Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Method for preparing rapid high oil absorption resin by using macromolecule pore-foaming agent

A technology of oleoresin and porogen, which is applied in the field of functional polymer materials, can solve the problems of cost reduction, slow oil absorption rate, and performance degradation, and achieve the effects of cost reduction, performance degradation, and high oil absorption

Inactive Publication Date: 2014-04-09
WUHAN INSTITUTE OF TECHNOLOGY
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to propose a method for preparing a fast and high oil-absorbing resin by using a macromolecular porogen, which overcomes the disadvantages of slow oil-absorbing rate of general resins and performance decline after repeated oil-absorbing, thereby reducing the cost

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing rapid high oil absorption resin by using macromolecule pore-foaming agent
  • Method for preparing rapid high oil absorption resin by using macromolecule pore-foaming agent
  • Method for preparing rapid high oil absorption resin by using macromolecule pore-foaming agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Dissolve 3.129 grams of poly-n-butyl methacrylate in 3.129 grams of n-butyl methacrylate, then add 1.252 grams of Span 80 and 0.275 grams of divinylbenzene into n-butyl methacrylate, stir evenly, and pass Nitrogen for 40 minutes to obtain an oily phase. Take 32 grams of deionized water as the water phase, and add the water phase to the oil phase dropwise at a constant speed at a stirring speed of 1000 rpm. After the dropwise addition, 0.082 g of ammonium persulfate (0.36 mmol) and 0.037 g of sodium bisulfite (0.356 mmol) were weighed to prepare an aqueous solution, added to the above emulsion, and continued to stir for 20 minutes until the emulsion was stable. React at 40 degrees Celsius for 24 hours, extract the product through a Soxhlet extractor for more than 12 hours, and dry it in vacuum to obtain a fast high oil-absorbing resin.

[0026] The obtained rapid high oil-absorbing resin has an oil absorption rate of 31 times for chloroform and 17 times for toluene; the...

Embodiment 2

[0031] Dissolve 1.877 g of polymethyl methacrylate in 4.381 g of methyl methacrylate, then add 1.252 g of Span 80 and 0.386 g of divinylbenzene into the methyl methacrylate, stir evenly, and blow in nitrogen for 20 minutes , to obtain the oil phase. Take 50 grams of deionized water as the water phase, and add the water phase to the oil phase dropwise at a constant speed at a stirring speed of 1000 rpm to obtain an emulsion. After the dropwise addition, weigh 0.114 g of ammonium persulfate (0.5 mmol) and 0.052 g of sodium bisulfite (0.5 mmol) to prepare an aqueous solution, add it to the above emulsion, and continue to stir for 30 minutes until the emulsion is stable. React at 50 degrees Celsius for 24 hours, extract the product through a Soxhlet extractor for more than 12 hours, and dry it in vacuum to obtain a fast high oil-absorbing resin.

[0032] The obtained rapid high oil-absorbing resin has an oil absorption rate of 17 times for chloroform and 9 times for toluene; the ...

Embodiment 3

[0034] Dissolve 2.503 g of n-butyl polyacrylate in 3.755 g of n-butyl acrylate, then add 1.252 g of Span 60 and 0.25 g of divinylbenzene into n-butyl acrylate, stir evenly, and inject nitrogen gas for 20 minutes to obtain oil Mutually. Take 32 grams of deionized water as the water phase, and add the water phase to the oil phase dropwise at a constant speed at a stirring speed of 1100 rpm to obtain an emulsion. After the dropwise addition, weigh 0.079 g of ammonium persulfate (0.346 mmol) and 0.035 g of sodium bisulfite (0.337 mmol) to prepare an aqueous solution, add it to the above emulsion, and continue stirring for 20 minutes until the emulsion is stable. React at 40 degrees Celsius for 24 hours, extract the product through a Soxhlet extractor for more than 12 hours, and dry it in vacuum to obtain a fast high oil-absorbing resin.

[0035] The obtained rapid high oil-absorbing resin has an oil absorption rate of 22 times for chloroform and 11 times for toluene; the time req...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a method for preparing a rapid high oil absorption resin by using a macromolecule pore-foaming agent. The method comprises the following steps: 1) firstly, dissolving the macromolecule pore-foaming agent in a monomer, adding an emulsifier and a cross-linking agent in the monomer, stirring uniformly, introducing nitrogen to obtain an oil phase; 2) taking a certain amount of deionized water as a water phase, dropwise adding the water phase to the oil phase at a constant speed to obtain emulsion after dropwise adding, adding the configured oxidation reduction initiation system in the emulsion, stirring continuously until the emulsion is stable, and finally polymerizing the emulsion to obtain oil absorption resin; and 3) extracting the oil absorption resin through a soxhlet extractor and carrying out vacuum drying to obtain rapid high oil absorption resin. In comparison with the prior art, the resin has higher oil absorption volume and oil absorption rate, so that the resin has good effect when an emergent oil product pollution event needs to be handled urgently. The resin has good reuse performance, so that the cost is lowered.

Description

technical field [0001] The invention relates to a method for preparing a rapid high oil-absorbing resin by using a macromolecule porogen, and belongs to the field of functional polymer materials. Background technique [0002] With the rapid development of my country's economy, sudden oil pollution incidents are increasing day by day. Such incidents often require rapid emergency treatment in a short period of time, so it is particularly important to have fast and efficient oil-absorbing resins. [0003] Super oil-absorbing resin is a resin with three-dimensional network chemical crosslinking structure, which has developed rapidly in recent years. Most of the oil-absorbing resins reported so far have a very slow oil absorption rate, and it usually takes several hours to reach the saturated oil absorption. For some porosity fast oil-absorbing resins, it also takes one or two hours to reach the saturated oil absorption. Most of these resins use organic solvents such as ethyl ac...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/26C08F212/08C08F220/14C08F220/18C08F212/36C08F222/14C08F4/40C09K3/32
Inventor 喻发全马立彬罗晓刚朱三薛亚楠蔡宁
Owner WUHAN INSTITUTE OF TECHNOLOGY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com