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High-chromium cast iron composite inoculant, preparation method and application thereof

A composite inoculant and high-chromium cast iron technology, which is applied in the field of chromium-containing cast iron alloys, can solve the problem that the comprehensive mechanical properties of high-chromium cast iron alloys cannot be effectively improved, and the crystal grain and structure refinement effect of the cast iron alloy matrix is ​​not ideal, etc. problem, to achieve the effect of matrix grain refinement, increase interface energy, strength and toughness

Active Publication Date: 2009-11-18
TIANJIN LIXINSHENG ADVANCED CASTING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The preparation methods of the inoculants reported in the above-mentioned documents are all produced by traditional processes such as crushing and mixing. The application of these inoculants in cast iron alloy casting is smelted by ordinary smelting processes and the ingots are crushed into small pieces for use. The grain size of the refiner is far from nanoscale, so the refinement effect on the grain and structure of the cast iron alloy matrix is ​​not ideal
Practice has proved that the inoculants produced by these traditional processes are used to refine the grain and structure of the high-chromium cast iron alloy. In the as-cast structure of the refined high-chromium cast iron alloy, the eutectic ledeburite structure The cementite phase is still in a relatively coarse sheet shape, and the comprehensive mechanical properties of high-chromium cast iron alloys cannot be effectively improved.

Method used

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  • High-chromium cast iron composite inoculant, preparation method and application thereof
  • High-chromium cast iron composite inoculant, preparation method and application thereof
  • High-chromium cast iron composite inoculant, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Weigh 1000 grams of commercially available Fe-Ce-Si-Ca master alloy and 100 grams of commercially available Fe-B master alloy, break them into small pieces, put them into the water-cooled copper crucible of the vacuum quenching furnace, and adjust the electrode position , so that the distance between it and the raw material alloy particles in the crucible is 0.5mm, close the furnace door, the inlet and outlet and the air release valve, and vacuumize to a temperature higher than 5×10 -3 Pa, wash the furnace with argon, then fill it with argon to 0.04Pa, adjust the arc current to gradually increase to 500A after arcing, melt the raw material alloy in the crucible, and when the alloy is completely melted into a liquid state, tilt the crucible so that The alloy liquid is led to the high-speed rotating water-cooled molybdenum wheel through the flow channel. The edge speed of the molybdenum wheel is 30m / s, and the surface temperature of the molybdenum wheel is 10°C. After cont...

Embodiment 2

[0042] Take by weighing 1200 grams of commercially available Fe-Ce-Si-Ca master alloy and 84 grams of commercially available Fe-B master alloy with embodiment 1, they are broken into fritters, put into the water-cooled copper crucible of vacuum quenching furnace , adjust the position of the electrode so that the distance between it and the raw material alloy particles in the crucible is 1.0 mm, close the furnace door, the inlet and outlet, and the air release valve, and evacuate to a temperature higher than 5×10 -3 After Pa, wash the furnace with argon gas, then fill it with argon gas to 0.045Pa, adjust the arc current to gradually increase to 550A after arcing, melt the raw material alloy in the crucible, and when the alloy is completely melted into a liquid state, tilt the crucible so that The alloy liquid is led to the high-speed rotating water-cooled molybdenum wheel through the flow channel. The edge speed of the molybdenum wheel is 35m / s, and the surface temperature of th...

Embodiment 3

[0044] Take by weighing 1100 grams of commercially available Fe-Ce-Si-Ca master alloys and 143 grams of commercially available Fe-B master alloys in Example 1, they are broken into fritters, and put into the water-cooled copper crucible of the vacuum quenching furnace , adjust the position of the electrode so that the distance between it and the raw material alloy particles in the crucible is 1.5 mm, close the furnace door, the inlet and outlet, and the air release valve, and evacuate to a temperature higher than 5×10 -3 Pa, wash the furnace with argon, then fill it with argon to 0.05Pa, adjust the arc current to gradually increase to 600A after arcing, melt the raw material alloy in the crucible, and when the alloy is completely melted into a liquid state, tilt the crucible so that The alloy liquid is led to the high-speed rotating water-cooled molybdenum wheel through the flow channel. The edge speed of the molybdenum wheel is 40m / s, and the surface temperature of the molybde...

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Abstract

The invention relates to a high-chromium cast iron composite inoculant, a preparation method and an application thereof, in particular to cast iron alloy containing chromium. The high-chromium cast iron composite inoculant is a nanocrystalline high-chromium cast iron composite inoculant containing rare-earth ferrosilicon and ferroboron. The high-chromium cast iron composite inoculant comprises Fe-Ce-Si-Ca intermediate alloy and Fe-B intermediate alloy, wherein the weight ratio between the Fe-Ce-Si-Ca intermediate alloy and the Fe-B intermediate alloy is 1:0.07-0.13. The nanocrystalline crystal grains of the inoculant are less than 100nm, the inoculant is a flaky inoculant obtained by carrying out melt fast-quenching processing on raw materials which comprise commercially purchased rare-earth ferrosilicon and commercially purchased ferroboron, the inoculant is used for carrying out crystal grain and tissue refining processing on the tissue of the high-chromium cast iron alloy of high-chromium cast iron wear parts used for engineering machinery, the processing method is a metal melt casting method, the casting defect of the existing casting technology of the high-chromium cast iron alloy is overcame, and matrix crystal grains and cementite phases are obviously refined, so that the overall mechanical properties of the high-chromium cast iron alloy are obviously improved.

Description

technical field [0001] The technical scheme of the invention relates to a chromium-containing cast iron alloy, in particular to a high-chromium cast iron composite inoculant and its preparation method and application. Background technique [0002] With the continuous development of construction machinery such as paver, cement asphalt mixing plant, crusher, brick making machine and coal washing machine, the demand for high chromium cast iron wear parts such as blade liners, blades, and knife angles of various types The mechanical properties put forward more and more stringent requirements. Relevant scholars and technicians have done some experimental research on how to improve the mechanical properties and wear and corrosion resistance of high chromium cast iron wear parts for construction machinery. In the as-cast structure of general high-chromium cast iron alloys, the grains of the matrix structure are relatively coarse, the cementite phase in the eutectic ledeburite stru...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C35/00C22C1/03C22C37/10C22C33/08B22D1/00
Inventor 崔春翔石卫东郝福林刘清信杨月明鲍中路
Owner TIANJIN LIXINSHENG ADVANCED CASTING
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