Electrolyte for dye-sensitized solar cell and preparation method thereof
A technology for solar cells and dye sensitization, which is applied in the field of electrolytes for dye-sensitized solar cells, can solve the problems of increased packaging difficulty, back electrode damage, and unsuitability for large-scale production, and meets industrial production, low volatility, good The effect of long-term stability
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Embodiment 1
[0032] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:
[0033] (1) Mix 1-ethyl-3-methylimidazole bistrifluoromethanesulfonimide salt and 1-propyl-3-methylimidazole iodide salt in a volume ratio of 1:1 to obtain liquid imidazole Salt ionic liquid.
[0034] (2) Add elemental iodine, lithium iodide and 4-tert-butylpyridine to the ionic liquid at a ratio of 1:10:0.5 in a molar ratio of iodine: iodide anion: 4-tert-butylpyridine, and stir at room temperature for 30 minutes , to obtain the mixed solution A component after completely dissolving; the concentration of iodine simple substance in the mixed solution A component is 0.01mol / L.
[0035] (3) Then add component B to component A according to the mass ratio of component A: component B is 17:2, and ultrasonically treat for 0.5 hours until the system is uniform to obtain a mixture; component B is nano-titanium dioxide.
[0036] (4) Add component C to the mixture obtained ...
Embodiment 2
[0046] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:
[0047](1) Iodine element and N-methyl ratio benzimidazole are added to 1-propyl-3-methylimidazole iodized salt solution in a ratio of 1:0.3 by iodine element: N-methyl ratio benzimidazole molar ratio , stirred at room temperature for 20 minutes, until completely dissolved to obtain component A of the mixed solution; the concentration of elemental iodine in the component A of the mixed solution was 0.1mol / L;
[0048] (2) Add component B to component A in the ratio of 10:1 by mass ratio of component A: component B, and ultrasonically treat for 1 hour until the system is uniform to obtain a mixture; the component B is nano-dioxide silicon.
[0049] (3) Add component C to the mixture obtained in step (2) according to the mass ratio of component A: component C in a ratio of 10:1, then stir at 80°C for 2 hours, and cool naturally to room temperature to obtain the obtain...
Embodiment 3
[0059] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:
[0060] (1) by elemental iodine: iodide negative ion: the mol ratio of guanidinium thiocyanate is that the mol ratio of elemental iodine, mass ratio is that 1: 1 mixture of potassium iodide and sodium iodide, guanidinium thiocyanate are added to In the 1-ethyl-3-methylimidazole thiocyanate solution, stir at room temperature for 60 minutes until completely dissolved to obtain component A of the mixed solution; the concentration of iodine in component A of the mixed solution is 0.05mol / L ;
[0061] (3) Add component B and component C to component A at the same time according to the mass ratio of component A: component B: component C at the ratio of 13:1:2, and then stir at 60°C for 2 hours , naturally cooled to room temperature to obtain the required electrolyte; the B component is polyethylene glycol, and the C component is triton.
[0062] Obtain a kind of electro...
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