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Conductive particles, anisotropic conductive film, assembly, and connection method

A conductive particle and anisotropic technology, applied in the direction of conductive adhesive connection, conductive connection, electrical component connection, etc., can solve the problems of indestructibility and low connection reliability, and achieve the goal of preventing agglutination and high connection reliability Effect

Inactive Publication Date: 2012-05-23
DEXERIALS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the conductive particles of (1) above have elastic deformability because the core particles are resin, so even if the nickel plating layer has protrusions, it cannot be damaged due to the hardness of the circuit board formed on the electrode surface in the circuit components. Oxide film, and there is a problem of lower connection reliability
[0007] In addition, the electroconductive particle of the surface of the nickel core particle described in (2) is gold-plated because the Mohs hardness of the gold formed on the surface is as low as 2.5, so the oxide film on the electrode surface in the circuit component cannot be destroyed, and there is a connection reliability. problem of getting low

Method used

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  • Conductive particles, anisotropic conductive film, assembly, and connection method
  • Conductive particles, anisotropic conductive film, assembly, and connection method
  • Conductive particles, anisotropic conductive film, assembly, and connection method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0136] In Comparative Example 1, the production of the conductive particles was performed as follows, except that, in the same manner as in Comparative Example 1, the evaluation of the conductive particles, the production of the anisotropic conductive film, the production of the junction body 1, and the preparation of the junction body 1 were performed. Evaluation, preparation of the bonded body 2 , evaluation of the bonded body 2 , and observation of the presence or absence of indentations in the bonded body 2 . The results are shown in Tables 1, 3 and 4, Figure 4 middle.

[0137] (Production of conductive particles)

[0138] Put nickel particles with an absolute specific gravity of 8.9 and an average particle size of 5.0 μm (manufactured by Nikko-rica Corporation, trade name nickel powder 123) into an aqueous solution of thallium nitrate, and stir at a rate of 30 mL / min while heating to 60 ° C. Nickel plating is performed by adding a mixed solution of nickel sulfate, sodi...

Embodiment 2

[0140] In Example 1, changing the mixing ratio of nickel sulfate, sodium hypophosphite, sodium citrate, and thallium nitrate in the mixed solution is nickel-nickel particles formed by a nickel-plated layer with a phosphorus concentration of 2.3% by mass on the surface. B, except that, in the same manner as in Example 1, the evaluation of the conductive particles, the production of the anisotropic conductive film, the production of the bonded body 1, the evaluation of the bonded body 1, the preparation of the bonded body 2, and the preparation of the bonded body 2 were carried out. Evaluation. The results are shown in Tables 1, 3 and 4.

Embodiment 3

[0142] In Example 1, changing the mixing ratio of nickel sulfate, sodium hypophosphite, sodium citrate, and thallium nitrate in the mixed solution is nickel-nickel particles formed by a nickel-plated layer with a phosphorus concentration of 6.9% by mass. C, except that, in the same manner as in Example 1, the evaluation of the conductive particles, the production of the anisotropic conductive film, the production of the junction body 1, the evaluation of the junction body 1, the preparation of the junction body 2, and the preparation of the junction body 2 were carried out. Evaluation. The results are shown in Tables 1, 3 and 4.

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PUM

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Abstract

Disclosed are: conductive particles which can be prevented from being aggregated, can damage oxide coating films on the surfaces of electrodes in circuit members upon the connection the circuit members to each other, and can achieve high connection reliability; and an anisotropic conductive film, an assembly, and a connection method each utilizing the conductive particles. Each of the conductive particles comprises a core particle and a conductive layer formed on the surface of the core particle, wherein the core particle is a nickel particle, the conducive layer is a nickel-coated layer having a phosphorus concentration of 10 mass% or less in the surface part thereof, and the conductive layer has an average thickness of 1 to 10 nm.

Description

technical field [0001] The present invention relates to a conductive particle, an anisotropic conductive film using the conductive particle, a bonded body, and a connection method. Background technique [0002] Circuit components such as the connection between a liquid crystal display and a Tape Carrier Package (TCP), the connection between a Flexible Printed Circuit (FPC) and a TCP, or the connection between an FPC and a Printed Wiring Board (PWB) For connection between them, a circuit connection material (for example, an anisotropic conductive film) in which conductive particles are dispersed in a binder resin is used. In addition, recently, when mounting a semiconductor silicon chip on a substrate, in order to connect circuit components, the semiconductor silicon chip is flip-chip mounted directly on the substrate without using wire bonding, and so-called flip chip assembly is performed. In this flip chip assembly, circuit connection materials such as anisotropic conduct...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B5/00B22F1/02H01B1/22H01B5/16H01R11/01H05K1/14H05K3/32H05K3/36B22F1/16
CPCC22C19/03H01B1/02B22F1/02H05K3/323H05K2201/0218C22C5/02B22F1/16Y10T428/12944Y10T428/287Y10T428/12181Y10T428/2991Y10T428/256H01B5/00H01R4/04H01R11/01
Inventor 石松朋之荒木雄太
Owner DEXERIALS CORP
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