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Low-smoke-density flame-retardant PC composition

A technology of smoke density and composition, applied in the field of low smoke density flame retardant PC composition, can solve the problems such as the inability to reflect the performance advantages of PC, the change of material properties, etc. Effect

Pending Publication Date: 2021-04-13
上海品诚控股集团有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The product in the patent CN106589784 is a PC / ABS alloy with low carbon content, but it is only suitable for low-end vehicles and construction fields
The smoke suppressant molybdenum compound in the patent 201210076335, in the pure PC formula, leads to the degradation of pure PC, which is not suitable for the pure PC formula, which leads to the inability to reflect the performance advantages of PC
The low-cost traditional solution in the existing technology is to add PPC, PEI and other high-temperature-resistant, low-smoke raw materials to PC, or add more fillers to dilute the resin, which will cause changes in the properties of the material itself

Method used

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Examples

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Embodiment Construction

[0017] The present invention will be described in detail below in conjunction with specific examples.

[0018] Table 1: Comparative Examples 1-5.

[0019]

[0020] Conclusion 1: It can be seen from Table 1 that the function of PPFBS is to catalyze the isomerization of PC, reduce the potential energy of PC material decomposition, promote carbon formation, and improve the flame retardant efficiency of phosphorus-based flame retardants. DMP-HDP has a high decomposition temperature, and under the same heat flux, it degrades slowly in the PC matrix, which can produce a continuous carbon-forming effect. The addition of too much PPFBS will not reduce the smoke density. The reason is that the P flame retardant is the main material in the material, and the carbonization of PC has reached the limit. Adding too much flame retardant will not reduce the smoke density. lower.

[0021] Table 2: Comparative Examples 6-7.

[0022]

[0023] Conclusion 2: Methyl-phenylsilane can diffuse...

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PUM

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Abstract

The invention discloses a low-smoke-density flame-retardant PC composition. The low-smoke-density flame-retardant PC composition is prepared from the following raw materials in parts by weight: 10 to 85 parts of PC resin, 5 to 50 parts of organic silicon PC, 0.1 to 2 parts of sulfonate flame retardant, 0 to 10 parts of phosphorus flame retardant, 0.3 to 5 parts of organic silicon flame retardant, 2 to 40 parts of reinforced filler and 0.5 to 5 parts of nano material. According to the low-smoke-density flame-retardant PC composition disclosed by the invention, by compounding a flame-retardant system and adding an inorganic nano material, the efficiency of a flame retardant can be improved and the release of combustible gas during degradation of the material is slowed down and reduced by virtue of a relatively large nano specific surface energy, so that smoke formation and combustion of the material are slowed down, and a low-smoke-density flame-retardant effect is achieved while the additive amount of the flame retardant is low; the low-smoke-density flame-retardant PC composition disclosed by the invention can be applied to the fields of rail transit, aerospace, buildings and the like which have strict requirements on the combustion smoke density of materials.

Description

technical field [0001] The invention belongs to the technical field of low-smoke density flame-retardant compositions, and in particular relates to a low-smoke density flame-retardant PC composition. Background technique [0002] PC has high impact strength and is a widely used engineering plastic. PC itself has a high carbon content and is self-extinguishing when the thickness is high. It is widely used in electronic appliances, rail transit, construction, etc. that require flame retardancy. field. The high carbon content of PC will produce more smoke when burning, especially after adding phosphorus flame retardant, at 50kW / m 2 Tested under the heat flux, the degradation or combustion of PC and flame retardants will produce greater smoke density. The disadvantages in the current prior art patents are: SabicUS9266541B2 uses a PC copolymerization scheme, which is expensive and not suitable for common raw material factories, and the material loses the performance of bispheno...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L83/10C08K13/04C08K7/14C08K3/34C08K3/36C08K5/42C08K5/5419C08K5/523
CPCC08L69/00C08K2201/011C08K2201/014C08L2201/02C08L83/10C08K13/04C08K7/14C08K3/34C08K3/36C08K5/42C08K5/5419C08K5/523
Inventor 马海丰陈增军宋治乾陈方
Owner 上海品诚控股集团有限公司
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