High performance polycarboxylic acid type concrete water reducing agent and preparation method thereof
A technology of concrete water reducing agent and polycarboxylic acid series, applied in the field of chemical preparations for building materials, can solve the problems of immature preparation method and mechanism, inability to fully reflect water reducing performance, and large amount of water reducing agent, achieving significant economical Benefits and social benefits, easy control of reaction materials, non-corrosion effect on equipment
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Embodiment 1
[0035] Raw materials for esterification:
[0036] 79.00% polyethylene glycol monomethyl ether,
[0037] 17.50% methacrylic acid,
[0038] 0.17% hydroquinone,
[0039] 3.33% p-toluenesulfonic acid;
[0040] Copolymerization raw materials:
[0041] 86.00% polyethylene glycol monomethacrylate,
[0042] 0.80% acrylamide,
[0043] 10.80% maleic anhydride,
[0044] 0.44% mercaptoethanol,
[0045] 1.13% ammonium persulfate,
[0046] 0.81% hydrogen peroxide,
[0047] 0.01% defoamer,
[0048] 0.01% sodium bicarbonate.
[0049] Preparation:
[0050] Put polyethylene glycol monomethyl ether in the reactor, add hydroquinone at the same time, raise the temperature to 90°C to fully dissolve hydroquinone in the polyethylene glycol monomethyl ether solution to form a slightly yellow solution, weigh 1 / 2 The formula quantity of p-toluenesulfonic acid is dissolved in methacrylic acid and added dropwise to the reactor with stirring device; then the temperature is raised to 105°C and ke...
Embodiment 2
[0052] Raw materials for esterification:
[0053] 78.90% polyethylene glycol monomethyl ether,
[0054] 17.60% methacrylic acid,
[0055] 0.25% Hydroquinone,
[0056] 3.25% p-toluenesulfonic acid;
[0057] Copolymerization raw materials:
[0058] 77.90% polyethylene glycol monomethacrylate,
[0059] 0.80% acrylamide,
[0060] 18.20% maleic anhydride,
[0061] 0.44% mercaptoethanol,
[0062] 1.32% ammonium persulfate,
[0063] 1.32% hydrogen peroxide,
[0064] 0.01% defoamer,
[0065] 0.01% sodium bicarbonate.
[0066] Preparation:
[0067] Put polyethylene glycol monomethyl ether in the reactor, add hydroquinone at the same time, raise the temperature to 95°C to fully dissolve hydroquinone in the polyethylene glycol monomethyl ether solution to form a slightly yellow solution, weigh 1 / 2 The formula quantity of p-toluenesulfonic acid is dissolved in methacrylic acid and added dropwise to the reactor with stirring device; then the temperature is raised to 105°C and ...
Embodiment 3
[0069] Raw materials for esterification:
[0070] 79.50% polyethylene glycol monomethyl ether,
[0071] 17.00% methacrylic acid,
[0072] 0.19% Hydroquinone,
[0073] 3.31% p-toluenesulfonic acid,
[0074] Copolymerization raw materials:
[0075] 85.50% polyethylene glycol monomethacrylate,
[0076] 0.80% acrylamide,
[0077] 10.70% maleic anhydride,
[0078] 0.43% mercaptoethanol,
[0079] 1.52% ammonium persulfate,
[0080] 1.03% hydrogen peroxide,
[0081] 0.01% defoamer,
[0082] 0.01% sodium bicarbonate.
[0083] Preparation:
[0084] Put polyethylene glycol monomethyl ether in the reactor, add hydroquinone at the same time, raise the temperature to 90°C to fully dissolve hydroquinone in the polyethylene glycol monomethyl ether solution to form a slightly yellow solution, weigh 1 / 2 The formula quantity of p-toluenesulfonic acid is dissolved in methacrylic acid and added dropwise to the reactor with stirring device; then the temperature is raised to 105°C and ...
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