Treatment-free environment-friendly coating for printing plate and preparation method of treatment-free environment-friendly coating
A printing plate, treatment-free technology, applied in the field of printing plates, can solve problems such as affecting the performance of use and easily causing microbial enrichment.
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Embodiment 1
[0051] Preparation of modified additives:
[0052] Step S11: Add 4-hydroxy-4'-methylbenzophenone and zinc powder into the flask, then add tetrahydrofuran, blow in nitrogen, and drop tetrahydrofuran into the flask under the condition of temperature -30°C and speed of 100r / min. Titanium chloride, after the dropwise addition, stir at room temperature for 1 hour, then heat up to 90°C for reflux reaction for 10 hours, and then perform post-treatment. The post-treatment steps are: cooling, suction filtration, rotary evaporation, and adding a hydrochloric acid solution with a mass fraction of 10%. , and then add toluene for extraction, after drying with anhydrous sodium sulfate, rotary evaporation and recrystallization, the intermediate 1 is obtained;
[0053] Step S12: Add intermediate 1 and dichloromethane to the flask, stir at room temperature for 10 min, then add 3,4-dihydropyran and pyridine p-toluenesulfonate into the flask at a temperature of 22°C, and stir at 22°C 1h, and th...
Embodiment 2
[0060] Preparation of modified additives:
[0061] Step S11: Add 4-hydroxy-4'-methylbenzophenone and zinc powder into the flask, then add tetrahydrofuran, blow in nitrogen, and drop tetrahydrofuran into the flask under the condition of temperature -30°C and speed of 100r / min. Titanium chloride, after the dropwise addition, stir at room temperature for 2 hours, then heat up to 90°C for reflux reaction for 10 hours, and then perform post-treatment. The post-treatment steps are: cooling, suction filtration, rotary evaporation, and then adding a hydrochloric acid solution with a mass fraction of 10%. , and then add toluene for extraction, after drying with anhydrous sodium sulfate, rotary evaporation and recrystallization, the intermediate 1 is obtained;
[0062] Step S12: Add intermediate 1 and dichloromethane to the flask, stir at room temperature for 10 min, then add 3,4-dihydropyran and pyridine p-toluenesulfonate into the flask at a temperature of 22°C, and stir at 24°C 1h, ...
Embodiment 3
[0069] Preparation of modified gelatin
[0070] Described modified gelatin is made by following steps:
[0071] Step S1: Add gelatin and phosphate buffer solution with a pH of 10 into the beaker, stir for 3 minutes, swell at room temperature for 40 minutes, then stir for 1 hour at a temperature of 55°C and a speed of 200 r / min, and obtain a gelatin solution after stirring;
[0072] Step S2: Add the gelatin solution into the flask, then add the modification aid prepared in Example 1, stir and react for 6 hours at a temperature of 50°C and a rotation speed of 300r / min, and perform post-treatment after the reaction. The post-processing step is: Freeze-dried at -45°C for 12 hours, then washed three times with methanol at 40°C, and washed three times with deionized water, and then freeze-dried at -60°C for 10 hours to obtain modified gelatin.
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