Pneumatic tire and process for production thereof, and tire curing bladder
A technology for pneumatic tires and a manufacturing method, which is applied to pneumatic tires, special tires, tire parts and other directions, can solve problems such as damage to the inner liner, and achieve the effects of reduced rolling resistance and good resistance to flex crack growth.
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Embodiment 1~35、 comparative example 1~9
[0212] (Production of polymer sheet and polymer laminate)
[0213] According to the formula shown in Table 1, put each formula into the twin-screw extruder (screw diameter: 50mm, L / D: 30, cylinder temperature: 200°C), kneaded at 200 rpm to prepare pellets (manufacturing example 1 to manufacturing example 8). The obtained pellets were put into a co-extruder (cylinder temperature: 200°C) to produce polymer sheets or polymer laminates having structures shown in Tables 3 to 6.
[0214] [Table 1]
[0215]
[0216] (Note 1) SIBS: "Sibstar 102T" manufactured by Kaneka Co., Ltd. (styrene-isobutylene-styrene triblock copolymer, weight average molecular weight 100,000, styrene unit content 25% by mass, Shore A hardness 25).
[0217] (Note 2) SIS: "D1161JP" manufactured by Kraton Polymers (styrene-isoprene-styrene triblock copolymer, weight average molecular weight 150,000, styrene unit content 15% by mass).
[0218] (Note 3) SIB: In a 2L reaction vessel with a stirrer, 589 mL of methylcyclohex...
Embodiment 36~70
[0270]
[0271]
[0272] According to the formula shown in Table 7, put each formula into the twin-screw extruder (screw diameter: 50mm, L / D: 30, cylinder temperature: 200°C), kneaded at 200 rpm to prepare pellets (Production Example 9 to Production Example 15). The obtained pellets were put into a co-extruder (cylinder temperature: 200°C) to produce polymer laminates having structures shown in Tables 9 to 11.
[0273]
[0274] (Note 1) IIR: "Exxon Chlorobutyl 1066" manufactured by Exxon Mobil Corporation.
[0275] (Note 2) NR: Natural rubber TSR20.
[0276] (Note 3) SIBS: "Sibstar 102T" manufactured by Kaneka Co., Ltd. (styrene-isobutylene-styrene triblock copolymer, weight average molecular weight 100,000, styrene unit content 25% by mass, Shore A hardness 25).
[0277] (Note 4) SIS: "D1161JP" manufactured by Kraton Polymers (styrene-isoprene-styrene triblock copolymer, weight average molecular weight 150,000, styrene unit content 15% by mass).
[0278] (Note 5) SIB: In a 2L reacti...
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