Porous ultra-low dielectric constant material film and preparation method thereof
A low dielectric constant, material thin film technology, applied in circuits, electrical components, electrical solid devices, etc., can solve the problem of not meeting the requirements of k value, and achieve ultra-low dielectric constant, good controllability, and simple process. Effect
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[0023] 1. Add CH 3 Si(OEt) 3 and (EtO) 3 Si-CH 2 -CH 2 -Si(OEt) 3 Mix and stir until well blended, P 123 , the mixture of hydrochloric acid, ethanol and water was stirred evenly, then added to the mixture of the precursor, and stirred in a water bath at 60° C. for 2 hours. The molar ratio of the above components in sample I is: CH 3 Si(OEt):(EtO) 3 Si-CH 2 -CH 2 -Si(OEt) 3 :P 123 :HCl:H 2 O:EtOH=0.25:0.375:1.23×10 -2 : 1.80×10 -2 :20:13.9. The molar ratio of the above components in sample II is: CH 3 Si(OEt):(EtO) 3 Si-CH 2 -CH 2 -Si(OEt) 3 :P123:HCl:H 2 O:EtOH=0.25:0.375:1.23×10 -2 : 1.80×10 -2 :20:14.37.
[0024] 2. Spin-coat the above-mentioned film-forming solution on a clean silicon wafer as a substrate at 25°C to form a film. The spin-coating step is as follows: first, spin at 800 rpm for 10 seconds, and then accelerate to 2000 rpm for 20 seconds. Let stand for 30-60 minutes before use.
[0025] 3. Place the above-mentioned films I and II in an ...
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