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Microporous photocatalyst bamboo charcoal polyester modified short fiber and preparation method thereof

A bamboo charcoal polyester and polyester modification technology, which is applied in the field of spinning, can solve the problems of insufficient moisture absorption effect, reduced efficacy, and can not be used continuously, and achieves the effects of strong adsorption, decomposition, sterilization, and strong absorption.

Active Publication Date: 2011-09-07
绍兴上虞弘强纺织新型材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In recent years, fiber manufacturers in developed countries, Japan, South Korea and Taiwan have achieved results in the research and development of functional textiles. Common functional fibers include fibers with relatively single functions such as moisture absorption and quick drying, antibacterial, anti-ultraviolet, far-infrared, and bamboo charcoal. Clearly smart fibers are still rare
The use effect is not very ideal. For example, the cross-shaped moisture-absorbing and quick-drying fiber often does not meet the relevant standards of INVISTA. It needs to be supplemented with hydrophilic treatment, but the washability after treatment is not durable; another example is bamboo charcoal. Fiber has strong functions of deodorization and adsorption of harmful microorganisms, but it will fail after a certain period of time and cannot be used continuously; most functional micropowders (such as antibacterial agents, bamboo charcoal micropowders, titanium dioxide micropowders, ceramic micropowders) are coated in chemical fiber The carrier is isolated from the outside world, unable to function and only the surface layer of fine powder plays a role, resulting in reduced efficacy and increased cost; most functional fibers with conventional polyester as the carrier have always had bottlenecks and local forbidden areas in the field of color spinning; the above problems Existence, it is necessary to develop a new generation of functional fibers and environmentally friendly fibers with higher efficiency, lower cost and wider application

Method used

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  • Microporous photocatalyst bamboo charcoal polyester modified short fiber and preparation method thereof
  • Microporous photocatalyst bamboo charcoal polyester modified short fiber and preparation method thereof
  • Microporous photocatalyst bamboo charcoal polyester modified short fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0076] 1. A method for producing polyester modified slices with a preliminary microporous structure tendency, comprising the following steps:

[0077] 1) First, purify terephthalic acid, ethylene glycol, polyethylene glycol, dimethyl isophthalate-5-sodium sulfonate and ethylene glycol antimony and triphenyl phosphate Fully mix and slurry in the slurry tank;

[0078] 2) Next, the mixed slurry is introduced into an esterification kettle for esterification reaction, and the esterification temperature is controlled at 260°C;

[0079] 3) again, in the polycondensation kettle, polyoxyethylene glycol and dimethyl isophthalate-5-sodium sulfonate and esterification reaction gained oligomer bishydroxyethyl terephthalate carry out reaction polycondensation and obtain a kind of having preliminary Polyester modified stock solution slurry with microporous structure trend, in which the polycondensation reaction temperature is 290°C, and the vacuum degree is 75Pa;

[0080] 4) Finally, extru...

Embodiment 2

[0129] 1. A method for producing polyester modified slices with a preliminary microporous structure tendency, comprising the following steps:

[0130] 1) First, purify terephthalic acid, ethylene glycol, polyethylene glycol, dimethyl isophthalate-5-sodium sulfonate and ethylene glycol antimony and triphenyl phosphate are mixed according to the following parts by weight ratio Fully mix and slurry in the slurry tank;

[0131] 2) Next, the mixed slurry is introduced into an esterification kettle for esterification reaction, and the esterification temperature is controlled at 200°C;

[0132] 3) again, in the polycondensation kettle, polyoxyethylene glycol and dimethyl isophthalate-5-sodium sulfonate and esterification reaction gained oligomer bishydroxyethyl terephthalate carry out reaction polycondensation and obtain a kind of having preliminary Polyester modified stock solution slurry with microporous structure trend, wherein the polycondensation reaction temperature is 245°C, ...

Embodiment 3

[0181] 1. A method for producing polyester modified slices with a preliminary microporous structure tendency, comprising the following steps:

[0182] 1) First, purify terephthalic acid, ethylene glycol, polyethylene glycol, dimethyl isophthalate-5-sodium sulfonate and ethylene glycol antimony and triphenyl phosphate are mixed according to the following parts by weight ratio Fully mix and slurry in the slurry tank;

[0183] 2) Next, the mixed slurry is introduced into an esterification kettle for esterification reaction, and the esterification temperature is controlled at 280°C;

[0184] 3) again, in the polycondensation kettle, polyoxyethylene glycol and dimethyl isophthalate-5-sodium sulfonate and esterification reaction gained oligomer bishydroxyethyl terephthalate carry out reaction polycondensation and obtain a kind of having preliminary Polyester modified stock solution slurry with microporous structure trend, wherein the polycondensation reaction temperature is 300°C, ...

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Abstract

The invention belongs to the spinning field, and relates to a microporous photocatalyst bamboo charcoal polyester modified short fiber and preparation thereof. For the microporous photocatalyst bamboo charcoal polyester modified short fiber, the surfaces and the inside have irregular microporous structures, all micropores penetrate through each other, photocatalyst compound micro powder and bamboo charcoal micro powder are uniformly distributed on the external surfaces, surface layers and insides of the whole short fiber as well as the surface and inside of each micropore, and the photocatalyst compound micro powder and the bamboo charcoal micro powder respectively account for 1.05-1.35wt% and 1.8-2.6wt% of the short fiber. The fiber provided by the invention is an environment-friendly one which has the functions of harmful gas and harmful microorganism absorption, bacterium resistance, mould proofing, deodorization, far infrared wave transmission, moisture absorption, quick drying and the like. Under the irradiation of light rays, the absorbed harmful gas and harmful microorganisms can be decomposed into carbon dioxide and water, thus the functions of purifying the air and cleaning the environment are achieved. Under the condition of illumination, the short fiber can be circularly and continuously used and can play corresponding roles.

Description

technical field [0001] The invention belongs to the field of spinning, and relates to a functional fiber product, in particular to a functional environment-friendly polyester modified staple fiber (microporous photocatalyst bamboo charcoal polyester modified staple fiber) and a preparation method thereof. Background technique [0002] Modern consumers' demand for clothing and home decorations is not only focused on fashion, but also on functionality. Comfortable, safe and healthy clothing that is also environmentally friendly has become a consumption trend. [0003] In recent years, fiber manufacturers in developed countries, Japan, South Korea and Taiwan have achieved results in the research and development of functional textiles. Common functional fibers include fibers with relatively single functions such as moisture absorption and quick drying, antibacterial, anti-ultraviolet, far-infrared, and bamboo charcoal. Clearly smart fibers are rare. The use effect is not very i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F1/10D01D1/00D01D5/08D01D5/247C08G63/688
Inventor 谢建强
Owner 绍兴上虞弘强纺织新型材料有限公司
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