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Special compound additive for polyethylene film with high tranparency and low density

A technology of low-density polyethylene and compounding additives, applied in the field of special compounding additives, can solve the hidden dangers of film physiological safety, film products are easy to stick to each other, fish eyes, and high turbidity, and achieve good physiological safety, high Safety and smoothness

Active Publication Date: 2010-06-02
南京淳达科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, no matter what kind of plastic resin products are used, the film products are very easy to stick to each other. Adding conventional anti-blocking agents will cause fish eyes, high turbidity, and decreased transparency, which will directly affect its application and effect.
Some of the additives use amines, aromatic components, etc., which pose a physiological safety hazard to films used for food and pharmaceutical packaging.

Method used

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  • Special compound additive for polyethylene film with high tranparency and low density
  • Special compound additive for polyethylene film with high tranparency and low density
  • Special compound additive for polyethylene film with high tranparency and low density

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] 1. Put each auxiliary agent of the present invention into a cantilever double-helix conical mixer according to the following weight ratio for premixing and coarse dispersion:

[0043] High-efficiency opening agent: 28

[0044] Silicone glidants: 12

[0045] Silicone reactive crosslinker: 5

[0046] Silicone antioxidant: 8

[0047] High pressure polyethylene carrier resin: 47

[0048] The operating speed of the cantilever double-helix conical mixer is 40-50 revolutions per minute, and the mixer is stirred for 60 minutes.

[0049] 2. Put the pre-mixed raw materials into a horizontal ball mill with a rotation speed of 45-50 revolutions per minute and a temperature of 80°C to preheat the raw materials for chemical bonding and refinement dispersion.

[0050]3. Put the above-mentioned finely dispersed raw materials into a twin-screw granulator, extrude and granulate at a flow rate of 200kg / hour at a temperature of 140°C-170°C to obtain the compound additive granules of th...

Embodiment 2

[0052] The weight ratio of each component is as follows:

[0053] High-efficiency opening agent: 30

[0054] Silicone glidants: 13

[0055] Silicone reactive crosslinker: 6

[0056] Silicone antioxidant: 8

[0057] High pressure polyethylene carrier resin: 43

[0058] Operate the above-mentioned mixture according to the process conditions of Example 1, and finally extrude and granulate to obtain the additive granules of the present invention.

Embodiment 3

[0060] Put each component of the present invention into the cantilever double-helix conical mixer according to the following weight ratio for premixing and coarse dispersion:

[0061] High-efficiency opening agent: 20

[0062] Silicone glidants: 6

[0063] Silicone reactive crosslinker: 4

[0064] Silicone antioxidant: 8

[0065] High pressure polyethylene carrier resin: 62

[0066] Other operation production technology is with embodiment 1.

[0067] The relevant physical indicators of the three compound additives are shown in Table 1.

[0068] Table 1

[0069]

[0070] Add the composite additives of the above three examples into the low-density polyethylene resin respectively at 2.5‰ (weight), and test the obtained high-pressure polyethylene product data as shown in Table 2.

[0071] Table 2

[0072]

[0073]

[0074] The film was left for half a month and no oily, hoarfrost and other phenomena were found. There is no difference in smoothness between the film...

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Abstract

The invention relates to a special compound additive for a polyethylene film with high tranparency and low density, which is a particle prepared by the following steps of: stirring and mixing 25-30 percent of silicon dioxide anti-block agent, 5-15 percent of organic silicon glidant, 2-8 percent of organic silicon active crosslinking agent, 1-10 percent of organic silicon antioxidant and the balance of high pressure polyethylene resin by taking high-pressure polyethylene as a carrier; carrying out treatments including preheating, ball milling and dispersing at the temperature of 75-85 DEG C; and finally, extruding pelletization through a twin-screw granulator at the temperature of 140-170 DEG C. The low density polyethylene film prepared by adding the compound additive is tasteless, has high transparency, favorable physiological safety, high anti-blocking property, favorable smoothness and favorable transference resistance and can be particularly used for fields including food covering films, drug covering films, business card covering films, identification card covering films, advertisement packaging and the like which have the requirements of high transparency, high safety and high anti-blocking property.

Description

technical field [0001] The invention relates to a special composite auxiliary agent used in the production of high transparency and low density polyethylene film. Background technique [0002] Low-density polyethylene (LDPE), also known as high-pressure polyethylene, is a high-quality material for packaging films. It is widely used in the packaging of food, medicine and daily necessities. It is a thermoplastic obtained by ethylene radical polymerization under high pressure. It is made of LDPE. The film exhibits good optical properties, strength, flexibility, sealing, transparency, chemical inertness, etc., and is easy to form and process, which determines that LDPE is one of the most widely used materials in the polymer industry today. However, no matter what kind of plastic resin products are used, film products are very easy to stick to each other. Adding conventional anti-blocking agents will cause fish eyes, high turbidity, and decreased transparency, which will directly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L83/04C08K3/36B29B9/06
Inventor 彭令才
Owner 南京淳达科技发展有限公司
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