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Technology for dispersing carbon nanotubes in lithium ion battery slurry

A technology of lithium-ion batteries and carbon nanotubes, applied in battery electrodes, circuits, electrical components, etc., can solve the problem of unsatisfactory unit activity content of lithium-ion batteries, poor conductivity of lithium-ion battery pole pieces, and insufficient lithium-ion battery pole pieces Smooth and other problems, to avoid excessive settling rate, improve dispersion uniformity, and strong process operability

Inactive Publication Date: 2014-02-26
东莞市金源电池科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the strong van der Waals interaction between carbon nanotubes, they are usually easy to agglomerate to form large tube bundles, which are difficult to disperse, which greatly restricts the exertion and application of its excellent performance.
[0003] In the prior art lithium-ion battery slurry, the content of carbon nanotubes is approximately 1.5% to 3%. Since the content of carbon nanotubes is not high enough, the conductivity of the lithium-ion battery is affected, and the prepared lithium-ion battery The unit activity content is not ideal
In addition, in the lithium-ion battery slurry in the prior art, the dispersion of carbon nanotubes is not uniform enough, and there is a problem of too fast agglomeration, and the sedimentation rate of the lithium-ion battery slurry is too fast. Therefore, the lithium-ion battery slurry is coated with Due to the uneven dispersion of carbon nanotubes in the cloth process, the lithium-ion battery pole piece is not smooth enough, and there is an obvious grainy feel, and the conductivity of the lithium-ion battery pole piece is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A carbon nanotube dispersion process for lithium ion battery slurry, which comprises the following steps:

[0046] Step 1. Preparation of carbon nanotube conductive paste

[0047] (1) adding a certain amount of carbon nanotubes, polyvinylpyrrolidone and N-methylpyrrolidone into the stirring tank and stirring for 30 minutes to obtain a premix;

[0048] (2) grinding the premix obtained in step 1 with a nano-scale zircon grinder, the number of times of grinding is 3 times, and the time of each grinding is 20 minutes, and the carbon nanotube conductive slurry is obtained after grinding;

[0049] In this embodiment, the carbon nanotube conductive paste includes the following components by weight: 3 kg of carbon nanotubes, 1.3 kg of vinylpyrrolidine, and 95.7 kg of N-methylpyrrolidone.

[0050] Step 2, the preparation of polyvinylidene fluoride glue

[0051] Dissolve 1 part by weight of polyvinylidene fluoride in 9 parts by weight of N-methylpyrrolidone, and stir for 120 mi...

Embodiment 2

[0060] A carbon nanotube dispersion process for lithium ion battery slurry, which comprises the following steps:

[0061] Step 1. Preparation of carbon nanotube conductive paste

[0062] (1) adding a certain amount of carbon nanotubes, polyvinylpyrrolidone and N-methylpyrrolidone into the stirring tank and stirring for 60 minutes to obtain a premix;

[0063] (2) grinding the premix obtained in step 1 with a nanoscale zircon grinder, the number of times of grinding is 4 times, and the time of each grinding is 10 minutes, and the carbon nanotube conductive slurry is obtained after grinding;

[0064] In this embodiment, the carbon nanotube conductive paste includes the following components by weight: 3.5 kg of carbon nanotubes, 1 kg of vinylpyrrolidine, and 95.5 kg of N-methylpyrrolidone.

[0065] Step 2, the preparation of polyvinylidene fluoride glue

[0066] Dissolve 0.8 part by weight of polyvinylidene fluoride in 9.2 parts by weight of N-methylpyrrolidone, and stir for 140...

Embodiment 3

[0075] A carbon nanotube dispersion process for lithium ion battery slurry, which comprises the following steps:

[0076] Step 1. Preparation of carbon nanotube conductive paste

[0077] (1) adding a certain amount of carbon nanotubes, polyvinylpyrrolidone and N-methylpyrrolidone into the stirring tank and stirring for 40 minutes to obtain a premix;

[0078] (2) grinding the premix obtained in step 1 with a nanoscale zircon grinder, the number of times of grinding is 4 times, and the time of each grinding is 15 minutes, and the carbon nanotube conductive slurry is obtained after grinding;

[0079] In this embodiment, the carbon nanotube conductive paste includes the following components by weight: 4 kg of carbon nanotubes, 2 kg of vinylpyrrolidine, and 94 kg of N-methylpyrrolidone.

[0080] Step 2, the preparation of polyvinylidene fluoride glue

[0081] Dissolve 1.2 parts by weight of polyvinylidene fluoride in 8.8 parts by weight of N-methylpyrrolidone, and stir for 160 mi...

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Abstract

The invention relates to the technical field of lithium ion batteries and especially relates to a technology for dispersing carbon nanotubes in lithium ion battery slurry. The technology comprises the following steps of 1, carbon nanotube conductive paste preparation, 2, polyvinylidene fluoride glue solution preparation, and 3, lithium ion battery slurry preparation: (1), mixing the polyvinylidene fluoride glue solution and the carbon nanotube conductive paste, (2), adding lithium cobaltate into the mixture for the first time and (3), adding lithium cobaltate and the polyvinylidene fluoride glue solution into the mixture obtained by the step (2) for the second time. The technology improves carbon nanotube dispersion uniformity and solves the problem of too fast agglomeration of the carbon nanotubes and the problem of a too fast rate of lithium ion battery slurry settlement. The carbon nanotubes are uniformly dispersed in the lithium ion battery slurry so that the pole piece of the lithium ion battery is smooth in lithium ion battery slurry coating and thus the pole piece of the lithium ion battery does not have obvious granular feel and has good electroconductivity.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a carbon nanotube dispersion process for lithium ion battery slurry. Background technique [0002] Due to their unique structure and excellent performance, carbon nanotubes are widely used in electronic devices, energy storage devices, structural and functional composite materials and other fields. Carbon nanotubes have high specific surface area, high aspect ratio, and excellent mechanical, electrical, and thermal properties. They are considered to be ideal fillers for polymer materials, which can enhance or improve the electrical and thermal conductivity of polymers. However, due to the strong van der Waals interaction between carbon nanotubes, they are usually easy to agglomerate to form large tube bundles, which are difficult to disperse, which greatly restricts the exertion and application of their excellent performance. [0003] In the prior art lithium-ion b...

Claims

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Application Information

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IPC IPC(8): H01M4/139
CPCY02E60/122H01M4/525H01M4/62H01M4/625Y02E60/10
Inventor 陈设军李志福刘涛张桂河许少图宋明
Owner 东莞市金源电池科技有限公司
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