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Industrial heat-resistant silane modified polyether sealant and preparation method thereof

A silane-modified polyether and sealant technology, applied in the direction of polyether adhesives, adhesives, adhesive types, etc., can solve problems such as poor heat resistance, ensure heat resistance and paintability, and improve heat resistance. performance and durability, and the effect of meeting the requirements of process adhesive spraying

Pending Publication Date: 2021-04-06
CHENGDU GUIBAO NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides an industrial heat-resistant silane-modified polyether sealant, which solves the problem of poor heat resistance of the silane-modified polyether sealant from the molecular structure

Method used

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  • Industrial heat-resistant silane modified polyether sealant and preparation method thereof
  • Industrial heat-resistant silane modified polyether sealant and preparation method thereof
  • Industrial heat-resistant silane modified polyether sealant and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0043] 85 parts of silane-modified polyether with a number average molecular weight of 14274, 50 parts of polypropylene glycol PPG3000, 10 parts of diisodecyl phthalate, 120 parts of nanometer calcium carbonate, 50 parts of heavy calcium carbonate, 10 parts of kaolin, 6 Part specific surface area is 150m 2 Add / g of fumed white carbon black into the high-speed disperser, stir at a low speed for 20 minutes until uniform, then raise the temperature of the material to 110°C and stir for 2 hours under a vacuum of -0.085MPa to obtain a mixed material; when the temperature of the mixed material is lowered to below 45°C, Add 3 parts of carbon black slurry, 5.5 parts of oligomer vinyltrimethoxysilane, 1.5 parts of benzotriazole UV absorber, 1.5 parts of hindered amine light stabilizer, 3 parts of N-β-(aminoethyl) -γ-Aminopropyltrimethoxysilane, 0.5 part of γ-(2,3-glycidoxy)propyltrimethoxysilane, 0.7 part of dibutyltin dilaurate, stirred at -0.085MPa vacuum for 40min and discharged ,...

Embodiment 2

[0045] 96 parts of silane-modified polyether with a number average molecular weight of 10012, 40 parts of diisononyl phthalate, 100 parts of nano-calcium carbonate, 40 parts of kaolin, 20 parts of silicon micropowder, 5 parts of titanium dioxide, and 2 parts of polyamide Add the wax into the high-speed disperser, stir at a low speed for 20 minutes until uniform, then raise the temperature of the material to 110°C and stir for 2 hours under a vacuum of -0.085MPa to obtain a mixed material; when the temperature of the mixed material is cooled below 45°C, add 6.7 parts of vinyl trimethoxy base silane, 1 part of salicylate UV absorber, 1 part of hindered amine light stabilizer, 4.2 parts of γ-aminopropyl trimethoxysilane, 0.2 part of chelated tin, and stirred for 40 minutes under -0.085MPa vacuum. material, to obtain the industrial heat-resistant silane-modified polyether sealant of the present invention.

Embodiment 3

[0047]98 parts of silane-modified polyether with a number average molecular weight of 23500, 75 parts of polypropylene glycol PPG3000, 128 parts of nano-calcium carbonate, 64 parts of heavy calcium carbonate, and 7 parts with a specific surface area of ​​150m 2 Add / g of fumed white carbon black into the high-speed disperser, stir at a low speed for 20 minutes until uniform, then raise the temperature of the material to 110°C and stir for 2 hours under a vacuum of -0.085MPa to obtain a mixed material; when the temperature of the mixed material is lowered to below 45°C, Add 5 parts of oligomer vinyltrimethoxysilane, 2 parts of benzophenone UV absorber, 2 parts of hindered amine light stabilizer, 3.6 parts of γ-aminopropyl triethoxysilane, 1.8 parts of γ-(2 , 3-glycidoxy)propyltrimethoxysilane and 0.8 parts of stannous octoate were stirred under a vacuum of -0.085 MPa for 40 minutes and then discharged to obtain the industrial heat-resistant silane-modified polyether sealant of t...

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Abstract

The invention discloses an industrial heat-resistant silane modified polyether sealant in the technical field of adhesives. The industrial heat-resistant silane modified polyether sealant is prepared from the following raw materials in parts by weight: 80-100 parts of silane modified polyether, 50-80 parts of a plasticizer, 160-200 parts of a filler, 0.1-10 parts of a thixotropic agent, 1-2 parts of an ultraviolet light absorber, 1-2 parts of a light stabilizer, 4-7 parts of a water remover, 3-6 parts of a coupling agent and 1-2 parts of a catalyst. According to the silane modified polyether sealant, a polysiloxane chain segment is introduced, so that the heat resistance of the sealant can be effectively improved, the finishing property is not influenced, and the silane modified polyether sealant prepared by adopting the formula and the method can be widely applied to the industrial fields of rail transit, automobile manufacturing, containers and the like.

Description

technical field [0001] The invention belongs to the technical field of adhesives, and in particular relates to an industrial heat-resistant silane-modified polyether sealant and a preparation method thereof. Background technique [0002] At present, the three most common sealants on the market are: polysulfide type, silicone type and polyurethane type. Polysulfide type sealants are increasingly being eliminated due to many problems such as slow curing at low temperature and poor durability. The terminal NCO group of polyurethane sealant is sensitive to moisture, and has poor storage stability. At the same time, it is easy to produce pores and slow curing speed; silicone sealant does not have paintability, and the adhesive layer is easy to oil out. Silane-modified polyether sealant, also known as MS glue, can combine the advantages of polyurethane-type and silicone-type sealants, exhibit excellent adhesion and paintability, and exhibit good environmental friendliness; solvent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J183/12C09J171/02C09J11/04C09J11/06C08G77/46
CPCC09J183/12C09J11/04C09J11/06C08G77/46C08L2201/08C08K2201/014C08K2003/265C08K2201/011C08K2003/2241C08L71/02C08K13/04C08K5/12C08K3/26C08K3/346C08K7/26C08K3/04C08K5/5425C08K5/544C08K5/5435C08L77/00C08K13/02C08K3/36C08K3/22
Inventor 王有治罗芳严聪张文焕张明黄强
Owner CHENGDU GUIBAO NEW MATERIAL
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