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Saloon car bumper special material capable of direct spray coating

A bumper and special material technology, applied in the field of improved new polypropylene materials, can solve the problems of easy sublimation, reduced melt flow rate, high thermal expansion coefficient of bumpers, etc., achieve stable shape and structure, improve dimensional stability, The effect of good processing fluidity

Inactive Publication Date: 2009-05-06
CHANGCHUN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Sometimes the flame is not handled properly, and the whole batch of painted bumpers will be scrapped, causing heavy losses
Chinese patent CN101070417A discusses grafting polypropylene with maleic anhydride (MAH), but the boiling point of maleic anhydride is low, the grafting process is easy to sublime, and it is corrosive to equipment
Chinese patent CN1235989A discloses the use of glycidyl methacrylate (GMA) as a grafting monomer, which reduces the melt flow rate of the material significantly, and improves the fluidity by increasing monomers such as small molecular weight polypropylene. Other properties of materials
Chinese patent CN1211590, etc. have described the use of thermoplastic elastomer POE as a toughening agent, but this toughening agent can only be physically blended with the matrix polypropylene plastic (PP) to achieve the purpose of toughening, and its blend shape and structure are not enough. Stablize
[0004] At present, the thermal expansion coefficient of the bumper material is high, and the fixing process and size matching of the bumper are required to be high. As a result, the size of the bumper changes due to temperature changes during use, resulting in deformation of the bumper and internal stress, which is easy to cause damage to the bumper. Loosening or breaking of bars

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] 1. Preparation of masterbatch

[0053] 600 grams of polypropylene and 400 grams of EPDM rubber are uniformly mixed, extruded and granulated through a twin-screw extruder.

[0054] 2. Dynamic vulcanization

[0055] Dissolve 5.4 grams of dicumyl peroxide in an appropriate amount of alcohol, mix it into the dried masterbatch, and extrude and granulate after the alcohol volatilizes.

[0056] 3. Second extrusion

[0057] 1000 grams of polypropylene are blended with the masterbatch after being dried and dynamically vulcanized, extruded and granulated to obtain the micro-crosslinked toughened masterbatch.

[0058] 4. Multi-monomer melt grafting

[0059]Dicumyl peroxide, methyl methacrylate, and styrene are dissolved and diluted with acetone solution according to a certain ratio, blended with polypropylene, extruded and granulated by a twin-screw extruder, and dried for later use.

[0060] 5. Blending and preparation of special materials

[0061] Get 2000 grams of micro-cr...

Embodiment 2

[0064] 1. Preparation of masterbatch

[0065] 900 grams of polypropylene and 600 grams of EPDM rubber are evenly mixed, extruded and granulated through a twin-screw extruder.

[0066] 2. Dynamic vulcanization

[0067] Dissolve 8.1 g of dicumyl peroxide in an appropriate amount of alcohol, mix it into the dried masterbatch, and extrude and granulate after the alcohol volatilizes.

[0068] 3. Second extrusion

[0069] 1800 grams of polypropylene are blended with the masterbatch after being dried and dynamically vulcanized, extruded and granulated to obtain the micro-crosslinked toughened masterbatch.

[0070] 4. Multi-monomer melt grafting

[0071] Dicumyl peroxide, methyl methacrylate, and styrene are dissolved and diluted with acetone solution according to a certain ratio, blended with polypropylene, extruded and granulated by a twin-screw extruder, and dried for later use.

[0072] 5. Blending and preparation of special materials

[0073] Get 3300 grams of micro-crosslin...

Embodiment 3

[0076] 1. Preparation of masterbatch

[0077] 600 grams of polypropylene and 400 grams of EPDM rubber are uniformly mixed, extruded and granulated through a twin-screw extruder.

[0078] 2. Dynamic vulcanization

[0079] Dissolve 6 grams of dicumyl peroxide in an appropriate amount of alcohol, mix it into the dried masterbatch, and extrude and granulate after the alcohol volatilizes.

[0080] 3. Second extrusion

[0081] 1000 grams of polypropylene are blended with the masterbatch after being dried and dynamically vulcanized, extruded and granulated to obtain the micro-crosslinked toughened masterbatch.

[0082] 4. Multi-monomer melt grafting

[0083] Dicumyl peroxide, methyl methacrylate, and styrene are dissolved and diluted with acetone solution according to a certain ratio, blended with polypropylene, extruded and granulated by a twin-screw extruder, and dried for later use.

[0084] 5. Blending and preparation of special materials

[0085] Get 2000 grams of micro-cro...

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Abstract

The invention discloses a special material for direct spray coating of a bumper, which is prepared by mixing of polypropylene, a rubber toughening agent, a crosslinking agent, grafted polypropylene, inorganic filler, black master bath, an antioxidant and a light stabilizer in proportion, preparation of the master bath, dynamic vulcanization, secondary extrusion, multi-monomer fusing and grafting, etc. The polarity of the special material for the bumper is changed by multi-monomer fusing and grafting modification of methyl methacrylate and so on, and the surface activity of the special material for the bumper is increased; and spray coating paint of the bumper comprises a plurality of chemical compositions, the appetency of various compositions and given functional groups is insufficient, a plurality of active functional groups are formed on the surface of the material by activation of a plurality of functional groups and can simultaneously form physical absorption or chemical bonding with the various chemical compositions in the paint, thereby the special material can perform direct spray coating without flame treating, achieves the optimum spray coating effect, and has good processing fluidity and high toughness.

Description

technical field [0001] The invention relates to an improved polypropylene new material, in particular to a special material for car bumpers with high toughness and high fluidity which can be directly sprayed. Background technique [0002] Polypropylene plastic (PP) lacks polar groups in its molecules. It is a non-polar material and has poor affinity with polar materials such as paint. The bumper must go through a flame treatment process before spraying. Sometimes, if the flame is not handled properly, the whole batch of painted bumpers will be scrapped, causing heavy losses. Chinese patent CN101070417A discusses grafting polypropylene with maleic anhydride (MAH), but the boiling point of maleic anhydride is low, the grafting process is easy to sublime, and it is corrosive to equipment. Chinese patent CN1235989A discloses the use of glycidyl methacrylate (GMA) as a graft monomer, which reduces the melt flow rate of the material significantly, and increases the fluidity of th...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L51/06C08L23/16C08L53/02C08L9/08C08K13/02C08K13/04C08K3/26C08K3/34C08K3/30C08K7/14
Inventor 敖玉辉李洪峰李姗姗初亚丽张会轩
Owner CHANGCHUN UNIV OF TECH
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