Lithium ion battery cathode and lithium ion battery therewith
A lithium-ion battery and negative electrode technology, which is applied in the field of lithium-ion battery composition, can solve the problems of poor cycle life characteristics of lithium batteries, large changes in battery thickness, and poor adhesion of anode sheets, etc., to ensure long-term cycle performance. Good long-term cycle characteristics and the effect of reducing battery expansion rate
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Embodiment 1
[0025] Negative sheet preparation process
[0026] Negative electrode slurry formula is based on dry material weight percentage, is made up of three parts: 2.5% sodium carboxymethyl cellulose (CMC-Na), 1.5% conductive carbon black, 96% negative electrode active material, wherein negative electrode active material adopts artificial graphite, carboxy Sodium methylcellulose has a number average molecular weight of about 500,000, a 1% aqueous solution viscosity of 150 mPa.s at 25°C, and a degree of substitution of 0.8. During the preparation of the slurry, the solvent is water, and water accounts for 60% of the total slurry.
[0027] First, add water and sodium carboxymethyl cellulose into the stirring grinder according to the above formula, and dissolve completely in a vacuum state, then add conductive carbon black into the dissolved water-based polymer solution according to the formula, and quickly stir and grind Until the fineness is below 5μm, finally add artificial graphite ...
Embodiment 2
[0036] The difference from Example 1 is that: the negative electrode formula contains 97.5% of the negative electrode active material, 1% of sodium carboxymethylcellulose, and 1.5% of conductive carbon black as an electrical conduction aid. Wherein the sodium carboxymethyl cellulose substitution degree that adopts is 1.0, molecular weight 1,000,000, its 1% aqueous solution 25 ℃ viscosity 1200mPa.s, other is identical with embodiment 1, repeats no more here.
Embodiment 3
[0038] The difference from Example 1 is that: the negative electrode formula contains 93.5% of the negative electrode active material, 5% sodium carboxymethyl cellulose, and 1.5% conductive carbon black as an electrical conduction aid. Wherein the sodium carboxymethylcellulose that adopts is 0.6, molecular weight 50,000, its 1% aqueous solution 25 ℃ viscosity 50mPa.s, other is identical with embodiment 1, repeats no more here.
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