Load-type non-metallocene catalyst, preparation method thereof, and application thereof
A non-metallocene and non-metallocene ligand technology, applied in the field of non-metallocene catalysts, can solve problems such as difficult adjustment, unfavorable stable operation of polymerization production, and low olefin polymerization activity
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[0078] The invention relates to a preparation method of a supported non-metallocene catalyst, comprising the following steps: reacting a chemical treatment agent selected from group IVB metal compounds with a porous carrier optionally subjected to thermal activation treatment to obtain a modified carrier; making the obtained The step of contacting the modified support with the non-metallocene ligand in the presence of a solvent to obtain a mixed slurry; and directly drying the mixed slurry to obtain the supported non-metallocene catalyst.
[0079] The porous carrier will be specifically described below.
[0080] According to the present invention, as the porous support, for example, those organic or inorganic porous solids conventionally used as supports in the production of supported olefin polymerization catalysts in the art can be cited.
[0081] Specifically, examples of the organic porous solid include olefin homopolymers or copolymers, polyvinyl alcohol or copolymers the...
Embodiment 1
[0241] The porous carrier is silicon dioxide, that is, silica gel, model ES757 of Ineos Company. First, the silica gel is thermally activated by continuously calcining at 600° C. for 4 hours under a nitrogen atmosphere.
[0242] The chemical treatment agent is titanium tetrachloride (TiCl 4 ). Weigh 5g of thermally activated silica gel, add 60ml of hexane, add titanium tetrachloride under normal temperature stirring conditions, react at 60°C for 2h, filter, wash with hexane 3 times, 60ml each time, and finally vacuum dry to obtain modified carrier.
[0243] Tetrahydrofuran is used as the solvent for dissolving the non-metallocene ligands. The non-metallocene ligand adopts the structure compound of.
[0244] Weigh the non-metallocene ligand, add tetrahydrofuran solvent and dissolve completely at room temperature to obtain a non-metallocene ligand solution, then add the modified carrier, stir for 2 hours, heat the obtained mixed slurry evenly to 60°C, and then directly evac...
Embodiment 2
[0248] Basically the same as Example 1, but with the following changes:
[0249] The porous carrier was changed to Grace's 955, and it was continuously calcined at 400° C. for 8 hours under a nitrogen atmosphere to be thermally activated. The chemical treatment agent was changed to zirconium tetrachloride (ZrCl 4 ), hexane was changed to toluene.
[0250] Non-metallocene ligands use The solvent used to dissolve the non-metallocene ligands was changed to toluene, and the obtained mixed slurry was evenly heated to 100° C., and then directly vacuum-dried to obtain a supported non-metallocene catalyst.
[0251] Wherein the ratio is, the molar ratio of the non-metallocene ligand to the chemical treatment agent is 1:6, the mass ratio to the porous carrier is 1:1, and the ratio to the solvent for dissolving the non-metallocene ligand is 1g:30ml .
[0252] Supported non-metallocene catalysts are designated CAT-2.
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