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Surface treating method for hydrogen occluding alloy

A hydrogen storage alloy and surface treatment technology, which is applied in metal material coating process, liquid chemical plating, coating and other directions, can solve the problem that the research on the high rate discharge performance of hydrogen storage alloy is not sufficient, and does not involve the recycling of hydrogen storage alloy. life and other issues, to achieve the effect of improving electrochemical performance, good plastic properties, and inhibiting pulverization

Inactive Publication Date: 2010-06-09
NANJING TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this article does not involve the process parameters of the treatment, and the research on the high-rate discharge performance of the hydrogen storage alloy is not sufficient, and it does not involve the research on the cycle life of the hydrogen storage alloy
The above studies did not further perform electroless plating on the surface of the hydrogen storage alloy, so as to further improve the electrochemical performance and corrosion resistance of the alloy, and improve the anti-powdering ability of the alloy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] 1) Fluorination treatment: Prepare one liter of treatment solution containing 0.6ml of aqueous solution with a mass percent concentration of 40% hydrofluoric acid and 0.1 mole of potassium fluoride. Heat the solution to 60 °C, add 10 g of LaNi prepared by melting method 4 Al rare earth based hydrogen storage alloy powder. Stir with a plastic stir bar for 30 minutes.

[0018] 2) Borohydride treatment: After the fluorination treatment is completed, immediately add 0.08 moles of potassium borohydride to the fluorination treatment solution and stir.

[0019] 3) After the hydrogen storage alloy powder treated in the above steps is washed with water, washed with absolute ethanol, suction filtered and dried, it is added to the prepared chemical plating solution for chemical nickel plating. The plating solution is composed of: nickel sulfate, 18g / L; sodium hypophosphite, 25g / L; complexing agent, 38g / L; thiourea, 0.001g / L. The pH value of the plating solution is adjusted to 9...

Embodiment 2

[0023] 1), fluoridation treatment: prepare 1 liter of treatment solution containing 0.9 ml of aqueous solution with a mass percent concentration of 40% hydrofluoric acid and 0.18 mole of sodium fluoride. Heat the solution to 75 °C, add 10 g of commercially available MmNi 3.8 co 0.75 mn 0.4 Al 0.2 Rare earth-based hydrogen storage alloy (sold by: Ningbo Shenjiang Technology Co., Ltd.). Stir with a plastic stir bar for 20 minutes.

[0024] 2) Borohydride treatment: After the fluorination treatment is completed, immediately add 0.09 mole of sodium borohydride to the fluorination treatment solution and stir.

[0025] 3) After the hydrogen storage alloy powder treated in the above steps is washed with water, washed with absolute ethanol, suction filtered and dried, it is added to the prepared chemical plating solution for chemical copper plating. The plating solution is composed of: copper sulfate, 12g / L; sodium hypophosphite, 12g / L; ethylenediaminetetraethyl disodium, 24g / L. ...

Embodiment 3

[0029] 1), fluoridation treatment: prepare an aqueous solution containing 0.75 ml of 40% hydrofluoric acid and 0.15 mole of potassium fluoride in one liter of treatment liquid. The solution was heated to 70° C., and 5 g of TiNi titanium-based hydrogen storage alloy powder prepared by mechanical ball milling was added. Stir with a plastic stir bar for 25 minutes.

[0030] 2) Borohydride treatment: After the fluorination treatment is completed, immediately add 0.1 mole of potassium borohydride to the fluorination treatment solution and stir.

[0031] 3) After the hydrogen storage alloy powder treated in the above steps is washed with water, washed with absolute ethanol, suction filtered and dried, it is added to the prepared chemical plating solution for chemical nickel plating. The plating solution is composed of: nickel sulfate, 20g / L; sodium hypophosphite, 30g / L; complexing agent, 40g / L; thiourea, 0.001g / L. The pH value of the plating solution is adjusted to 9 with ammonia ...

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Abstract

The invention relates to a surface processing method of metal hydride. The surface processing method comprises fluoridation, hydroborate processing and chemical plating. A close coating is formed on the surface of metal hydride powder after being processed by the surface processing method and the close coating has high catalytic activity, good plastic property and strong corrosion resistance so asto improve the charge discharge efficiency of the metal hydride, reduce a charging platform, raise a discharging platform and increase the discharge capacity of the metal hydride. As a result, the high-rate discharge property of the metal hydride is greatly improved and the cycle life of the metal hydride is prolonged.

Description

technical field [0001] The invention belongs to the field of energy and relates to a surface treatment method of a hydrogen storage alloy. Background technique [0002] Ni-MH secondary batteries involve a series of issues such as energy, materials, chemistry and environmental protection. In recent years, nickel-metal hydride secondary batteries have attracted widespread attention in high-power electric tools such as electric vehicles, which puts forward higher requirements for the electrochemical performance of batteries. The hydrogen storage alloy, which is the main component of the anode material of the Ni-MH battery, plays a decisive role in the performance of the battery (discharge capacity, high rate discharge and cycle life). Therefore, improving the electrochemical performance of hydrogen storage alloys is the key to improving battery performance. Changing the composition, organization and structure of alloys and establishing new alloy systems have attracted the att...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C18/31C23C18/18
Inventor 马立群赵相玉丁毅杨猛张玉洁
Owner NANJING TECH UNIV
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