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Battery separator, preparation method thereof and lithium ion battery

A battery separator and separator technology, used in secondary batteries, battery pack components, circuits, etc., can solve problems such as adverse effects on battery quality, side reactions of chemical components, affecting battery quality, etc., to achieve good safety, reduce The effect of wrinkling and suppressing static electricity

Pending Publication Date: 2020-12-22
ZHUHAI COSMX BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, non-aqueous adhesive-coated separators often produce a large electrostatic effect during use, which not only seriously affects the normal production process when lithium-ion batteries are wound, but also easily absorbs dust and affects battery quality. The main ways to solve the problem are: (1) neutralize the charge by using additional devices (such as ion blower, anti-static bar, etc.) during the lithium-ion battery winding process or introduce the charge into the ground to eliminate static electricity It can only partially or temporarily eliminate the static electricity on the glued partitions. If the partitions are rubbed in the subsequent production process, static electricity will still be generated, and the static electricity cannot be eliminated from the root; (2) Antistatic agents are added to the glued layer Antistatic agents are generally surfactants with both polar and non-polar groups, and their polar hydrophilic groups can absorb a small amount of water on the surface of the separator to achieve the purpose of removing static electricity. However, the antistatic agent The chemical composition is easy to produce side reactions in the internal environment of the battery, and the introduced moisture often reacts with the lithium salt in the electrolyte to produce a large amount of gas, which causes the battery to swell and adversely affects the quality of the battery

Method used

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  • Battery separator, preparation method thereof and lithium ion battery
  • Battery separator, preparation method thereof and lithium ion battery
  • Battery separator, preparation method thereof and lithium ion battery

Examples

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Embodiment 1

[0048] Such as figure 1 As shown, the battery separator provided in this embodiment (hereinafter referred to as the composite porous separator) includes a porous polymer substrate, a ceramic coating (about 2 μm in thickness) coated on one surface of the porous polymer substrate, coated on the porous polymer A conductive coating (about 1 μm in thickness) on the other surface of the substrate and a conductive coating (about 1 μm in thickness) coated on the surface of the ceramic coating; wherein, such as figure 2 with image 3 As shown, the shape of the conductive material in the conductive coating is one-dimensional, so as to build a conductive network; the content of the conductive material in the conductive coating is about 1.34%.

[0049] The battery provided in this example is formed by using the above-mentioned composite porous separator.

[0050] The electrical composite porous separator of this embodiment and the battery formed by using the separator are specifically ...

Embodiment 2

[0065]The difference between the battery separator provided in this example and the battery formed by using the separator and Example 1 is that the addition amount (ie content) of the conductive material in the conductive coating is about 0.89%;

[0066] The difference in the corresponding preparation process is only that: in step 1, the mass ratio of polyvinylidene fluoride to carbon nanotubes is 1:0.0090.

Embodiment 3

[0068] The difference between the battery separator provided in this example and the battery formed using the separator and Example 1 is that the amount of conductive material added in the conductive coating is about 0.45%;

[0069] The difference in the corresponding preparation process is only that: in step 1, the mass ratio of polyvinylidene fluoride to carbon nanotubes is 1:0.0045.

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Abstract

The invention provides a battery separator, a preparation method thereof and a lithium ion battery, the battery separator comprises a separator substrate and a conductive coating coated on at least one surface of the substrate, the raw materials of the conductive coating comprise a binder and a conductive material, and the shape of the conductive material comprises at least one of zero dimension,one dimension and two dimension. The problem of static electricity generated in the use process of the partition plate can be effectively solved, the foreign matter adsorption probability is reduced,and the comprehensive quality of safety, circularity and the like of the battery is improved.

Description

technical field [0001] The invention relates to the field of lithium ion batteries, in particular to a battery separator, a preparation method thereof and a lithium ion battery formed by using the separator. Background technique [0002] Lithium-ion batteries have the characteristics of high energy density, long cycle life, no memory effect, and environmental protection. As energy storage devices, they are widely used in consumer electronics and power tools. As an important component of lithium-ion batteries, the battery separator determines the interface structure and internal resistance of the battery, and directly affects the cycle, capacity and safety of the battery. [0003] At present, lithium-ion batteries mainly use porous polymer substrates as separators (or diaphragms), which are arranged between the positive and negative electrodes. The interface between them is easy to change, so that the gap between the two increases, which leads to problems such as battery cap...

Claims

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Application Information

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IPC IPC(8): H01M2/16H01M2/14H01M2/18H01M10/0525B82Y40/00
CPCB82Y40/00H01M10/0525Y02E60/10
Inventor 苏权飞李素丽徐延铭李俊义
Owner ZHUHAI COSMX BATTERY CO LTD
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