Strip-shaped electrode used for cylindrical jelly roll and lithium secondary battery comprising same
A lithium secondary battery, cylindrical technology, applied in the field of lithium secondary batteries, can solve problems such as electrode coating cracking, and achieve the effect of excellent adhesion and excellent conductivity
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Embodiment 1
[0088] Preparation of slurry for the first positive electrode active material layer
[0089] Preparation of LiNi as the cathode active material at a weight ratio of 94:3:2.7 0.6 co 0.2 mn 0.2 (LG Chem, HN601A), carbon black (Denka, SB50L) as a conductive material, PVDF (Kureha, KF7200) as a polymer binder. PVDF was dissolved in N-methylpyrrolidone as a solvent to form a binder solution, and active material particles and conductive materials were introduced into this binder solution, and then dispersed at 3,000 rpm in a commercially available homogenizer 50 minutes to obtain the first slurry for positive electrode material.
[0090] Preparation of the slurry for the second positive electrode active material layer
[0091] Preparation of LiNi as the cathode active material at a weight ratio of 96:3:0.3 0.6 co 0.2 mn 0.2 (LG Chem, HN601A), carbon black (Denka, SB50L) as a conductive material, PVDF (Kureha, KF7200) as a polymer binder. PVDF was dissolved in N-methylpyr...
Embodiment 2
[0095] Obtain the positive pole in the same manner as in Example 1, except that the positive electrode active material is used: conductive material: the weight ratio of the binder is 94.75:3:2.25 to prepare the first positive electrode slurry of Example 1, And use positive electrode active material: conductive material: the composition that the weight ratio of binder is 96.25:3:0.75 prepares the second positive electrode slurry, makes the binder contained in the first positive electrode active material layer and is contained in the second The weight ratio of the binder in the positive electrode active material layer became 75:25 (weight basis).
Embodiment 3
[0097] Obtain the positive electrode in the same manner as in Example 1, except that the first positive electrode slurry of Example 1 is prepared using a positive electrode active material: a conductive material: a weight ratio of 96.2:3:1.8 of the binder, And use positive electrode active material: conductive material: the composition that the weight ratio of binding agent is 95.8:3:1.2 prepares the second positive electrode slurry, makes the binding agent contained in the first positive electrode active material layer and is contained in the second The weight ratio of the binder in the positive electrode active material layer became 60:40 (weight basis).
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