Polyester composite for forming thermoset films
A heat-curing and composition technology, applied in the directions of instruments, optics, nonlinear optics, etc., can solve the problems of low solubility of ester solvents, difficulty in applying planarization film production lines, reduction of planarization and transparency, etc., and achieve high Effects of heat resistance, high solvent resistance, and high planarization
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[0176] The following examples are given to illustrate the present invention in more detail, but the present invention is not limited to these examples.
[0177] [Abbreviated symbols used in Examples]
[0178] The meanings of the abbreviated symbols used in the following examples are as follows.
[0179]
[0180] HBPDA: 3,3'-4,4'-Dicyclohexyltetracarboxylic dianhydride
[0181] THPA: 1,2,5,6-tetrahydrophthalic anhydride
[0182] BPDA: biphenyltetracarboxylic dianhydride
[0183] HBPA: hydrogenated bisphenol A
[0184] BTEAC: Benzyltriethylammonium Chloride
[0185]
[0186] HBPDA: 3,3'-4,4'-Dicyclohexyltetracarboxylic dianhydride
[0187] CBDA: 1,2,4,5-cyclohexanetetracarboxylic dianhydride
[0188] THPA: 1,2,5,6-tetrahydrophthalic anhydride
[0189] DA-4P: 1,3-bis(4-aminophenyl)benzene
[0190] DDS: 4,4'-Diaminodiphenylsulfone
[0191]
[0192] CBDA: 1,2,4,5-cyclohexanetetracarboxylic dianhydride
[0193] pDA: p-phenylenediamine
[0194]
[0195] MAA: methac...
Synthetic example 1
[0211] HBPDA 12.0 g, HBPA 10.2 g, THPA 0.95 g, and BTEAC 0.22 g were reacted in PGMEA 54.48 g at 120° C. for 19 hours to obtain a polyester polymer solution (solid content concentration: 30.0% by mass (P1). The resulting The Mn of the polyester polymer is 2,280, and the Mw is 4,200.
Synthetic example 2
[0213] After dissolving 14.6 g of DA-4P in 40.68 g of DMAc, it was cooled with water and kept at 23°C. 4.90 g of CBDA and 7.60 g of THPA were reacted in this solution at 23 degreeC for 24 hours, and the amino group containing carboxylic acid compound solution (40.0 mass % of solid content concentration) was obtained. (A1)
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