Bio-based methanol gasoline detergent and dispersant and preparation method thereof
  • Bio-based methanol gasoline detergent and dispersant and preparation method thereof
  • Bio-based methanol gasoline detergent and dispersant and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A bio-based methanol gasoline detergent and dispersant is composed of the following volume percentage functional components:

[0032] Surface active component: C 4 ~C 5 Morpholine and / or N-methylmorpholine 30.0%;

[0033] Dispersed Peat Component: C 16 ~C 18 Fatty acids 20.0%; C n Fatty amine calcium salt 15.0%;

[0034] Cleansing components: C n Fat calcium salt 35.0%;

[0035] Among them: the surface active component is C 4 ~C 5 One of morpholine and N-methylmorpholine or a mixture of the two in equal proportions by volume; C of the dispersed peat component 16 ~C 18 The fatty acid is petroleum yeast fatty acid (RCOOH) or oleic acid (C 18 h 34 o 2 ), the C n Fatty amine calcium salt is T154+T109 mother liquor prepared with polyisobutylene bis-succinimide and alkyl salicylate calcium in a volume ratio of 1:1; the C of the cleansing component n Fatty calcium salt is T115B+T105 mother liquor prepared with sulfurized alkylphenate calcium and medium alkali valu...

Embodiment 2

[0037] A bio-based methanol gasoline detergent and dispersant is composed of the following volume percentage functional components:

[0038] Surface active component: C 4 ~C 5 Morpholine and / or N-methylmorpholine 35.0%;

[0039] Dispersed Peat Component: C 16 -C 18 Fatty acids 16.0%; C n Fatty amine calcium salt 17.0%;

[0040] Cleansing components: C n Fat calcium salt 32.0%;

[0041] Among them: the surface active component is C 4 ~C 5 One of morpholine and N-methylmorpholine or a mixture of two in equal proportions by volume; C of dispersed peat components 16 ~C 18 The fatty acid is petroleum yeast fatty acid (RCOOH) or oleic acid (C 18 h 34 o 2 ), the C n Fatty amine calcium salt is T154+T109 mother liquor prepared with polyisobutylene bis-succinimide and alkyl salicylate calcium in a volume ratio of 1:1; the C of the cleansing component n Fatty calcium salt is T115B+T105 mother liquor prepared with sulfurized alkylphenate calcium and medium alkali value syn...

Embodiment 3

[0043] A bio-based methanol gasoline detergent and dispersant is composed of the following volume percentage functional components:

[0044] Surface active component: C 4 ~C 5 Morpholine and / or N-methylmorpholine 37.0%;

[0045] Dispersed Peat Component: C 16 ~C 18 Fatty acids 14.0%; C n Fatty amine calcium salt 18.0%;

[0046] Cleansing components: C n Fat calcium salt 31.0%;

[0047] Among them: the surface active component is C 4 ~C 5 One of morpholine and N-methylmorpholine or a mixture of two in equal proportions by volume; C of dispersed peat components 16 ~C 18 The fatty acid is petroleum yeast fatty acid (RCOOH) or oleic acid (C 18 h 34 o 2 ), the C n Fatty amine calcium salt is T154+T109 mother liquor prepared with polyisobutylene bis-succinimide and alkyl salicylate calcium in a volume ratio of 1:1; the C of the cleansing component n Fatty calcium salt is T115B+T105 mother liquor prepared with sulfurized alkylphenate calcium and medium alkali value syn...

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Abstract

The invention discloses a cleaning and dispersing agent for bio-based methanol gasoline and a preparation method of the cleaning and dispersing agent. The cleaning and dispersing agent consists of 30-40% of surfactant ingredient, 32-35% of dispersing peat ingredient and 30-35% of cleaning and washing ingredient; and the cleaning and dispersing agent product is prepared through uniformly mixing the three functional ingredients at normal temperature. According to the cleaning and dispersing agent and the preparation method of the cleaning and dispersing agent, cleanable, environmental-friendly, reproducible and degradable petroleum yeast fatty acid is selected as a cheap additive, so that the energy is saved and the emission is reduced; and compared with the prior art, the cleaning and dispersing agent is low in cost, non-toxic, free of pollution, low in dosage and remarkable in cleaning and dispersing effect and cannot cause secondary pollution to the environment. According to the cleaning and dispersing agent and the preparation method of the cleaning and dispersing agent, organic modification is carried out by using substances such as the yeast fatty acid, morpholine and fatty-amine calcium salts, so that the special cleaning and dispersing agent for the methanol gasoline is synthesized; and the cleaning and dispersing agent disclosed by the invention has the advantages that the formation of carbon deposit can be prevented effectively, formed carbon deposit is removed, a fuel injection nozzle, an air inlet valve and a combustion chamber of a gasoline engine are effectively prevented from emergence and production of carbon deposit, and the removal ratio is up to 32.12-64.14%.

Description

technical field [0001] The invention relates to the field of alternative fuels for alcohols, in particular to a bio-based methanol gasoline detergent and dispersant which mainly uses biomass energy and can be blended with bio-alcohols in a high proportion and a preparation method thereof. It can effectively prevent and reduce the carbon deposits in engine fuel injectors, intake valves and combustion chambers. Background technique [0002] For a long time, gasoline and diesel have been the main fuels for various types of motor vehicles. This usage pattern is increasingly restricted by serious environmental pollution and increasingly scarce resources. In order to improve this dilemma, a variety of energy alternatives have been adopted at home and abroad. However, if these alternatives are to be popularized on a large scale, there are serious defects. In recent years, as the international oil price continues to hover at a high level, the promotion, application and research pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L1/10C10L1/233C10L1/188C10L1/234C10L1/189
Inventor 牛锋黄晓磊吴慧昊
Owner NORTHWEST UNIVERSITY FOR NATIONALITIES
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