Thermal insulating and fireproof board for external wall

A technology of external wall insulation and fireproof board, which is applied in the field of building decoration materials, can solve the problems of low strength, poor heat resistance of phenolic resin, mechanical obstruction of respiratory tract, etc., and achieve the effect of high strength

Active Publication Date: 2012-07-25
CHONGQING YUWANTONG NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyurethane insulation materials also produce a large amount of smoke and dust during the combustion process. After the smoke is inhaled by the human body, it will directly cause mechanical obstruction of the respiratory tract, reduce the effective breathing area of ​​the human lungs, and cause casualties.
[0003] Neither phenolic resin nor boron-modified phenolic resin can meet the requirements of fire protection and heat preservation of building exterior walls. Phenolic resin has poor heat resistance, low strength, high brittleness, poor toughness, and poor flame retardant effect, so it is impossible to be used for External wall insulation
Boron-modified phenolic resin only solves the problem of instantaneous high temperature resistance and reduces the thermal conductivity. The instantaneous high temperature resistance is only 600-700 degrees, and its oxygen index is 37-38, which also fails to meet the requirements of external wall fire insulation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0020] This external wall thermal insulation fireproof board is made by the steps of following order:

[0021] (1) Mix and stir 50Kg phenol, 50Kg diboron trioxide, 50Kg paraformaldehyde and hydrochloric acid, raise the temperature to 60°C, and react for 1 hour to prepare a boron-modified phenolic resin with a pH value of 5.

[0022] (2) Adding 1Kg of nano-sized aluminum oxide and 20Kg of polyphosphate amine to 50Kg of boron-modified phenolic resin to prepare a boron-modified phenolic resin composite material.

[0023] (3) Add 10Kg of perlite to 50Kg of boron-modified phenolic resin composite material and stir evenly.

[0024] (4), add 5Kg of butyronitrile to the mixture obtained in step (3), and stir evenly.

[0025] (5), add 2Kg of phosphoric acid to the mixture obtained in step (4), and stir evenly.

[0026] (6) Add a mixture of 0.8Kg silicone and 1.2Kg sodium dodecylbenzenesulfonate to the mixture obtained in step (5), stir evenly, and add 0.1035 cubic meters of carbon di...

Embodiment approach 2

[0029] This external wall thermal insulation fireproof board is made by the steps of following order:

[0030] (1) Mix and stir 100Kg phenol, 1Kg diboron trioxide, 100Kg paraformaldehyde and sulfuric acid, raise the temperature to 120°C, and react for 6 hours to prepare a boron-modified phenolic resin with a pH value of 6.

[0031] (2) Add 50Kg of nano-sized aluminum oxide and 1Kg of polyphosphate amine to 100Kg of boron-modified phenolic resin to prepare a boron-modified phenolic resin composite material.

[0032] (3) Add 30Kg of light calcium carbonate to 100Kg of boron-modified phenolic resin composite material and stir evenly.

[0033] (4), add 20Kg butylbenzene to the mixture obtained in step (3), and stir evenly.

[0034] (5) Add 10Kg of phosphorous acid or metaphosphoric acid to the mixture obtained in step (4), and stir evenly.

[0035] (6) Add a mixture of 6Kg silicone and 4Kg sodium dodecylbenzenesulfonate to the mixture obtained in step (5), stir evenly, and add 0...

Embodiment approach 3

[0038] This external wall thermal insulation fireproof board is made by the steps of following order:

[0039] (1) Mix and stir 68Kg phenol, 18Kg diboron trioxide, 85Kg paraformaldehyde and nitric acid, raise the temperature to 80°C, and react for 2.5 hours to prepare a boron-modified phenolic resin with a pH value of 5.4.

[0040] (2) Adding 18Kg of nano-sized aluminum oxide and 13Kg of polyphosphate amine into 68Kg of boron-modified phenolic resin to prepare a boron-modified phenolic resin composite material.

[0041] (3) Add 16Kg of mica powder into 68Kg of boron-modified phenolic resin composite material and stir evenly.

[0042] (4) Add 1Kg of modified polyvinyl alcohol fibers to the mixture obtained in step (3), and stir evenly.

[0043] (5) Add 5Kg of benzenesulfonic acid to the mixture obtained in step (4), and stir evenly.

[0044] (6) Add a mixture of 4Kg silicone and 4Kg sodium dodecylbenzenesulfonate to the mixture obtained in step (5), stir evenly, and add 0.205...

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PUM

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Abstract

The invention relates to a thermal insulating and fireproof board for an external wall. The board is prepared by mixing a boron modified phenolic resin composite material with a refractory aggregate, butyronitrile or butylbenzene, inorganic acid or organic acid, a mixture of silicone and sodium dodecyl benzene sulfonate, and a carbon dioxide gas and then curing the materials. With good fireproof and flame resistant performances as well as good thermal insulation property, the thermal insulating and fireproof board for an external wall in the invention also has high strength, and its combustion performance can reach the national A1 grade standard.

Description

technical field [0001] The invention relates to building decoration materials, in particular to a thermal insulation and fireproof board for external walls. Background technique [0002] At present, about 80% of the thermal insulation and decorative panels of building exterior walls are organic combustible materials, including molded polystyrene boards, extruded polystyrene boards and polyurethane foam. The heat distortion temperature of polystyrene board is only 70 degrees Celsius to 98 degrees Celsius, and the glass transition temperature is 100 degrees Celsius. Polystyrene is composed entirely of carbon and hydrogen elements. It is extremely flammable in nature. When burning, the fire spreads quickly, reaching 15 meters per minute. The amount of combustion heat is large, and the amount of smoke is also large. After being exposed to fire, it shrinks and melts. , leading to the generation of cavities in the external insulation system, the burning is violent in the flashove...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L61/14C08L29/04C08L83/04C08K13/02C08K3/22C08K3/32C08K5/42C08G8/28C08G8/10
Inventor 徐小波
Owner CHONGQING YUWANTONG NEW MATERIAL TECH
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