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Nitrogen fertilizer immobilization process using active soil and flocculant/adsorbent composite material

A composite material and flocculant technology, applied in fertilization devices, fertilizer mixtures, agricultural gas emission reduction, etc., can solve the problems of complicated slow-release fertilizer production process, high production cost restrictions, etc., to improve nitrogen utilization and soil improvement. , Environmentally friendly effect of raw materials

Active Publication Date: 2013-04-17
安徽帝元生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the complex production process or high production cost of slow-release fertilizers limit its large-scale promotion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The nitrogen fertilizer immobilization technology of active soil, flocculant and adsorbent composite material includes the following steps:

[0022] (1) 300 mesh colloidal grade attapulgite and magnesium hydroxide were uniformly mixed at a mass ratio of 95:5, and then irradiated with gamma rays with an energy of 5 MeV and a dose of 20 kGy for 30 minutes to obtain modified attapulgite;

[0023] (2) Mix the modified attapulgite and acrylic acid evenly according to the mass ratio of 97:3, and then irradiate with ultraviolet rays with a wavelength of 354 nm for 30 minutes, and the mixture is 5 cm away from the light source to form attapulgite-polyacrylic acid network composite;

[0024] (3) Mix attapulgite-polyacrylic acid network compound and 300-mesh straw ash evenly at a mass ratio of 70:30, and then use 110°C hydrothermal treatment for 10 minutes to form attapulgite-polyacrylic acid-biological carbon ternary Complex;

[0025] (4) Mix the attapulgite-polyacrylic aci...

Embodiment 2

[0028] (1) 200-mesh colloidal grade attapulgite and magnesium hydroxide were uniformly mixed at a mass ratio of 90:10, and then irradiated with gamma rays with an energy of 5 MeV and a dose of 50 kGy for 30 minutes to obtain modified attapulgite;

[0029] (2) Mix the modified attapulgite and acrylic acid at a mass ratio of 95:5, and then irradiate with ultraviolet rays with a wavelength of 354 nm for 20 minutes. The mixture is 5 cm away from the light source to form an attapulgite-polyacrylic acid network composite ;

[0030] (3) Mix attapulgite-polyacrylic acid network compound and 200-mesh straw ash evenly in a mass ratio of 60:40, and then use 110°C hydrothermal treatment for 15 minutes to form attapulgite-polyacrylic acid-biological carbon ternary Complex;

[0031] (4) Mix the attapulgite-polyacrylic acid-biological carbon ternary compound with polyacrylamide, chitosan and sodium tripolyphosphate according to the mass ratio of 95:1:3:1, and then shear at a high speed of 1...

Embodiment 3

[0034] (1) 200 mesh colloidal grade attapulgite and magnesium hydroxide were uniformly mixed at a mass ratio of 93:7, and then irradiated with gamma rays with an energy of 5 MeV and a dose of 30 kGy for 20 minutes to obtain modified attapulgite;

[0035] (2) Mix the modified attapulgite and acrylic acid according to the mass ratio of 97:3, and then irradiate with ultraviolet rays with a wavelength of 354 nm for 15 minutes. The mixture is 5 cm away from the light source to form attapulgite-polyacrylic acid network composite ;

[0036] (3) Mix the attapulgite-polyacrylic acid network compound and 200-mesh straw ash evenly at a mass ratio of 70:30, and then use 110°C hydrothermal treatment for 20 minutes to form attapulgite-polyacrylic acid-biological carbon ternary Complex;

[0037] (4) Mix the attapulgite-polyacrylic acid-biological carbon ternary compound with polyacrylamide, chitosan and sodium tripolyphosphate according to the mass ratio of 95:1:2:2, and then shear at a hig...

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PUM

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Abstract

The invention discloses a nitrogen fertilizer immobilization process using an active soil and flocculant / adsorbent composite material. Attapulgite clay is chemically modified by irradiation to improve dispersibility and can form a multilayer micro- / nano-scale network structure by self-assembly in a water-poor environment under the action of flocculants, the adsorbed nitrogen fertilizer together with the non-adsorbed nitrogen fertilizer is embedded inside the network structure by use of biological carbon with high adsorbability, so that the nutrients of the nitrogen fertilizer are effectively stored in the network structure to prevent free migration of the nutrients and control the loss of the nutrients to the environment. The process can effectively reduce the migration and loss of nitrogen elements, increase the utilization efficiency of chemical fertilizers and reduce the environmental pollution caused by the loss of nitrogen elements. The process can achieve the effects of reducing the discharge of fertilizers, increasing the utilization efficiency of nitrogen fertilizers, reducing the consumption of chemical fertilizers, protecting the environment, reducing the cost and simplifying the process, and is significant in controlling eutrophication non-point pollution of water bodies and protecting the ecological environment.

Description

technical field [0001] The method relates to a novel long-term immobilization method of nitrogen fertilizer, in particular to a nitrogen fertilizer immobilization technology of active soil, flocculant and adsorbent composite material. Background technique [0002] my country is a big producer and consumer of chemical fertilizers. At present, my country's fertilizer utilization rate is very low, nitrogen, phosphorus, and potassium fertilizers are 25% to 30%, 10% to 25%, and 35% to 50%, respectively. At present, my country uses 240 kilograms of chemical fertilizer per hectare, and the amount of fertilizer per unit area is 1.6 times the world average. The utilization rate of chemical fertilizers in my country is much lower than that of developed countries, and the use efficiency of chemical fertilizers is showing a downward trend. The annual loss of nitrogen due to fertilization in the country reaches 16.5 million tons, and the economic loss is nearly 100 billion yuan. The m...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05G3/08C05G3/90
CPCY02P60/21
Inventor 姜疆蔡冬清余增亮吴跃进
Owner 安徽帝元生物科技有限公司
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