High-foam-stability and low-sensitivity concrete air entraining agent and preparation method thereof
A low-sensitivity, concrete technology, applied in the field of low-sensitivity concrete air-entraining agent and preparation, high foam stability, can solve the needs of air-entrainment and foam stabilization, without considering the hard water situation in alpine regions, concrete air-entraining agent research Less problems, low CMC value, simple preparation method, improved strength and viscoelasticity
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Embodiment 1
[0031] A high-foam-stabilizing, low-sensitivity concrete air-entraining agent is made of the following components by mass percentage: Gemini surfactant 20%, viscosity modifier 2%, foam stabilizer 2%, synergist 1%, Water 75%;
[0032] The viscosity regulator is prepared from xanthan gum, guar gum and bone glue in a mass ratio of 1:0.2:1, and the synergist is sodium nitrite;
[0033] The preparation method of the high foam stability and low sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0034] Step 1: Preparation of Gemini Surfactants
[0035] (1) Add lauroyl chloride with dichloromethane as a solvent in the reaction kettle, add dropwise 1% pyridine of the solution mass, slowly add N,N-diethylethanolamine, lauroyl chloride and N, under ice bath and stirring conditions The molar ratio of N-diethylethanolamine is 1:1.2, then the temperature is raised to 20°C, and the reaction is carried out for 3 hours to obtain the intermediate product 1; ...
Embodiment 2
[0047] A high-foam-stabilizing, low-sensitivity concrete air-entraining agent is made of the following components by mass percentage: Gemini surfactant 40%, viscosity regulator 3%, foam stabilizer 5%, synergist 2%, water 50%;
[0048] The viscosity regulator is prepared from xanthan gum, guar gum and bone glue in a mass ratio of 1:0.2:1.2, and the synergist is sodium nitrite;
[0049] The preparation method of the high foam stability and low sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0050] Step 1: Preparation of Gemini Surfactants
[0051] (1) Add lauroyl chloride with dichloromethane as a solvent in the reaction kettle, add dropwise 1% pyridine of the solution mass, slowly add N,N-diethylethanolamine, lauroyl chloride and N, under ice bath and stirring conditions The molar ratio of N-diethylethanolamine was 1:1.4, then the temperature was raised to 25°C, and the reaction was carried out for 2 hours to obtain the intermediate product ...
Embodiment 3
[0063] A high-foam-stabilizing, low-sensitivity concrete air-entraining agent is made of the following components by mass percentage: Gemini surfactant 30%, viscosity regulator 3%, foam stabilizer 5%, synergist 2%, Water 60%;
[0064] The viscosity modifier is prepared from xanthan gum, guar gum and bone glue at a mass ratio of 1:0.2:1.5, and the synergist is sodium nitrite;
[0065] The preparation method of the high foam stability and low sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0066] Step 1: Preparation of Gemini Surfactants
[0067] (1) Add lauroyl chloride with dichloromethane as a solvent in the reaction kettle, dropwise add 1.5% pyridine of solution mass, slowly add N,N-diethylethanolamine, lauroyl chloride and N, The molar ratio of N-diethylethanolamine was 1:1.2, then the temperature was raised to 25°C, and the reaction was carried out for 2 hours to obtain the intermediate product 1;
[0068] (2) Add myristoyl chloride ...
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