MOLD FOR HOT-FORMING Zn-PLATED STEEL SHEET
a technology of zn-plated steel and hot-forming tool, which is applied in the direction of manufacturing tools, shaping tools, vacuum evaporation coating, etc., can solve the problems of hot pressing method, zn softening, product shape and surface quality of formed steel sheets, etc., to inhibit zn adhesion, reduce zn reactivity, and reduce zn reactivity
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example 1
[0046]In Example 1, the influences of the composition and hydrogen content of a coating film on Zn adhesion resistance were examined. Hereinafter, a coating film formed on a substrate surface is often referred to as a coating.
[0047]A mirror-surface substrate constituted of SKD11 and having an HRC of 60 and a substrate Ra of 0.005 μm was prepared as a substrate for evaluating the surface profile of a coating. Meanwhile, a mirror-surface bending tool constituted of SKD61 and having a substrate Ra of 0.01 to 3 μm was prepared for evaluating Zn adhesion resistance. As a coating, each of coating films of nitrides, i.e., TiN, CrN and TiAlN, as conventional coating films, DLC films having the hydrogen contents shown in Table 1, and the DLC films containing Si or W as shown in Table 1 was formed on a surface of the substrate.
[0048]These coatings were formed by the un-balanced magnetron sputtering method. The film deposition conditions for the un-balanced magnetron sputtering method included...
example 2
[0061]In Example 2, the influence of the surface profile of a DLC film on Zn adhesion resistance was examined.
[0062]Samples were produced in the same manner as in Example 1, except that a substrate was coated with a DLC film having a hydrogen content of 10 atom % and the Ra, RΔq and Rsk were changed as shown in Table 2. In Example 1 and Example 3, which will be given layer, a substrate having a mirror surface was used. In this Example 2, however, the roughness of the substrate was varied by the method described above, and a DLC film was formed thereon. Thus, samples which varied in the Ra, RΔq and Rsk were prepared.
[0063]A Zn adhesion evaluation test was conducted in the same manner as in Example 1 to evaluate Zn adhesion resistance. The results thereof are shown in Table 2.
TABLE 2Evaluationof ZnRaRΔqRskadhesionNo.(μm)(°)(−)resistance10.010.01−2.0020.10.03−2.0030.50.05−1.0041.00.10−0.5152.00.30−0.2163.00.40−0.2372.00.60−0.1382.00.70−0.1392.00.300.52
[0064]The following can be seen fr...
example 3
[0065]In Example 3, the influence of the proportion of sp2 bonds in a DLC film on Zn adhesion resistance was examined.
[0066]Samples were produced in the same manner as in Example 1, except that one of the coating films was formed by the arc ion plating (AIP) method and that the voltage which was applied to the substrate during film deposition by the AIP method or UBMS method was changed to thereby form DLC films differing in the proportion of sp2 bonds as shown in Table 3. The hydrogen content was regulated in the same manner as in Example 1. The film deposition conditions for the arc ion plating method included a substrate temperature of 400° C., a total gas pressure of 4 Pa and a bias voltage of −50 V. A Zn adhesion evaluation test was conducted in the same manner as in Example 1 to evaluate Zn adhesion resistance.
[0067]The proportion of sp2 bonds was ascertained by EELS analysis. The measurement conditions for the EELS analysis are as follows.
EELS analysis apparatus: Tridiem, man...
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