Base metal nickel internal electrode slurry of microwave multiple-layer sheet ceramic capacitor

A multi-layer chip ceramic, internal electrode technology, applied in the direction of fixed capacitor electrodes, fixed capacitor parts, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problem of microwave multilayer ceramic capacitor dielectric layers. Micro-cracks, stress of difficult metal parts and ceramic body parts, and internal stress exist for a long time, so as to reduce the generation of micro-cracks, reduce internal stress, and reduce production costs.

Inactive Publication Date: 2009-10-28
广州三则电子材料有限公司
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  • Application Information

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Problems solved by technology

[0007] The above three Chinese patent applications all focus on solving the problem of layer cracking between layers, but they cannot effectively solve the problem of microcracks in the dielectric layer caused by the internal stress of microwave multilayer ceramic capacitors (non-layer cracking)
In fact, although the problem of cracking between layers has been solved, the more difficult stress problem of metal parts and ceramic body parts still needs to be solved in depth
This volume change caused by the phase change will inevitably lead to the long-term existence of internal stress, resulting in the generation of microcracks in the dielectric layer.
Judging from the above three patent formulas, this deeper problem and difficulty have not been considered.

Method used

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  • Base metal nickel internal electrode slurry of microwave multiple-layer sheet ceramic capacitor
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Embodiment approach

[0022] An implementation method in the method for preparing the electrode slurry of the present invention is introduced below, comprising the following steps:

[0023] ①Heat 2-6% ethyl cellulose and 15%-20% dihydroterpineol at 68°C for 60 minutes and stir twice during the process to fully dissolve it to obtain organic carrier A;

[0024] ②The high-crystallinity nano-nickel powder and the yttria-stabilized nano-zirconia powder are fully stirred and mixed according to the proportion to obtain the mixture B;

[0025] ③ Adding dihydroterpineol accounting for 8-12% of the total amount and an organic carrier accounting for 20% of organic carrier A to mixture B, fully stirring and mixing to obtain mixture C;

[0026] 4. Roll the mixture C 3 times in a three-roll pulper, then add an organic carrier that occupies 80% of the organic carrier A and dihydroterpineol accounting for 15-20% of the total amount, and then grind it again in a three-roll pulper. Press twice to obtain the base me...

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Abstract

The invention relates to base metal nickel internal electrode slurry of a microwave multiple-layer sheet ceramic capacitor, which comprises 40 to 50 of high-crystallinity nanometer nickel powder, 2 to 10 of yttrium oxide stable zirconia nanometer powder bodies and 40 to 58 of organic carriers according to the weight percentage, wherein the organic carriers comprise 2 percent to 6 percent of cellulosic resin and 38 percent to 52 percent of dihydroterpineol. Aiming at the stress problem of a metal part and a ceramic part of the microwave multiple-layer sheet ceramic capacitor, the invention can reduce the volume change caused by the phase change to reduce the internal stress, microcracks of a dielectric layer are reduced to increase the reliability of the microwave ceramic capacitor, and consequently, the microwave multiple-layer sheet ceramic capacitor can also use a base metal nickel electrode technology to replace the prior silver palladium noble metal technology. The invention saves social resources, greatly reduces the production cost and quickly realizes the industrialization.

Description

technical field [0001] The invention relates to a base metal nickel internal electrode slurry, in particular to a slurry using high crystallization nano-nickel powder and yttria-stabilized nano-zirconia powder as raw materials for making microwave multilayer chip ceramic capacitors. Background technique [0002] Traditional electronic pastes are generally conductive silver pastes, conductive palladium pastes, conductive gold pastes, resistive pastes and other precious metal pastes. However, in the past ten years, the low-cost base metal nickel conductive paste has developed rapidly, and its main application field is multilayer chip ceramic capacitors. With the miniaturization of the whole machine and the rapid increase of mobile electronic equipment, the development of multilayer chip ceramic capacitors is also extremely rapid. Traditional precious metal pastes are clearly beyond the reach of users in terms of cost. The multilayer chip ceramic capacitor with the base metal...

Claims

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Application Information

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IPC IPC(8): H01G4/008H01B1/22
Inventor 陈建权
Owner 广州三则电子材料有限公司
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