Electrochemical polymerization process for forming solid electrolyte layer on solid electrolytic capacitor
A solid electrolyte layer, solid electrolysis technology, applied in capacitor electrolyte/absorbent, capacitor parts and other directions, can solve the problem that the performance of solid electrolytic capacitors cannot meet expectations, the conductivity of the conductive layer cannot be controlled, and the pH value range is not limited, etc. The problem is that the pH value control and adjustment method is simple, the properties are controllable, and the operation is simple.
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Embodiment 1
[0019] After the 13VF aluminum foil (effective area 3.5mm×4.0mm) containing alumina was prepared by chemical polymerization for the first solid electrolyte layer polypyrrole, the electrochemical polymerization process was carried out, specifically, the aluminum foil containing the first solid electrolyte layer polypyrrole was combined with The external electrode is connected as the anode, and the conductive electrode such as stainless steel is used as the cathode, and the constant current polymerization is carried out in a mixed solution containing 0.4M Py (pyrrole monomer) and 0.3M p-toluenesulfonate at 5°C. Add p-toluenesulfonic acid regularly to control the pH value of the solution at 3.5±0.1, and the current density is 3mA / cm 2 , the time is 90 minutes, and then washed and dried to obtain the second solid electrolyte layer polypyrrole. After the electrochemical polymerization process is completed, a carbon-containing cathode layer and a silver-containing cathode layer are ...
Embodiment 2
[0021] The difference from Example 1 is that the pH value of the solution is controlled at 4.0±0.1 by adding p-toluenesulfonic acid regularly.
Embodiment 3
[0023] The difference from Example 1 is that the pH value of the solution is controlled at 4.5±0.1 by adding p-toluenesulfonic acid regularly.
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