Hydroxyl and amino modified antiknock composite material and preparation method thereof
A composite material and amino-modified technology, which is applied in the field of anti-corrosion and anti-explosion materials, can solve the problems of poor low-temperature flexibility, decreased coating film strength, and loss of anti-ballistic and explosion-proof materials, so as to avoid poor low-temperature flexibility, reduce explosion impact damage, The effect of improving the resistance to gas explosion impact
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Embodiment 1
[0026]An anti-knock composite material modified by hydroxyl and amino groups provided in Example 1 of the present invention includes semi-prepolymer A component and B component, wherein the semi-prepolymer A component includes the following raw materials in mass percentage: poly 40-60% of ether diol or polyester diol, 8-10% of polyisocyanate, 30-35% of hydroxyl-modified nano-carbon and secondary doped polyaniline composite material; component B includes the following raw materials in mass percentage : Amino-terminated polyether or carboxyl-terminated polyether 50-70%, diamine chain extender 10-30%, molecular sieve powder slurry 0.5-1%, color paste 0.5-1%, and amino-modified nano-carbon and intrinsic state polymer Composite material of aniline and secondary doped polyaniline 0.1-0.5%, polyether diol or polyester diol, polyisocyanate exists in semi-prepolymer A component in the form of isocyanate-terminated semi-prepolymer , the nano-carbon and secondary doped polyaniline compos...
Embodiment 2
[0036] Based on the same inventive concept, Embodiment 2 of the present invention provides a method for preparing the above-mentioned hydroxyl and amino modified anti-knock composite material, the method comprising:
[0037] Step 1: Mix the graphene raw material and the mixed acid at a mass percentage of 0.1:100, ultrasonically disperse evenly and stir at 60°C for 6-8 hours, then wash with deionized water until pH = 1, then the molar mass percentage is Add aniline and ammonium persulfate at a ratio of 0.8:1, stir at room temperature for 2 hours, then let stand for 12 hours, then wash with deionized water several times and filter with suction until the filtrate is neutral, and dry the product at 80°C to obtain the target product Composite materials of hydroxyl-modified graphene and primary doped polyaniline.
[0038] Specifically, after adding aniline and ammonium persulfate at a ratio of 0.8:1 according to the molar mass percentage, aniline is polymerized under the action of a...
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