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Slag modifier and preparation method and application thereof

A modifier and slag technology, applied in the field of steelmaking and refining, can solve the problems of increasing the cost of steelmaking, affecting refining efficiency, and high cost, and achieving the effects of saving resources, highlighting economic benefits, and hard texture

Active Publication Date: 2014-06-04
大连环球矿产股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CaO+CaF 2 Al-based regulators have been widely used. Although the operation method is simple and the cost is low, the amount of slag is large and the slag formation speed is slow, and it cannot fundamentally solve the problem of re-oxidation of molten steel by FeO and MnO in slag; Al-based deoxidation effect is good, but High cost; CaC 2 The base is a better diffusion deoxidizer, but in the process of use, there will be occasional carburization
[0004] Chinese patent CN1441066A discloses an aluminum slag making ball. The process of using a binder will have many effects: the use of bentonite will reduce the alkalinity of the refining slag and affect the refining efficiency; the addition of organic matter such as starch will increase the hydrogen of the molten steel, Increase the probability of steel white spot defects
Chinese patent CN100569962 uses a large amount of metal aluminum powder, which increases resource consumption and steelmaking costs, and the increased carbonization probability of a large amount of calcium carbide is not conducive to the production of ultra-low carbon steel.

Method used

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  • Slag modifier and preparation method and application thereof
  • Slag modifier and preparation method and application thereof
  • Slag modifier and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] ① Weigh 60 parts by mass of aluminum ash with an Al content of 45%, 10 parts by mass of aluminum chips with an Al content of 89%, 25 parts by mass of active lime with a CaO content of 89% and CaF 2 5 parts by mass of fluorite with a content of 80%, mixed in closed pre-mixing equipment;

[0024] ②Mechanically formed under the pressure of 35MPa, it is a sphere of ∮15~∮40.

[0025] The detected component content is SiO 2 : 5.6%, CaO: 26.5%, Al: 35.5%, Al 2 o 3 : 28.9%, MgO: 2.1%, traces of impurities.

Embodiment 2

[0027] The slag modifier obtained in Example 1 was tested in the following process: converter tapping-ladle argon blowing-adding slag modifier-RH process, and added to the surface of molten steel in an amount of 1-2Kg / t. The average content of (FeO+MnO) in slag before RH treatment reached 9.58%, and the average removal rate of FeO content in converter residue reached 69.98%.

Embodiment 3

[0029] ① Weigh 50 parts by mass of aluminum ash with an Al content of 48%, 20 parts by mass of aluminum chips with an Al content of 85%, 12 parts by mass of active lime with a CaO content of 88%, and CaF 2 Content is 85% of 8 parts by mass and CaC 2 10 parts by mass of calcium carbide with a content of 75%, mixed in closed premixing equipment;

[0030] ②Mechanically formed under the pressure of 35MPa, it is a sphere of ∮15~∮40.

[0031] The detected component content is SiO 2 : 3.5%, CaO: 22%, Al: 41%, Al 2 o 3 : 26.3%, MgO: 2.4%, CaF 2 : 4.2%, trace amount of impurities.

[0032] The slag modifier was added to 23 furnaces of molten steel for testing, and the average content of (FeO+MnO) in the slag reached 7.58%.

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Abstract

The invention discloses a slag modifier which comprises the following components by weight percentage: 40-70% of aluminium dross, 10-35% of aluminium skimmings, 10-40% of active lime, 0.5-10% of fluorite, and 0-35% of calcium carbide, wherein the Al content in the aluminium dross is 15-50%, and the Al content in the aluminium skimmings is 75-95%. The slag modifier prepared by the invention is hard in quality, is not cracked, has no powder, cannot cause dust when molten steel is fed, and is beneficial to environment protection. As a large amount of aluminium dross is used, a new effective utilization way can be provided for the industrial slag, and simultaneously, the aluminium skimmings adopt leftover bits and pieces produced during processing in aluminum industry, so that the situation that regenerative aluminum processing is performed again is avoided, resources are saved, and economic benefits are outstanding.

Description

technical field [0001] The invention relates to a slag modifier, which belongs to the field of steelmaking and refining. Background technique [0002] my country has become the world's largest producer and consumer of aluminum. It produces more than 10 million tons of electrolytic aluminum and more than 4 million tons of secondary aluminum every year. Various by-products will be produced in the process of aluminum smelting and forming, and the aluminum produced in the process of mechanical forming Chips (or aluminum particles, aluminum wire segments) contain high aluminum content, up to 80%-95%, and can be used directly. The slag produced in the electrolytic aluminum or cast aluminum production process is called chemical aluminum ash. The current annual output of aluminum ash is 850,000-1.3 million tons. If the year-by-year growth and savings over the years are considered, this figure will be even more alarming. In the past, people regarded aluminum ash as waste and dumped i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/00C21C5/36C21C5/54
CPCY02P10/20
Inventor 张延大张梦显姜山
Owner 大连环球矿产股份有限公司
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