Acrylic acid series nucleocapsid polymer emulsion and re-dispersible emulsion powder, and method for producing thereof
A polymer emulsion, acrylic technology, applied in the field of acrylic core-shell polymer emulsion and redispersible latex powder and its preparation, can solve the problem of limited dispersion, poor water resistance and ionic stability of redispersible latex powder, The performance of the film has not been reached, and the effect of long storage period, reduced packaging cost and good storage stability has been achieved.
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Embodiment 1
[0041] Embodiment one: (1) Synthesis of acrylic core-shell polymer emulsion
[0042] The monomer composition is methyl methacrylate, butyl acrylate, 2-hydroxyethyl acrylate, 3-hydroxypropyl acrylate, methacrylic acid, and N-methylol acrylamide, and its component formula is as follows:
[0043] components
[0044] Step 1: Preparation of the initiator: adding the ammonium persulfate initiator into the deionized water, stirring well until all the solids are dissolved, and preparing an initiator solution with a concentration of 2.5% by mass.
[0045] Step 2: the preparation of core (shell) monomer pre-emulsion, first deionized water, emulsifier and anhydrous sodium carbonate are added in the reactor that stirrer is housed, stir and disperse for 20 minutes, add the core of above-mentioned quality ( The monomers of the shell) layer were stirred and dispersed for 30 minutes to obtain the core (shell) monomer pre-emulsion;
[0046] Step 3: To prepare the nuclear seed microe...
Embodiment 2
[0053] Embodiment two: (1) Synthesis of acrylic core-shell polymer emulsion
[0054] The monomer composition is propyl methacrylate, methyl methacrylate, butyl acrylate, hexyl acrylate, 2-hydroxybutyl acrylate, methacrylic acid, and N-methylol acrylamide, and its component formula is as follows:
[0055] components
(nuclear) mass (g)
(shell) mass (g)
Propyl methacrylate
Acrylic acid-2-hydroxybutyl
ester
N-Methylolacrylamide
Emulsifier
24
22
26.5
20
4.5
2
1
3.2
1.2
30
45
10
8
2
4
1
3.2
1.2
ammonium persulfate initiator
1
Deionized water
150
150
[0056] Step 1: the preparation of core (shell) monomer pre-emulsion, first deionized water, emulsifier and anhydrous sodium carbonate are added in the reactor that agitator is equipped wit...
Embodiment 3
[0065] Embodiment three: (1) Synthesis of acrylic core-shell polymer emulsion
[0066] The monomer composition is methyl methacrylate, ethyl methacrylate, butyl methacrylate, methyl acrylate, butyl acrylate, propyl acrylate, 2-hydroxyhexyl acrylate, methacrylic acid, N-methylol Acrylamide,
[0067] Its component formula is as follows:
[0068] Component
(nuclear) mass (g)
(shell) mass (g)
16
30
Hexyl methacrylate
18.5
28
Propyl acrylate
2-Hydroxyethyl Acrylate
ester
N-Methylolacrylamide
Emulsifier
12
18
15
13
5
2
1.5
2.3
0.8
20
6
5
2
2
6
1
2.3
0.8
ammonium persulfate initiator
0.9
Deionized water
200
200
[0069] Step 1: the preparation of core (shell) monomer pre-emulsion, fir...
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