Hydroxyl and amino modified antiknock composite material and preparation method thereof
A composite material and amino modification technology, which is applied in the field of anti-corrosion and anti-explosion materials, can solve the problems of decreased coating film strength, separation of fillers and resins, loss of anti-ballistic and anti-explosion materials, etc.
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Embodiment 1
[0024] An anti-knock composite material modified by hydroxyl and amino groups provided in Example 1 of the present invention includes semi-prepolymer A component and B component, wherein the semi-prepolymer A component includes the following raw materials in mass percentage: poly 40-60% of ether diol or polyester diol, 8-10% of polyisocyanate, 30-35% of hydroxyl-modified carbon nanotube and secondary doped polyaniline composite material; component B includes the following mass percentages Raw materials: amino-terminated polyether or carboxyl-terminated polyether 50-70%, diamine chain extender 10-30%, molecular sieve powder slurry 0.5-1%, color paste 0.5-1%, and amino-modified carbon nanotubes and intrinsic Composites of state polyaniline and secondary doped state polyaniline 0.1-0.5%, polyether diol or polyester diol, polyisocyanate exists in the form of isocyanate-terminated semi-prepolymer semi-prepolymer group A Score.
[0025]The composite material of hydroxyl-modified ca...
Embodiment 2
[0030] Based on the same inventive concept, Embodiment 2 of the present invention provides a method for preparing the above-mentioned hydroxyl and amino modified anti-knock composite material, the method comprising:
[0031] Step 1: Mix the carbon nanotube raw material and the mixed acid at a mass percentage of 0.1:100, ultrasonically disperse evenly, stir at 60°C for 6-8 hours, and then wash with deionized water until pH=1. Add aniline and ammonium persulfate at a ratio of 0.8:1, stir at room temperature for 2 hours, then let stand for 12 hours, then wash with deionized water several times and filter with suction until the filtrate is neutral, and dry the product at 80°C to obtain the target The product is a composite material of hydroxyl-modified carbon nanotubes and primary doped polyaniline.
[0032] Specifically, when aniline and ammonium persulfate are added according to the ratio of 0.8:1 by molar mass percentage, aniline undergoes a polymerization reaction under the ac...
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