Nematicidal composition containing fluorine ensulfone and organophosphorus
A technology of fluorine sulfone and organophosphorus, applied in the field of pesticides, can solve the problems of poor penetration of animal cell membranes, etc., and achieve the effects of good temperature and salt resistance, high yield, and short process
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Embodiment 1
[0042] This embodiment is a nematicidal composition containing fluorine sulfone and organic phosphorus, including the following components in parts by weight:
[0043] 10 parts of sulfone, 20 parts of organophosphorus, 5 parts of surface active agent, 2 parts of penetration aid, 20 parts of filler or solvent;
[0044] Wherein the penetration aid is prepared by the following steps:
[0045] S1: Add alkylphenol polyoxyethylene ether and NaOH to the four-necked flask, N 2Replace the air in the reaction bottle for 10 minutes, start stirring, control the temperature at 90°C, vacuum at 20mmHg, and react for 5 hours to obtain Intermediate A;
[0046] S2: Lower the temperature of intermediate A to 20°C, add allyl chloroacetate, control the reaction temperature at 60°C, react for 2 hours, wash with hot water, and collect the upper layer at rest to obtain intermediate B;
[0047] S3: Intermediate B and NaHSO 3 Add solvent water, add co-solvent isopropanol and catalyst and mix evenly,...
Embodiment 2
[0054] This embodiment is a nematicidal composition containing fluorine sulfone and organic phosphorus, including the following components in parts by weight:
[0055] 20 parts of sulfone, 10 parts of organophosphorus, 5 parts of surface active agent, 3 parts of penetration aid, 20 parts of filler or solvent;
[0056] Wherein the penetration aid is prepared by the following steps:
[0057] S1: Add alkylphenol polyoxyethylene ether and NaOH to the four-necked flask, N 2 Replace the air in the reaction bottle for 10 minutes, start stirring, control the temperature at 90°C, vacuum at 20mmHg, and react for 5 hours to obtain Intermediate A;
[0058] S2: Lower the temperature of intermediate A to 20°C, add allyl chloroacetate, control the reaction temperature at 60°C, react for 2 hours, wash with hot water, and collect the upper layer at rest to obtain intermediate B;
[0059] S3: Intermediate B and NaHSO 3 Add solvent water, add co-solvent isopropanol and catalyst and mix evenly...
Embodiment 3
[0066] This embodiment is a nematicidal composition containing fluorine sulfone and organic phosphorus, including the following components in parts by weight:
[0067] 20 parts of sulfone, 20 parts of organophosphorus, 5 parts of surface active agent, 3 parts of penetration aid, 30 parts of filler or solvent;
[0068] Wherein the penetration aid is prepared by the following steps:
[0069] S1: Add alkylphenol polyoxyethylene ether and NaOH to the four-necked flask, N 2 Replace the air in the reaction bottle for 20 minutes, start stirring, control the temperature at 100°C, vacuum at 25mmHg, and react for 6 hours to obtain Intermediate A;
[0070] S2: Lower the temperature of Intermediate A to 30°C, add allyl chloroacetate, control the reaction temperature to 70°C, react for 3 hours, wash with hot water, and collect the upper layer at rest to obtain Intermediate B;
[0071] S3: Intermediate B and NaHSO 3 Add solvent water, add co-solvent isopropanol and catalyst and mix evenl...
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