Low-temperature-resistant spandex fiber and preparation method thereof
A technology of spandex fiber and low temperature resistance, which is applied in the field of polyurethane fiber, can solve the problems such as the inability to directly apply spandex fiber, and achieve the effects of high recovery rate, excellent low temperature resistance and excellent mechanical properties
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[0037] The invention provides a method for preparing low temperature resistant spandex fibers as described above, comprising the following steps:
[0038] 1) polyether diol and diisocyanate are mixed and reacted to obtain isocyanate group-terminated polyurethane prepolymer;
[0039] 2) using an organic solvent to dissolve the polyurethane prepolymer to obtain a prepolymer solution;
[0040] 3) adding a mixed amine solution to the prepolymer solution for chain extension reaction to obtain a polyurethane urea solution, which is fully matured to obtain a spinning stock solution;
[0041] 4) The spinning dope is dry-spun to obtain low-temperature-resistant spandex fibers.
[0042] Wherein, the organic solvent is one or a combination of N,N-dimethylformamide or N,N-dimethylacetamide;
[0043] The mass concentration of the spinning stock solution is 35% to 42%;
[0044] The mass concentration of the mixed amine solution is 3-7%;
[0045] The reaction temperature of the step 1) i...
Embodiment 1
[0066] The polyether diol that adopts is poly-2-methyltetrahydrofuran diol (molecular weight 1000), and diisocyanate is diphenylmethane diisocyanate;
[0067] The mixed amines are diethylamine and 1-methyl-2,4-cyclohexanediamine respectively;
[0068] Wherein, the spandex fiber also contains polyurethane plasticizer (molecular weight: 200), and the addition amount is 0.3%, which is calculated based on the mass of the prepared spandex fiber.
Embodiment 2
[0070] The polyether diol that adopts is poly-2-methyltetrahydrofuran diol (molecular weight 1400), and diisocyanate is diphenylmethane diisocyanate;
[0071] The mixed amines are diethylamine, 3,3'-dimethyl-4,4'-diamino-dicyclohexylmethane and 4-methyl-o-phenylenediamine, in which 3,3'-dimethyl-4 , the molar ratio of 4'-diamino-dicyclohexylmethane to 4-methyl o-phenylenediamine is 2:1;
[0072] Wherein, the spandex fiber also contains polyurethane plasticizer (molecular weight: 500), and the addition amount is 1.5%, which is calculated based on the mass of the prepared spandex fiber.
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