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Preparation method of compound leather bactericidal and mildew-proof agent

A bactericidal antifungal agent, leather technology, applied in the direction of fungicides, biocides, biocides, etc.

Inactive Publication Date: 2012-01-18
覃终
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a kind of preparation of leather composite fungicide and antifungal agent for the various disadvantages of existing fungicide and antifungal agents and for solving the technical problems existing in the known technology, especially with guanidine compound, quaternary ammonium salt Combination of similar compounds, 2-bromo-2-nitro-1,3-propanediol, iodopropynyl butyl carbamate, Torlon B, corrosion inhibitor, ethanol and water as a compound fungicide and antifungal agent for leather The preparation and application of it has the characteristics of safety, high efficiency, broad spectrum, low toxicity and environmental protection.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] components kilogram kg Mass percentage % Polyhexamethyleneguanidine 3 3 Lauryl dimethyl benzyl ammonium chloride 7 7 Torrey B 0.3 0.3 2-Bromo-2-nitro-1,3-propanediol 1 1 95% ethanol 10 10 Butyl iodopropynylcarbamate 0.6 0.6 sodium benzoate 1.5 1.5 sodium salicylate 1.5 1.5 water 75.1 75.1 total 100 100

[0051] 1. Mix polyhexamethyleneguanidine, dodecyldimethylbenzyl ammonium chloride, 2-bromo-2-nitro-1,3-propanediol and Tuoliron B with the above-mentioned mass percentage and the above-mentioned mass percentage 50% of the water was mixed and stirred for 3 hours to prepare mixed substance A;

[0052] 2. Mix butyl iodopropynyl carbamate, sodium benzoate, sodium salicylate, and ethanol with the remaining 50% of the above mass percentage and stir for 3 hours to prepare mixed substance B;

[0053] 3. Stir and react the above mixed substance A with the above mixed substance B for 2 hours, t...

Embodiment 2

[0056] components kilogram kg Mass percentage % Polyhexamethyleneguanidine 4 4 Lauryl dimethyl benzyl ammonium chloride 6 6 Torrey B 0.3 0.3 2-Bromo-2-nitro-1,3-propanediol 1 1 95% ethanol 10 10 Butyl iodopropynylcarbamate 0.6 0.6 sodium benzoate 1 1 sodium salicylate 1 1 water 76.1 76.1 total 100 100

[0057] 1. Mix polyhexamethyleneguanidine, dodecyldimethylbenzyl ammonium chloride, 2-bromo-2-nitro-1,3-propanediol and Tuoliron B with the above-mentioned mass percentage and the above-mentioned mass percentage 50% of the water was mixed and stirred for 3 hours to prepare mixed substance A;

[0058] 2. Mix butyl iodopropynyl carbamate, sodium benzoate, sodium salicylate, and ethanol with the remaining 50% of the above mass percentage and stir for 3 hours to prepare mixed substance B;

[0059] 3. Stir and react the above mixed substance A with the above mixed substance B for 2 hours, then let ...

Embodiment 3

[0062] components kilogram kg Mass percentage % polyhexamethylene biguanide 3 3 Dodecyldimethylethylbenzylammonium chloride 7 7 Torrey B 0.3 0.3 2-Bromo-2-nitro-1,3-propanediol 1 1 95% ethanol 10 10 Butyl iodopropynylcarbamate 0.6 0.6 sodium gluconate 1.5 1.5 sodium salicylate 1.5 1.5 water 75.1 75.1 total 100 100

[0063] 1. Combine polyhexamethylene biguanide, dodecyl dimethyl ethyl benzyl ammonium chloride, 2-bromo-2-nitro-1,3-propanediol and Torlon B with the above-mentioned 50% water by mass percentage was mixed and stirred for 3 hours to be mixed with substance A;

[0064] 2. Mix butyl iodopropynylcarbamate, sodium gluconate, sodium salicylate, and ethanol with the remaining 50% of the above-mentioned mass percentage and stir for 3 hours to prepare a mixed substance B;

[0065] 3. Stir and react the above mixed substance A with the above mixed substance B for 2 hours, then let it stand...

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Abstract

The invention aims to provide a compound leather bactericidal and mildew-proof agent, and in particular provides a preparation method taking the composition of a guanidine compound, a quaternary ammonium compound, 2-bromo-2-nitro-1,3-propanediol, 3-iodo-2-propynyl butylcarbamate, ethylenediaminetetraacetic acid (EDTA) B, a corrosion inhibitor, ethanol and water as the compound leather bactericidal and mildew-proof agent. The compound leather bactericidal and mildew-proof agent comprises the following components by mass percent: 1-6% of guanidine compound, 1-10% of quaternary ammonium compound, 0.05-3% of EDTA B, 0.1-2% of 2-bromo-2-nitro-1,3-propanediol, 1-50% of ethanol, 0.05-5% of 3-iodo-2-propynyl butylcarbamate, 0.1-20% of corrosion inhibitor and the balance of water. The preparation method is characterized by comprising the following steps of: mixing the guanidine compound, the quaternary ammonium compound, the 2-bromo-2-nitro-1,3-propanediol and the EDTA B with 50% of water by mass percent, and stirring the mixture for 3 hours to prepare a mixture A; mixing the 3-iodo-2-propynyl butylcarbamate, the corrosion inhibitor and the ethanol with the residual 50% of water by mass percent, and stirring the mixture for 3 hours to prepare a mixture B; and stirring the mixture A and the mixture B to react for 2 hours, then standing for 2 hours, determining the content of the mixture of the mixture A and the mixture B, and packaging the qualified mixture, thus obtaining a qualified product. The invention also aims to dilute the compound leather bactericidal and mildew-proof agent, and the dilution ratio is 50-500 times.

Description

technical field [0001] The invention belongs to the field of disinfection and sterilization products, and relates to a compound sterilization and anti-mildew preparation of leather, especially a preparation of guanidine compounds, quaternary ammonium salt compounds, 2-bromo-2-nitro-1,3-propanediol, iodine The composition of butyl propynyl carbamate, torilon B, corrosion inhibitor, ethanol and water is used as a compound fungicide and antifungal agent for leather. Background technique [0002] Leather raw materials are rich in nutrients such as protein and fat, which are easily invaded by microorganisms during storage, and are prone to mildew during processing. hotbed. [0003] The porosity and polar structure of the leather structure make it easy to absorb moisture and make the leather acidic. These factors constitute the basic conditions for mildew. Mildewed leather shows white, blue and black colonies and stains. The mold on the surface will develop into the interior of ...

Claims

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Application Information

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IPC IPC(8): A01N47/44A01N47/12A01N37/44A01N33/20A01N33/12A01P1/00A01P3/00
Inventor 李新建
Owner 覃终
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