Magnetic material and method for producing same
A technology of magnetic materials and manufacturing methods, applied in the direction of magnetic materials, magnetic objects, inorganic materials, etc., can solve the problem of high resistivity
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Embodiment 1 and comparative example 1
[0297] Additionally prepared CoCl 2 ·6H 2 O (cobalt(II) chloride hexahydrate) and FeCl 2 4H 2 O (iron(II) chloride tetrahydrate) aqueous solution, they are mixed, will be adjusted to 50.3mM CoCl 2 and FeCl 2 The mixed aqueous solution is put into the reactor to make the reaction field liquid. In addition, the composition of cobalt contained in the above-mentioned mixed aqueous solution, that is, the composition of feed cobalt was set to 4 atomic %. Then, while vigorously stirring in the atmosphere, 660 mM potassium hydroxide aqueous solution (pH adjustment solution) was added dropwise to adjust the pH of the system in the range of 4.57 to 10.1. solution (the composition of cobalt in the reaction solution (feeding cobalt composition) is 4 atomic %) into the FeCl of 168mM 2 and CoCl 2The mixed aqueous solution was allowed to react for 15 minutes, then the dropping of the pH adjusting solution and the reaction solution was stopped, and the stirring operation was continued ...
Embodiment 2~10、 comparative example 5~13
[0314] In addition to changing the feed Co composition to 1 atomic % (Comparative Example 5), 2 atomic % (Comparative Example 6), 8 atomic % (Comparative Example 7), 10 atomic % (Comparative Example 8), 15 atomic % (Comparative Example 9), 20 atomic % (Comparative Example 10), 33 atomic % (Comparative Example 11), 50 atomic % (Comparative Example 12) and 75 atomic % (Comparative Example 13), prepared by the same method as Comparative Example 1 Ferrite nano powder. The nanopowder was analyzed by X-ray diffraction method. As a result, it can be seen that the cubic Co-ferrite phase is the main phase, and the rhombohedral Co-hematite phase is contained as an impurity phase. Therefore, the ccs-(Fe, Co) phase was not contained in this powder, and it was used as the powder of Comparative Examples 5-13, and the magnetic characteristics etc. are shown in Table 1. The feed amounts of these are consistent with the Co content obtained by XRF to the % point.
[0315] These ferrite nanopo...
Embodiment 11
[0320] Additional preparation of MnCl 2 4H 2 O (manganese(II) chloride tetrahydrate), CoCl 2 ·6H 2 O (cobalt(II) chloride hexahydrate) and FeCl 2 4H 2 O (iron(II) chloride tetrahydrate) aqueous solution, they are mixed, will be adjusted to 50.3mM MnCl 2 、CoCl 2 and FeCl 2 The mixed aqueous solution was put into the reactor to make the reaction field liquid. It should be noted that the compositions of cobalt and manganese contained in the above-mentioned mixed aqueous solution, that is, the feed cobalt composition and the feed manganese composition were set to be 4 atomic % and 0.1 atomic %, respectively. Then, while vigorously stirring in the atmosphere, 660 mM potassium hydroxide aqueous solution (pH adjustment solution) was added dropwise, and the pH of the adjustment system was slowly shifted from the acid side to the alkaline side in the range of 4.69 or more and 9.32 or less. 168mM FeCl was added dropwise 2 and CoCl 2 The mixed aqueous solution of the above was ...
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