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MOFs mixed matrix filtering material for sewage treatment and preparation method thereof

A filter material and mixed matrix technology, applied in water/sludge/sewage treatment, osmosis/dialysis water/sewage treatment, sustainable biological treatment, etc., can solve the problem that the reverse osmosis treatment unit cannot operate normally and the ultrafiltration membrane is easy to foul Blocking, high investment costs and other problems, to achieve the effect of good effluent water quality, strong pollution holding capacity, and high filtration speed

Active Publication Date: 2020-11-06
鄂尔多斯市清科紫荆技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the advanced treatment of sewage often requires ultra- and microfiltration membrane technology, but the investment cost of this technology is relatively high
For reclaimed water reuse and "zero discharge" treatment, it is necessary to protect the membrane system to reduce fouling of membrane materials. Sand filter + carbon filter + ultrafiltration pretreatment units are often installed at the front end of nanofiltration and reverse osmosis. The process is long, the sand filter and carbon filter are easy to harden and difficult to clean, and the ultrafiltration membrane is easy to be fouled, which directly leads to a series of practical problems such as the failure of the subsequent nanofiltration and reverse osmosis treatment units.

Method used

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  • MOFs mixed matrix filtering material for sewage treatment and preparation method thereof
  • MOFs mixed matrix filtering material for sewage treatment and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Add IRMOF series materials, ZIF series materials, and CPL series materials into modifier acid anhydrides. After the ester bonds in the anhydrides are broken, they react with functional groups in MOFs. After surface modification, they are mixed with polysulfone respectively, and then melt-spun to make a 8-55μm fiber filaments. A MOFs mixed matrix filter material with a ratio of polymer to MOFs material of 98.5:1.5, a pore size of 0.2 μm, a porosity of 70%, and a filter layer thickness of 1100 mm was prepared by fiber filament construction, combination and stacking methods. The filter material is fixedly installed in a filter tank with a diameter of 1400mm to build an efficient integrated water purification equipment. The equipment is used for domestic sewage (turbidity: 35.5NTU; suspended solids: 71.3mg / L; COD Cr : 70.4mg / L; BOD 5 : 25.8mg / L; ammonia nitrogen: 17.2mg / L;) treatment, at room temperature and 0.15MPa operating pressure, the filtration speed is 38.5-39.2m / h...

Embodiment 2

[0032] The IRMOF series materials are added to the modifier acid anhydride. The ester bond in the anhydride is broken and reacts with the functional groups in the MOFs. After surface modification, it is mixed with polysulfone, and then melt-spun to make fibers with a diameter of 8-55 μm. Through the method of fiber filament construction, combination and superposition, the proportions of polymer and MOFs materials are 98:2, 98.5:1.5, 99:1, 99.5:0.5, the pore size is 0.2 μm, and the porosity is 70%. A MOFs mixed matrix filter material with a filter layer thickness of 1100 mm. The filter material is fixedly installed in a filter tank with a diameter of 1400mm to build an efficient integrated water purification equipment. The equipment is used for domestic sewage (turbidity: 35.5NTU; suspended solids: 71.3mg / L; COD Cr : 70.4mg / L; BOD 5 : 25.8mg / L; ammonia nitrogen: 17.2mg / L;) treatment, at room temperature and 0.15MPa operating pressure, the filtration speed is 38.0-39.0m / h, the...

Embodiment 3

[0037] The IRMOF series materials are added to the modifier acid anhydride. The ester bond in the anhydride is broken and reacts with the functional groups in the MOFs. After surface modification, it is mixed with polysulfone, and then melt-spun to make fibers with a diameter of 8-55 μm. Through the fiber filament construction, combination and superposition method, the ratio of polymer to MOFs material is 98.5:1.5, the pore size is 0.1 μm, 0.2 μm, 0.3 μm, the porosity is 70%, and the thickness of the filter layer is 1100mm. MOFs Mixed matrix filter material. The filter material is fixedly installed in a filter tank with a diameter of 1400mm to build an efficient integrated water purification equipment. The equipment is used for coal mine wastewater (turbidity: 61.3NTU; suspended solids: 123.5mg / L; COD Cr : 8.9mg / L; BOD 5 : 4.3mg / L; ammonia nitrogen: 1.7mg / L) treatment, at room temperature and 0.15MPa operating pressure, the filtration speed is 38.2-39.5m / h, the pressure loss...

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Abstract

The invention discloses an MOFs mixed matrix filtering material for sewage treatment and a preparation method thereof, and belongs to the technical field of advanced sewage treatment. The filtering material is composed of fiber yarns made of a polymer material and an MOFs material; the mass fraction of the polymer material is 97% or above, and the MOFs material is 3% or less; the pore diameter ofthe filtering material is 0.04-0.6 [mu]m, and the void ratio range is 45%-75%. The filtering material is fixedly mounted in a filtering tank, and efficient integrated water purifying equipment is built. The equipment is used for treating domestic sewage and industrial wastewater, the turbidity and suspended solids are reduced by 92% or above, the CODCr, BOD5 and ammonia nitrogen contents are reduced by about 23%, the filtering speed is six times that of sand filtration, and the effluent quality is superior to that of a micro-filtration membrane. When the filtering material is applied to the efficient integrated water purification equipment, the equipment has the outstanding advantages of being good in effluent quality, small in occupied area, low in investment cost, low in operation cost and the like, and has wide application prospects.

Description

technical field [0001] The invention belongs to the technical field of advanced sewage treatment, and in particular relates to a MOFs mixed matrix filter material and a preparation method for sewage treatment. Background technique [0002] With the growth of urban population and the development of industrial and agricultural production, the amount of sewage discharge is increasing day by day, and the national environmental protection supervision department has increasingly strict standards for sewage discharge. At present, the advanced treatment of sewage often requires ultra- and microfiltration membrane technology, but the investment cost of this technology is relatively high. For reclaimed water reuse and "zero discharge" treatment, it is necessary to protect the membrane system to reduce fouling of membrane materials. Sand filter + carbon filter + ultrafiltration pretreatment units are often installed at the front end of nanofiltration and reverse osmosis. The process i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/06B01D71/30B01D71/38B01D71/64B01D71/68B01D67/00C02F1/44C02F101/16
CPCB01D71/06B01D71/68B01D71/64B01D71/38B01D71/30C02F1/44B01D67/0002C02F2101/16Y02W10/10
Inventor 李继定易汉平李洋吴珍董布和孙丽娅
Owner 鄂尔多斯市清科紫荆技术开发有限公司
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