Electromagnetic wave absorbing thermally conductive composition and thermosoftening electromagnetic wave absorbing heat dissipation sheet and method of heat disspation work
A composition and electromagnetic wave technology, applied in chemical instruments and methods, magnetic materials, iron compounds, etc., can solve problems such as unsuitable heat dissipation products, low thermal conductivity, etc.
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Embodiment 1-4
[0058] The acrylic-based electromagnetic wave absorbing and thermally conductive composition consisting mainly of a mixture of acrylic resin and electromagnetic wave absorbing filler and having a softening point of at least 40° C. is molded into a heat-softening electromagnetic wave absorbing heat dissipation sheet as described below.
[0059] In all cases, acrylic resin was used as the resin component of the acrylic-based electromagnetic wave absorbing heat-conducting composition and paraffin was used as the heat-softening component. Another ingredient included in the composition is a carbon functional silane used as a surface treatment agent for electromagnetic wave absorbing fillers and thermally conductive fillers. The starting materials used to formulate the compositions are listed below.
[0060] Starting materials
[0061] 1) Paraffin: Paraffin 115 (melting point, 47°C) and Paraffin 130 (melting point, 55°C), manufactured by Nippon Seiro Co., Ltd.
[0062] 2) Acryli...
Embodiment 5-8
[0091] A fluorocarbon resin-based electromagnetic wave absorbing heat conducting composition consisting mainly of a mixture of a fluorocarbon resin and an electromagnetic wave absorbing filler and having a softening point of at least 40° C. is molded into a heat softening electromagnetic wave absorbing heat dissipation sheet as follows.
[0092] In all cases, liquid fluorocarbon resin was used as the resin component of the fluorocarbon resin-based electromagnetic wave absorbing heat-conducting composition and polyvinylidene fluoride / hexafluoropropylene / tetrafluoroethylene ternary resin was used as the heat-softening component. Another ingredient included in the composition is a carbon functional silane used as a surface treatment agent for electromagnetic wave absorbing fillers and thermally conductive fillers. The starting materials used to formulate the compositions are listed below.
[0093] Starting materials
[0094] 1) Kynar 9301 (thermal softening temperature, 80°C),...
Embodiment 9-18 and comparative example 1
[0105] A silicone-based electromagnetic wave absorbing heat conducting composition consisting mainly of a mixture of a silicone resin and an electromagnetic wave absorbing filler and having a softening point of at least 40° C. is molded into a heat softening electromagnetic wave absorbing heat dissipation sheet as described below.
[0106] In all cases, the methylphenylsiloxane resin (by combining the structural unit CH 3 SiO 3 / 2 , (CH 3 ) 2 SiO,C 6 h 5 SiO 3 / 2 , (C 6 h 5 )(CH 3 ) SiO and (C 6 h 5 )2 A copolymer obtained from SiO) is used as a heat-softening component in a silicone-based electromagnetic wave absorbing heat-conducting composition. Two vinyl-group-carrying dimethylpolysiloxanes with different viscosities were used as matrix components. The composition also includes a silicon atom-bonded alkoxy group-containing organopolysiloxane having the following general formula (1) as a surface treatment agent for the electromagnetic wave absorbing filler and the ...
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