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Manufacturing method of high-calcium solid sulfur ash aerated concrete building blocks

A high-calcium sulfur-fixing ash and aerated concrete technology, applied in the field of building materials, can solve the problems of low compressive strength and post-freezing strength, difficult process control, and easy plugging of pipes, etc., to achieve compressive strength and freezing The effect of high final strength, simple process flow, and not easy to crack and deform

Inactive Publication Date: 2013-01-02
贵州省建筑材料科学研究设计院有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to high calcium sulfur-fixing ash requires a lot of water, has a large self-hardening property, condenses too quickly, and is easy to block pipes, so when reaching the same consistency, it needs to increase the amount by about 50% compared with the normal amount, resulting in low product strength and low sulfur-fixing ash content. The fluctuation is large, and the process control is difficult; in addition, the content of free calcium oxide and sulfur trioxide in high-calcium sulfur-fixing ash seriously exceeds the technical requirements of fly ash for silicate products, so it is necessary to mix it when the raw materials are unqualified. Quantity control makes its comprehensive utilization very difficult
At present, the utilization of high-calcium sulfur-fixing ash mainly focuses on the production of sulphoaluminate cement, cement admixture, molecular sieve, soil conditioner, autoclaved brick, etc. There are also reports of its use in aerated concrete, but the solid The content of f-CaO in sulfur ash is 1% to 3.6%, the content of SO 3 is 3% to 7%, and the product is easy to crack and deform, and its compressive strength and strength after freezing are relatively low, reaching It does not meet the requirements of China's national standard GB11968-2006 "Autoclaved Aerated Concrete Blocks", so the existing method of using high calcium and sulfur-fixed ash to make aerated concrete blocks is not ideal and has not been widely used yet.

Method used

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  • Manufacturing method of high-calcium solid sulfur ash aerated concrete building blocks

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Embodiment 1

[0013] Embodiment 1 of the present invention: calculated by weight, get 50 parts of high-calcium sulfur-fixing ash, 20 parts of fly ash, 9 parts of ordinary Portland cement whose label is 42.5, and the siliceous material of finely ground silica sand or microsilica fume 5 parts of lime, 15 parts of lime, 1 part of gypsum, and 0.06 parts of aluminum powder are used as raw materials. The sulfur trioxide content of the high-calcium sulfur-fixing ash should be controlled within the range of 4.5% to 15%, and the free calcium oxide content should be controlled within 1.8%. ~10% range; gypsum can be natural gypsum or phosphogypsum or desulfurized gypsum from industrial by-products; lime should be ground quicklime, and the sum of the percentages of CaO and MgO in the ground quicklime should be controlled at CaO+MgO ≥75% range; then put high-calcium sulfur-fixing ash, fly ash, siliceous materials and gypsum together into a ball mill for mixing and ball milling for 5 to 20 minutes, then...

Embodiment 2

[0014] Embodiment 2 of the present invention: calculated by weight, get 70 parts of high-calcium sulfur-fixing ash, 30 parts of fly ash, 10 parts of ordinary Portland cement whose label is 42.5, and the siliceous material of finely ground silica sand or microsilica fume 10 parts of lime, 16 parts of lime, 1 part of gypsum, and 0.06 parts of aluminum powder are used as raw materials. The sulfur trioxide content of the high-calcium sulfur-fixing ash should be controlled within the range of 4.5% to 15%, and the free calcium oxide content should be controlled within 1.8%. ~10% range; gypsum can be natural gypsum or phosphogypsum or desulfurized gypsum from industrial by-products; lime should be ground quicklime, and the sum of the percentages of CaO and MgO in the ground quicklime should be controlled at CaO+MgO ≥75% range; then put high-calcium sulfur-fixed ash, fly ash, siliceous materials, and gypsum into the mixer and add water to stir it. The weight of water added is 0.3 to ...

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Abstract

The invention discloses a manufacturing method of high-calcium solid sulfur ash aerated concrete building blocks. According to the invention, 40-70 parts of high-calcium solid sulfur ash, 20-40 parts of fly ash, 5-12 parts of cement, 0.1-15 parts of a silicon material, 10-20 parts of lime, 0.1-2 parts of gypsum, and 0.06-0.1 parts of aluminum powder are adopted as raw materials; high-calcium solid sulfur ash, fly ash, the silicon material, and gypsum are added into a mixer; water is added to the mixer, and stirring is carried out, such that a slurry is obtained; aluminum powder, lime, and cement are added to the slurry, and the mixture is well mixed by stirring, such that a casting slurry is obtained; the casting slurry is cast into a mold, and standing and preventive maintenance are carried out; when preventive maintenance is finished, building blocks are obtained by cutting; and the building blocks are subjected to autoclaved maintenance in an autoclave, such that finished products are obtained. With the method provided by the invention, the manufactured product can hardly crack and deform, and has advantages of high compressive strength and after-freeze strength. The method provided by the invention has the advantages of simple technical process, high high-calcium solid sulfur ash utilization amount, low manufacturing cost, convenient construction, and the like.

Description

technical field [0001] The invention relates to a method for manufacturing a high-calcium-sulfur-fixed ash aerated concrete block, and belongs to the technical field of building material manufacturing. Background technique [0002] High-calcium sulfur-fixed ash is the fly ash discharged from the furnace combustion desulfurization process using circulating fluidized bed combustion. With the rapid development of science and technology, people's awareness of energy conservation and environmental protection is constantly increasing, and energy conservation and environmental protection have become major themes of today's social development. Circulating fluidized bed combustion technology is a new coal-fired technology that can burn various low-quality fuels, such as high-sulfur and high-ash coal, coal gangue, peat, tailings, slag, etc. This technology is one of the advanced technologies for clean coal combustion and sustainable development strategy. It integrates the advantages...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04C04B22/04
Inventor 万军贾韶辉董发勤杨革新陈滨刘恒波贺深阳宋美赵怡然
Owner 贵州省建筑材料科学研究设计院有限责任公司
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