Non-aqueous organic electrolyte, lithium ion secondary battery containing non-aqueous organic electrolyte, preparation method of lithium ion secondary battery and terminal communication equipment
An organic electrolyte, non-aqueous technology, applied in the field of lithium ion secondary battery and its preparation, non-aqueous organic electrolyte, terminal communication equipment, can solve the problems of deterioration of battery performance, failure to work normally, increase of battery pressure, etc. Improved interfacial stability, excellent electrochemical stability, and the effect of inhibiting decomposition
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[0109] Preparation of positive electrode sheet
[0110] The positive electrode active material that the embodiment of the present invention selects is LiMn 1.5 Ni 0.5 o 4 and 0.5Li 2 MnO 3 *0.5LiNiO 2 For the materials mixed with a mass ratio of 9:1, the solid-phase ball milling method is used to disperse the mixture evenly before batching. Mix the dispersed positive electrode active material, conductive agent carbon black powder material and binder PVDF powder material according to the mass ratio of 85:10:5, and then add N-methylpyrrolidone (NMP) solution to prepare oil-based slurry , and finally the slurry is coated on both sides of the aluminum current collector to make a lithium ion secondary battery cathode sheet.
[0111] Preparation of negative electrode sheet
[0112] Negative electrode active material artificial graphite powder, binder carboxymethyl cellulose (CMC), binder styrene butadiene rubber (SBR) emulsion are mixed according to mass ratio 100:3:2, then a...
Embodiment 1
[0122] The non-aqueous organic solvent γ-butyrolactone (GBL), fluoroethylene carbonate (FEC) and propylene carbonate (PC) are mixed according to the volume ratio of 85:10:5 to make a non-aqueous organic solvent, and then the non-aqueous organic solvent is added to the non-aqueous organic solvent. Add 0.1% (Wt) glutaronitrile in the solvent, then add 2% (Wt) vinylene carbonate (VC), finally add a certain quality of lithium salt LiPF 6 The prepared concentration is 0.9M / L to obtain a non-aqueous organic electrolyte. The prepared non-aqueous organic electrolyte solution was injected into the above-mentioned square wound pouch battery to obtain Example 1 of the present invention.
Embodiment 2
[0124] As shown in Example 1, the difference is that the amount of glutaronitrile in the prepared non-aqueous organic electrolyte solution was changed to 1% (wt), to obtain Example 2 of the present invention.
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