Method for achieving low defect density algan single crystal boules

Abstract

A method for growing bulk GaN and AlGaN single crystal boules, preferably using a modified HVPE process, is provided. The single crystal boules typically have a volume in excess of 4 cubic centimeters with a minimum dimension of approximately 1 centimeter. If desired, the bulk material can be doped during growth to achieve n-, i-, or p-type conductivity. In order to have growth cycles of sufficient duration, preferably an extended Ga source is used in which a portion of the Ga source is maintained at a relatively high temperature while most of the Ga source is maintained at a temperature close to, and just above, the melting temperature of Ga. To grow large boules of AlGaN, preferably multiple Al sources are used, the Al sources being sequentially activated to avoid Al source depletion and excessive degradation. In order to achieve high growth rates, preferably a dual growth zone reactor is used in which a first, high temperature zone is used for crystal nucleation and a second, low temperature zone is used for rapid crystal growth. Although the process can be used to grow crystals in which the as-grown material and the seed crystal are of different composition, preferably the two crystalline structures have the same composition, thus yielding improved crystal quality.

Description

CROSS REFERENCES TO RELATED APPLICATIONS [0001] The present application is a continuation of U.S. application Ser. No. 09 / 903,047 filed Jul. 9, 2001, priority of which is claimed under 35 U.S.C. § 120, which is a continuation of U.S. application Ser. No. 09 / 900,833, filed Jul. 6, 2001, priority of which is also claimed under 35 U.S.C. §120.FIELD OF THE INVENTION [0002] The present invention relates generally to semiconductor materials and, more particularly, to a method for growing bulk single crystals. BACKGROUND OF THE INVENTION [0003] Recent results in the development of GaN-based light-emitting diodes (LEDs) and laser diodes LDs) operating in the green, blue, and ultraviolet spectrum have demonstrated the tremendous scientific and commercial potential of group III nitride semiconductors (e.g., GaN, AlN, InN, and their alloys). These applications require electrically conducting substrates (e.g., GaN or AlGaN) so that a vertical device geometry can be utilized in which the electro...

AI Technical Summary

Benefits of technology

[0016] According to one aspect of the invention, an extended Ga source is located within a reactor such that a portion of the Ga source is maintained at a relatively high temperature while most of the Ga source is maintained at a temperature close to, and just above, the melting temperature of Ga. In at least one embodiment of the invention, in order to obtain the desired temperature spread in the Ga source, a portion of the source tube extends outside of the reactor. Assuming the use of a modified HVPE process for the growth of the single crystal boule, preferably the high temperature is in the range of 450° C. to 850° C., and more preferably at a temperature of approximately 650° C., while the low temperature is less than 100° C. and preferably in the range of 30° C. to 40° C. As a result of this source configuration, the amount of Ga undergoing a reaction is controllable and limited, thus allowing extended growth cycles to be realized without experiencing degradation in the as-grown material.

Problems solved by technology

Although the high temperature of this zone allows high quality crystal growth, the growth rate at this temperature is relatively low.

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