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Preparation of hard polyurethane conductive foam plastic for carbon nanotube filling

A technology of rigid polyurethane and carbon nanotubes, applied in the field of new polymer materials, can solve the problems such as no reports of CNTs/polyurethane foam composite materials, and achieve the effect of improving electrical conductivity and improving mechanical properties

Inactive Publication Date: 2007-05-30
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] However, as far as the available literature and patent reports are concerned, there is no report on CNTs / polyurethane foam composites

Method used

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  • Preparation of hard polyurethane conductive foam plastic for carbon nanotube filling
  • Preparation of hard polyurethane conductive foam plastic for carbon nanotube filling
  • Preparation of hard polyurethane conductive foam plastic for carbon nanotube filling

Examples

Experimental program
Comparison scheme
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Embodiment Construction

[0042] The examples given below are specific descriptions of the present invention. It is necessary to point out that the following examples are only used to further illustrate the present invention, and cannot be interpreted as limiting the protection scope of the present invention. Those skilled in the art according to the above-mentioned SUMMARY OF THE INVENTION Some non-essential improvements and adjustments to the present invention still belong to the protection scope of the present invention.

[0043] Density 0.25g / cm 3The formula of the embodiment 1~10 of the rigid polyurethane foam of left and right is shown in Table 3

[0044] The formula of table 3 embodiment 1~10

[0045] implement

example

Polyether polyol

Isocyanate

carbon nanotubes

Organotin

Triethanolamine

water

silicone oil

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Abstract

The invention discloses a making method and device of carbon nanometer pipe with high-density conductive hard-polyurethane foam plastic, which comprises the following steps: oxidizing the surface of carbon nanometer pipe; adopting distilled water as diluent; vibrating and grinding through ultrasound; dispersing carbon nanometer pipe in the polyether polyol; evaporating water in the system; obtaining the composite liquid of carbon nanometer pipe and polyether polyol; blending with organic tin, silicon oil and water according to certain proportion through mechanic stirring device evenly; mixing with certain quantity of isocyanate completely; casting in the mould; closing mould lid; ripening; obtaining the product.

Description

1. Technical field [0001] The invention belongs to the technical field of new polymer materials, and relates to a method for producing conductive or antistatic rigid polyurethane foam plastics by utilizing carbon nanotubes (CNTs) and polyurethane. 2. Background technology [0002] Polymer materials have excellent comprehensive properties (such as light weight, corrosion resistance, easy processing, low cost, convenient use, etc.), and are widely used in the field of defense industry. The volume resistivity of polymer materials is usually very large, about 10 10 ~10 20 Between Ω·cm, it is undoubtedly very good as an electrical insulating material. However, with the development of the national defense electronics industry and information technology and the requirements for electromagnetic shielding of weapons, wave-absorbing stealth and special items (such as high-energy explosives, precision electronic and electrical components), polymer materials with certain conductive fu...

Claims

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Application Information

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IPC IPC(8): C08G18/48C08K3/04C08G101/00
Inventor 李忠明石磊杨鸣波
Owner SICHUAN UNIV
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