A kind of ultra-hydrophobic ultraviolet curing coating and preparation method thereof

A technology for curing coatings and ultraviolet light, applied in the field of coatings, can solve the problems of inability to meet the requirements of super-hydrophobicity and low water contact angle, and achieve the effect of increasing hydrophobicity and improving hydrophobicity.

Active Publication Date: 2022-02-18
矽时代材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the self-cleaning and anti-fouling functions of UV light-curing coatings, the more commonly used method is to introduce low surface tension silicon or fluorine structures into the molecular structure, but the coatings obtained by this method have low water contact angles and cannot meet superhydrophobic requirements

Method used

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  • A kind of ultra-hydrophobic ultraviolet curing coating and preparation method thereof
  • A kind of ultra-hydrophobic ultraviolet curing coating and preparation method thereof
  • A kind of ultra-hydrophobic ultraviolet curing coating and preparation method thereof

Examples

Experimental program
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Embodiment 1

[0039] An embodiment of the UV-curable coating of the present invention, the UV-curable coating in this embodiment comprises the following components in parts by weight: 15 parts of fluorine-containing acrylate polymer, 40 parts of photo-curable resin, acrylate reactive monomer 37 parts of body, 0.7 parts of leveling agent, 0.8 parts of coupling agent, 5 parts of photoinitiator and 1.5 parts of lotus leaf powder;

[0040] Wherein, the photocurable resin is polyurethane acrylate; the acrylate active monomer is composed of the following components by weight: 20 parts of isobornyl acrylate, 15 parts of isooctyl acrylate and 1,6-hexanediol diol 2 parts of acrylate; the leveling agent is an acrylate leveling agent; the coupling agent is a KH550 coupling agent; the photoinitiator is composed of the following components by weight: 2-phenylbenzyl-2 - 1 part of dimethylamine-1-(4-morpholinebenzylphenyl) butanone and 4 parts of 1-hydroxy-cyclohexyl-phenylmethanone.

[0041] The prepara...

Embodiment 2

[0053] An embodiment of the UV-curable coating of the present invention, the UV-curable coating in this embodiment comprises the following components in parts by weight: 10 parts of fluorine-containing acrylate polymer, 45 parts of photo-curable resin, acrylate reactive monomer 36 parts of body, 0.5 parts of leveling agent, 1.5 parts of coupling agent, 6.5 parts of photoinitiator and 2.5 parts of lotus leaf powder;

[0054] Wherein, the photocurable resin is composed of the following components by weight: 20 parts of polyurethane acrylate and 25 parts of epoxy acrylate; the acrylate reactive monomer is composed of the following components by weight: 2-phenoxy 22 parts of ethyl acrylate, 6 parts of cyclotrimethylolpropane methylal acrylate and 8 parts of isooctyl acrylate; the leveling agent is a silicone leveling agent with a primary hydroxyl group; the coupling agent It is a KH560 coupling agent; the photoinitiator consists of the following components by weight: 3.5 parts of ...

Embodiment 3

[0057] An embodiment of the UV-curable coating of the present invention, the UV-curable coating in this embodiment comprises the following components in parts by weight: 10 parts of fluorine-containing acrylate polymer, 35 parts of photo-curable resin, acrylate reactive monomer 35 parts of body, 1 part of leveling agent, 5 parts of coupling agent, 6 parts of photoinitiator and 8 parts of lotus leaf powder;

[0058] Wherein, the photocurable resin is polyester acrylate; the acrylate active monomer is hydroxyethyl acrylate; the leveling agent is a vinyl group-containing silicone leveling agent; the coupling agent is KH570 coupling agent; the photoinitiator consists of the following components by weight: 2 parts of 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, 2-hydroxyl-2-methyl-1 -2 parts of phenyl-1-propanone and 2 parts of phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide.

[0059] The preparation method of the fluorine-containing acrylate polymer and the preparation method...

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Abstract

The invention discloses an ultraviolet curable coating, which comprises the following components in parts by weight: 10-20 parts of fluorine-containing acrylate polymer, 30-45 parts of photocurable resin, 30-40 parts of acrylate active monomer, photoinitiator 3-10 parts of agent, 0.5-5 parts of coupling agent, 0.3-1 part of leveling agent and 0.5-8 parts of lotus leaf powder. Lotus leaf powder is added to the UV-curable coating of the present invention, and the super hydrophobicity of lotus leaf powder is utilized, combined with fluorine-containing acrylate polymer and photocurable resin, the hydrophobicity of the coating can be increased, and the cured coating can be made The water contact angle is greater than 150.0°, forming a "lotus leaf effect", forming a superhydrophobic coating, improving the hydrophobicity and anti-fouling ability of the cured coating, and avoiding the colloid caused by adding too much fluorine or silicon to the coating. Problems with opacity and poor strength. The invention also discloses a preparation method of the ultraviolet curing paint.

Description

technical field [0001] The invention relates to a coating, in particular to a superhydrophobic ultraviolet-curable coating and a preparation method thereof. Background technique [0002] Superhydrophobic coatings refer to coatings with a contact angle of water droplets greater than 150.0° on the surface, which is related to the chemical composition and microscopic geometry of the solid surface. For the self-cleaning and anti-fouling functions of UV light-curing coatings, the more commonly used method is to introduce low surface tension silicon or fluorine structures into the molecular structure, but the coatings obtained by this method have low water contact angles and cannot meet the requirements of superhydrophobicity. Contents of the invention [0003] The object of the present invention is to overcome the deficiencies in the prior art and provide a super-hydrophobic, ultraviolet fast curing (water drop angle > 150.0°) coating and a preparation method thereof. [0...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/14C09D163/10C09D167/06C09D5/16C08G18/50C08G18/67
CPCC09D175/14C09D163/10C09D167/06C09D5/1681C09D5/1687C08G18/5015C08G18/672C08L2205/025C08L2205/03C08L2205/035
Inventor 黄山柯松柯明新
Owner 矽时代材料科技股份有限公司
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