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Electrolyte for dye-sensitized solar cell and preparation method thereof

A technology for solar cells and dye sensitization, which is applied in the field of electrolytes for dye-sensitized solar cells, can solve the problems of increased packaging difficulty, back electrode damage, and unsuitability for large-scale production, and meets industrial production, low volatility, good The effect of long-term stability

Inactive Publication Date: 2009-11-04
IRICO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The problems of this method are: the punching process is easy to cause damage to the back electrode coated with the metal layer, thereby affecting the performance of the battery; the cycle process will cause a considerable amount of waste of electrolyte; the battery needs to be packaged twice, which increases the difficulty of packaging; Complicated operation, not suitable for mass production
As people's requirements for the practical application of DSC batteries have been put forward, researchers have begun to use screen printing to prepare nano-oxide photoanodes and metal back electrodes, but research on screen-printed electrolytes has not been reported yet.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:

[0033] (1) Mix 1-ethyl-3-methylimidazole bistrifluoromethanesulfonimide salt and 1-propyl-3-methylimidazole iodide salt in a volume ratio of 1:1 to obtain liquid imidazole Salt ionic liquid.

[0034] (2) Add elemental iodine, lithium iodide and 4-tert-butylpyridine to the ionic liquid at a ratio of 1:10:0.5 in a molar ratio of iodine: iodide anion: 4-tert-butylpyridine, and stir at room temperature for 30 minutes , to obtain the mixed solution A component after completely dissolving; the concentration of iodine simple substance in the mixed solution A component is 0.01mol / L.

[0035] (3) Then add component B to component A according to the mass ratio of component A: component B is 17:2, and ultrasonically treat for 0.5 hours until the system is uniform to obtain a mixture; component B is nano-titanium dioxide.

[0036] (4) Add component C to the mixture obtained ...

Embodiment 2

[0046] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:

[0047](1) Iodine element and N-methyl ratio benzimidazole are added to 1-propyl-3-methylimidazole iodized salt solution in a ratio of 1:0.3 by iodine element: N-methyl ratio benzimidazole molar ratio , stirred at room temperature for 20 minutes, until completely dissolved to obtain component A of the mixed solution; the concentration of elemental iodine in the component A of the mixed solution was 0.1mol / L;

[0048] (2) Add component B to component A in the ratio of 10:1 by mass ratio of component A: component B, and ultrasonically treat for 1 hour until the system is uniform to obtain a mixture; the component B is nano-dioxide silicon.

[0049] (3) Add component C to the mixture obtained in step (2) according to the mass ratio of component A: component C in a ratio of 10:1, then stir at 80°C for 2 hours, and cool naturally to room temperature to obtain the obtain...

Embodiment 3

[0059] A preparation method for an electrolyte for a dye-sensitized solar cell, comprising the following steps:

[0060] (1) by elemental iodine: iodide negative ion: the mol ratio of guanidinium thiocyanate is that the mol ratio of elemental iodine, mass ratio is that 1: 1 mixture of potassium iodide and sodium iodide, guanidinium thiocyanate are added to In the 1-ethyl-3-methylimidazole thiocyanate solution, stir at room temperature for 60 minutes until completely dissolved to obtain component A of the mixed solution; the concentration of iodine in component A of the mixed solution is 0.05mol / L ;

[0061] (3) Add component B and component C to component A at the same time according to the mass ratio of component A: component B: component C at the ratio of 13:1:2, and then stir at 60°C for 2 hours , naturally cooled to room temperature to obtain the required electrolyte; the B component is polyethylene glycol, and the C component is triton.

[0062] Obtain a kind of electro...

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PUM

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Abstract

The invention relates to electrolyte for a cell, in particular to electrolyte for a dye-sensitized solar cell. The electrolyte comprises a composition A, a composition B and a composition C, wherein the mass ratio of the composition A to the composition B to the composition C is 2-17:1-2:1-2; the composition A is a mixed solution formed by a redox couple, an additive which is chelated with a photo anode, and an ionic liquid; the redox couple comprises elementary iodine; the ionic liquid is an imidazole salt ionic liquid which is in the liquid state at room temperature; the molar ratio of the elementary iodine to the additive is 1:0.2-2; the concentration of the elementary iodine in the composition A of the mixed solution is between 0.01 and 1 mol / L; the composition B is an adhesive for increasing the viscosity of a system; and the composition C is a viscosity regulator for regulating the leveling property of the system under the condition of silk-screen printing. The invention has the advantages that the electrolyte system has small volatility and good long-term stability, and can perform silk-screen printing and meet the requirements of industrialized production.

Description

1. Technical field: [0001] The invention relates to a battery electrolyte, in particular to an electrolyte for a dye-sensitized solar battery. 2. Background technology: [0002] With the increasing severity of the global energy crisis, people are eager to find a sustainable clean energy source. Solar energy, as an inexhaustible natural energy source, has increasingly attracted the attention of countries all over the world. Among them, the material-sensitized solar cell (DSC cell) is considered to be the representative of the third-generation solar cell because of its low cost and wide application. [0003] Electrolyte is one of the core parts of dye-sensitized solar cells, and the composition of the electrolyte greatly affects the photoelectric performance and long-term stability of the cells. Traditional organic liquid electrolytes are highly volatile, and batteries prepared with them are difficult to seal. Long-term use will cause problems such as electrolyte leakage and...

Claims

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Application Information

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IPC IPC(8): H01G9/20H01M14/00H01L51/42H01L51/48
CPCY02E10/542Y02E10/549Y02P70/50
Inventor 李德娜汪志华
Owner IRICO
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