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Hydroxyl and amino modified antiknock composite material and preparation method thereof

A composite material and amino-modified technology, which is applied in the field of anti-corrosion and anti-explosion materials, can solve the problems of poor low-temperature flexibility, decreased coating film strength, and loss of anti-ballistic and explosion-proof materials, so as to avoid poor low-temperature flexibility, reduce explosion impact damage, The effect of improving the resistance to gas explosion impact

Pending Publication Date: 2021-05-14
青岛海弗莱安全科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if too much filler is added, the explosion-proof material will easily cause the filler to separate from the resin under high-speed impact, which is manifested by a sharp drop in the strength of the coating film under high-speed impact; although increasing the hard segment content of the resin increases the strength of the material, its hardness is also greatly improved. As a result, the low-temperature flexibility of the material deteriorates, and the material loses the effect of anti-ballistic and explosion-proof in low-temperature environments

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026]An anti-knock composite material modified by hydroxyl and amino groups provided in Example 1 of the present invention includes semi-prepolymer A component and B component, wherein the semi-prepolymer A component includes the following raw materials in mass percentage: poly 40-60% of ether diol or polyester diol, 8-10% of polyisocyanate, 30-35% of hydroxyl-modified nano-carbon and secondary doped polyaniline composite material; component B includes the following raw materials in mass percentage : Amino-terminated polyether or carboxyl-terminated polyether 50-70%, diamine chain extender 10-30%, molecular sieve powder slurry 0.5-1%, color paste 0.5-1%, and amino-modified nano-carbon and intrinsic state polymer Composite material of aniline and secondary doped polyaniline 0.1-0.5%, polyether diol or polyester diol, polyisocyanate exists in semi-prepolymer A component in the form of isocyanate-terminated semi-prepolymer , the nano-carbon and secondary doped polyaniline compos...

Embodiment 2

[0036] Based on the same inventive concept, Embodiment 2 of the present invention provides a method for preparing the above-mentioned hydroxyl and amino modified anti-knock composite material, the method comprising:

[0037] Step 1: Mix the graphene raw material and the mixed acid at a mass percentage of 0.1:100, ultrasonically disperse evenly and stir at 60°C for 6-8 hours, then wash with deionized water until pH = 1, then the molar mass percentage is Add aniline and ammonium persulfate at a ratio of 0.8:1, stir at room temperature for 2 hours, then let stand for 12 hours, then wash with deionized water several times and filter with suction until the filtrate is neutral, and dry the product at 80°C to obtain the target product Composite materials of hydroxyl-modified graphene and primary doped polyaniline.

[0038] Specifically, after adding aniline and ammonium persulfate at a ratio of 0.8:1 according to the molar mass percentage, aniline is polymerized under the action of a...

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PUM

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Abstract

The invention discloses a hydroxyl and amino modified antiknock composite material and a preparation method thereof, and belongs to the technical field of anticorrosion antiknock materials. Amino and hydroxyl are introduced into a composite material formed by nanocarbon and polyaniline, and in the process of introducing the amino and hydroxyl into the composite material formed by the nanocarbon and the polyaniline, secondary doping and dedoping of the polyaniline can be achieved, and then functionalized nanocarbon, a secondarily-doped polyaniline composite material and a polyurea elastomer material are mixed. The nanocarbon and polyaniline composite material is functionalized in advance, and then the functionalized nanocarbon and polyaniline composite material is connected into an antiknock elastomer material in a physical dispersion and chemical reaction combined mode, so that the defect that the material is poor in low-temperature flexibility due to the fact that the hard segment content in a resin system is increased to reinforce the material is overcome. The composite material can be used for improving the gas explosion impact resistance of petrochemical enterprise buildings, and can effectively reduce the explosion impact damage of the petrochemical enterprise buildings.

Description

technical field [0001] The invention relates to the technical field of anti-corrosion and anti-explosion materials, in particular to an anti-explosion composite material modified by hydroxyl and amino groups and a preparation method thereof. Background technique [0002] In recent years, the explosion-proof problem of personnel-concentrated places such as control rooms of petrochemical enterprises has attracted widespread attention. Polyurea elastomer has extremely high adhesion to substrates including metals and non-metals. After proper substrate treatment, it can be well combined with most materials, such as concrete, steel and aluminum, forming a layer and sandwich-like composite structures. [0003] Accidents in chemical companies in recent years have shown that Vapor Cloud Explosion (VCE) accidents caused by equipment leakage are extremely destructive, often causing a large number of casualties in concentrated places near the device. However, only a few of Sinopec's n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/02C08L79/02C08K3/04C08K9/02C08K9/04
CPCC08L75/02C08K2201/011
Inventor 杨小刚王向阳杜传宝
Owner 青岛海弗莱安全科技有限公司
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