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Water-based ink, elastic emulsion used for water-based ink and preparation method of elastic emulsion

A technology of water-based ink and elastic emulsion, which is applied in the direction of ink, application, household appliances, etc., and can solve the problems of difficult application of water-based ink, low viscosity of elastic emulsion, poor rheology, etc.

Inactive Publication Date: 2012-03-21
GUANGDONG YINGKE GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Invention Patent Publication No. CN101638452A "High Solid Containing Pure Acrylic Elastic Emulsion", CN1557850A "Preparation Method of Silicone Modified Acrylic Elastic Emulsion", CN101358049A "Elastic Emulsion for Curing Building Putty and Its Preparation Method" etc. The elastic emulsion viscosity prepared Low, poor rheology, difficult to apply to water-based inks

Method used

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  • Water-based ink, elastic emulsion used for water-based ink and preparation method of elastic emulsion
  • Water-based ink, elastic emulsion used for water-based ink and preparation method of elastic emulsion

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] In a three-necked flask with a stirrer, add 70 parts of alkali-soluble acrylic emulsion with a solid content of 42%, an acid value of 150, a molecular weight of 50,000 to 100,000, and Tg=78°C, and then add 16.8 parts of deionized water and 8 1 part of isopropanol, and then add 5.2 parts of monoethanolamine while stirring to obtain a transparent acrylic resin solution with a solid content of 29.4%. The measured viscosity is 150-200 seconds (domestic Tu 4# cup, the test temperature is 40 ℃) , PH value is 9.6.

[0045]

Embodiment 2

[0047] 1. In a round bottom flask with stirring (stirring on, 300-500 rpm), add 130 grams of deionized water, 5 grams of polymerizable emulsifier Emulsogen APS 100 (100%, Clariant Note: 100% is The effective content of this emulsifier, German Clariant products, can be polymerized anionic emulsifier allyl polyoxyethylene ether ammonium sulfate), 12 grams of Emulsogen EPA073 (28%, Clariant, that is, anionic emulsifier alkyl polyoxyethylene ether sulfate Sodium), 9 grams of Emulsogen LCN 407 (70%, Clariant, that is, non-ionic emulsifier alkyl polyoxyethylene ether containing 40 EO), stirred for 5 minutes, and then added 50 grams of styrene, 30 gram of ethyl acrylate, 350 gram of butyl acrylate, 20 gram of N-methylolacrylamide (48%), 10 gram of monobutyl itaconate to prepare the pre-emulsion;

[0048] 2. Dissolve 3.5 grams of ammonium persulfate with 100 grams of deionized water to obtain an aqueous solution of ammonium persulfate;

[0049] 3. Add 200 grams of deionized water, 1 ...

Embodiment 3

[0054] In the pre-emulsion of Embodiment 1, the consumption of monobutyl itaconate is changed into 20 grams, and the consumption of butyl acrylate is changed into 340 grams. Elastic Lotion B.

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Abstract

The invention discloses an elastic emulsion for water-based ink, which is prepared by the following raw materials comprising, by weight, 5 to 8 parts of styrene, 3 to 5 parts of ethyl acrylate, 32 to 35 parts of butyl acrylate, 1 to 2 parts of itaconic acid mono-n-butyl ester, 1 to 2 parts of N-hydroxymethyl acrylamide, 5 to 10 parts of acrylic ester resin liquid, 0.05 to 0.1 part of sodium bicarbonate, 2 to 3 parts of composite emulsifying agent, 0.35 to 0.5 part of composite initiating agent and 35 to 45 parts of deionized water. The invention further discloses a preparation method of the elastic emulsion for the water-based ink and the water-based ink utilizing the elastic emulsion. The water-based ink prepared by utilizing the elastic emulsion serving as a binder has good rheological property, printing adaptability and folding resistance, and the elasticity is good after a film is formed.

Description

technical field [0001] The invention relates to an elastic emulsion for water-based ink and a preparation method thereof, and to a water-based ink using the elastic emulsion. Background technique [0002] Due to its excellent resilience, flexibility, adhesion, weather resistance and other properties, elastic emulsion is widely used in elastic latex paint, elastic putty and elastic coating, especially in the construction field. But it is rarely used in water-based inks. [0003] Rheology is one of the most important basic properties of water-based inks. Rheology plays a major role in the precipitation and aggregation of pigments in water-based inks, printing transferability and leveling and film-forming properties, and the emulsion used as water-based inks directly affects the rheology of water-based inks. Invention Patent Publication No. CN101638452A "High Solid Containing Pure Acrylic Elastic Emulsion", CN1557850A "Preparation Method of Silicone Modified Acrylic Elastic E...

Claims

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Application Information

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IPC IPC(8): C09D11/10C08F220/18C08F212/08C08F222/16C08F220/58C08F2/30C08F2/26C09D11/107
Inventor 刘润林连坤鹏朱力勇赵英华
Owner GUANGDONG YINGKE GRP CO LTD
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