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Method for preparing biomass oil in microwave thermal decomposition way

A biomass oil and biomass technology, which is used in the preparation of liquid hydrocarbon mixtures, petroleum industry, etc., can solve the problems of insufficient liquefaction reaction advantages, great difficulties, serious friction and wear on high temperature walls, and achieve accurate and controllable pyrolysis temperature. , Reduce the cost of pretreatment, the effect of reducing particle size requirements

Inactive Publication Date: 2009-10-21
上海鸿泽企业发展有限公司
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Problems solved by technology

[0005] Combining the above existing technologies, it can be known that biomass pyrolysis liquefaction is a process in which biomass is degraded into liquid products and some gas products and solid products after being heated under the condition of complete anoxic or limited oxygen supply. The key to biomass pyrolysis liquefaction The equipment is a pyrolysis reactor. According to different classifications of reactions, the existing domestic and foreign pyrolysis liquefaction technologies mainly include the following types: (1) fluidized bed type, (2) rotating cone type, (3) ablation type; , (1) The main disadvantage of the fluidized bed type is that the introduction of fluidized gas increases the energy consumption of the system, because this part of the added gas will also undergo a process of heating and cooling. In addition, the fluidizing gas also dilutes the pyrolysis process. The non-condensable gas produced greatly reduces its calorific value, which brings difficulties to its application; (2) The main disadvantage of the rotating cone reactor is that the outer rotating cone must be supported by a cantilevered shaft for rotating motion, and the supporting The bearing of the extension shaft must be able to work reliably for a long time under high temperature and high dust conditions, which is quite difficult. In addition, inert heat carriers such as sand are constantly spiraling between the two cone walls, and its friction on the high temperature wall The wear will also be very serious; (3) The ablative pyrolysis liquefier needs inert gas such as nitrogen for cleaning, and there must be rotating parts in the reactor. The advantages of this liquefaction reaction are not obvious enough

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  • Method for preparing biomass oil in microwave thermal decomposition way

Examples

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Effect test

Embodiment 1

[0022] 50Kg granular waste wood chips are loaded into the raw material bin (about 3mm in particle size), and sent into the microwave pyrolysis reactor through a screw conveyor, and the feeding rate of the screw conveyor is set at 40Kg / h. The temperature of the sawdust entering the front end of the microwave pyrolysis reactor rises gradually to 90°C to 100°C after absorbing microwaves. Since the pressure inside the pyrolysis reactor is a slight negative pressure, reaching -0.02MPa, a large amount of water evaporates at this time. for the drying stage. Since the screw conveyor in the microwave pyrolysis reactor has a stirring function while conveying the sawdust, it promotes the uniform heating effect of the microwave. When the sawdust is transported to the middle section of the pyrolyzer, it starts to carbonize, and the temperature is in the range of 200°C to 350°C. At this time, it enters the carbonization stage. Since the carbonized sawdust absorbs microwaves dozens of times...

Embodiment 2

[0024] 30Kg section-shaped waste corn stalks are packed into the raw material bin (about 10mm in section length), and sent into the microwave pyrolysis reactor by a screw conveyor, and the feeding rate of the screw conveyor is set to 30Kg / h. The temperature of the straw entering the front end of the microwave pyrolysis reactor rises gradually to 90°C to 100°C after absorbing the microwave. Since the pressure inside the pyrolysis reactor is a slight negative pressure, reaching -0.02MPa, a large amount of water evaporates at this time, and the reaction The first stage is the drying stage. Because the screw conveyor in the microwave pyrolysis reactor has a stirring function while transporting the stalk, it promotes the uniform heating effect of the microwave. When the straw is transported to the middle section of the pyrolyzer, it starts to carbonize, and the temperature is in the range of 200°C to 250°C. At this time, it enters the carbonization stage. Since the microwave absor...

Embodiment 3

[0026]80Kg of the compressed straw sawdust mixture made by the granulator is packed into the raw material bin (5mm in particle diameter, 15mm in length), and sent into the microwave pyrolysis reactor by the screw conveyor, and the feed rate of the screw conveyor is set to 50Kg / h. The temperature of the material entering the front end of the microwave pyrolysis reactor rises gradually to 90°C to 100°C after absorbing microwaves. Since the pressure inside the pyrolysis reactor is a slight negative pressure, reaching -0.02MPa, a large amount of water evaporates at this time. for the drying stage. Because the screw conveyor in the microwave pyrolysis reactor has a stirring function while conveying the material, it promotes the uniform heating effect of the microwave. Carbonization begins when the material is transported to the middle section of the pyrolyzer, and the temperature is in the range of 280°C to 300°C, at this time it enters the carbonization stage. Since the microwa...

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Abstract

The invention discloses a method for preparing biomass oil in a microwave thermal decomposition way, which comprises the following steps: biomass enters a screw conveyer from a storage hopper, the feeding speed of the screw conveyer is 30-60 kilogram / h; the biomass enters a microwave pyrolysis reactor through the screw conveyor, the temperature of the biomass after absorbing microwave rapidly rises to 450-550 DEG C to reach the best temperature 475-500 DEG C of the biomass producing the oil; the biomass is thermally decomposed in the microwave pyrolysis reactor to produce high-temperature organic steam, the organic steam is sent to a cyclone separating device for gas and solid separation to remove carbon grains and sand; the organic steam is discharged through the cyclone separating device, the biomass is sent to a condenser for quenching, a condensable part of the biomass is changed into the biomass oil, and the biomass oil is dropped into an oil tank, thereby the biomass oil is prepared. The invention accords with the best process requirement of the biomass oil extraction without thermal conduction and has low cost, controllable and precise thermal decomposition temperature and no thermal inertia.

Description

【Technical field】 [0001] The invention belongs to the technical field of new energy, and specifically relates to a method for preparing biomass oil by microwave pyrolysis. 【Background technique】 [0002] Human beings are facing enormous pressure on energy and the environment. Today's energy mainly comes from fossil fuels such as coal, oil, and natural gas. Although the application of fossil energy has greatly promoted the progress of society, its resources are increasingly depleted and cannot be achieved. regeneration. At the same time, the excessive use of fossil energy has caused increasingly serious environmental problems. Therefore, the development and search for new alternative energy has become one of the major issues that human society needs to solve urgently. Replacing fossil fuels with biomass energy can not only reduce CO 2 Greenhouse gas emissions can also reduce SO emissions due to fossil fuel use 2 , NO X Therefore, biomass energy is the most important altern...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G1/00
Inventor 潘子荣
Owner 上海鸿泽企业发展有限公司
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