Formula and preparation method of all-steel tire carcass

A tire and carcass technology, applied in the field of all-steel tire carcass formulation and its preparation, can solve the problems of low Green strength, affect product safety performance, and cannot improve the dynamic fatigue performance of rubber-coated steel wires, and achieves improved dynamic fatigue performance, The effect of reducing the symptoms of leaky tires and improving driving safety performance

Inactive Publication Date: 2019-08-23
JIANGSU GENERAL SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current carcass formula has two defects: one is the poor dynamic fatigue performance caused by the high modulus, and the other is the stretching deformation caused by the low Green strength during the tire building process, and there is a phenomenon of thread leakage in the tire, which affects the safety performance of the product.
There are two solutions, one is to increase the green strength by increasing the carbon black filling, and at the same time cause the heat generation of the formula to increase, and the effect is limited
The other is pre-vulcanization technology, which improves the strength of the rubber compound through radiation pre-vulcanization. This technology requires high cost through equipment modification, and it is in the initial stage of the experiment, and it cannot improve the dynamic fatigue performance of the rubber-coated steel wire.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] All-steel tire carcass formula, each component includes by weight: 70 parts of natural rubber, 30 parts of trans-isoprene-butadiene copolymer, 55 parts of carbon black N375, 0.5 parts of cobalt decanoate, ZnO 4 parts, 1 part of anti-aging agent RD, 1 part of anti-aging agent 4020, 3 parts of insoluble sulfur, 1 part of accelerator DZ, 0.5 part of anti-scorch agent CTP.

[0020] The preparation method of above-mentioned all-steel tire carcass formula comprises the following steps,

[0021] (1) Master refining:

[0022] a. One-stage masterbatch mixing: 70 parts of natural rubber, 30 parts of trans-isoprene-butadiene copolymer, 45 parts of carbon black N375, 0.5 parts of cobalt caprate, and 4 parts of ZnO were sequentially mixed in mass fraction , 1 part of anti-aging agent RD and 1 part of anti-aging agent 4020 were added to the internal mixer, the filling factor was kept at 70%, the rotation speed was 50 rpm, and the rubber was removed at 150-160 °C, and the mixing time...

Embodiment 2

[0026] The all-steel tire carcass formula, each component includes by weight parts: 80 parts of natural rubber, 20 parts of trans isoprene-butadiene copolymer, 60 parts of carbon black N330, 1.5 parts of cobalt boroacylate, 4.5 parts of ZnO, 1 part of anti-aging agent RD, 2 parts of anti-aging agent 4020, 4 parts of insoluble sulfur, 1 part of accelerator CZ, 0.3 part of anti-scorch agent CTP.

[0027] The preparation method of above-mentioned all-steel tire carcass formula comprises the following steps,

[0028] (1) Master refining:

[0029] a. One-stage masterbatch mixing: by mass fraction, 80 parts of natural rubber, 20 parts of trans-isoprene-butadiene copolymer, 40 parts of carbon black N330, 1.5 parts of cobalt boroacylate, and 4.5 parts of ZnO , 1 part of anti-aging agent RD and 2 parts of anti-aging agent 4020 were added to the internal mixer, the filling factor was kept at 75%, the rotation speed was 20 rpm, and the rubber was removed at 150-160 °C, and the mixing ti...

Embodiment 3

[0033] All-steel tire carcass formula, each component includes by weight parts: 95 parts of natural rubber, 5 parts of trans-isoprene-butadiene copolymer, 25 parts of carbon black N375, 25 parts of carbon black N330, decane 0.5 parts of cobalt acid, 0.5 parts of cobalt boroacylate, 5 parts of ZnO, 1.5 parts of anti-aging agent RD, 1.5 parts of anti-aging agent 4020, 2 parts of insoluble sulfur, 1 part of accelerator NS, and 0.2 parts of anti-scorch agent CTP.

[0034] The preparation method of above-mentioned all-steel tire carcass formula comprises the following steps,

[0035] (1) Master refining:

[0036] a. One-stage masterbatch mixing: by mass fraction, 95 parts of natural rubber, 5 parts of trans isoprene-butadiene copolymer, 20 parts of carbon black N375, 20 parts of carbon black N330, cobalt caprate Add 0.5 parts, 0.5 parts of cobalt boroacylate, 5 parts of ZnO, 1.5 parts of anti-aging agent RD, and 1.5 parts of anti-aging agent 4020 into the internal mixer, keep the ...

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Abstract

The invention belongs to the technical field of tire formulas, and concretely relates to a formula and a preparation method of an all-steel tire carcass. The formula comprises, by mass, 70-95 parts ofnatural rubber, 5-30 parts of a trans-isoprene-butadiene copolymer, 50-60 parts of carbon black, 0.5-1.5 parts of a cobalt salt, 4-5 parts of ZnO, 0-2 parts of stearic acid, 2-3 parts of an antioxidant, 2-4 parts of insoluble sulfur, 1-2 parts of a promoter and 0.2-0.5 part of an anti-scorching agent CTP. The invention can improve the dynamic fatigue performance of the carcass formula and prolongthe service life of tires, and the high modulus caused by crystallization of the formula at normal temperature can effectively reduce exposed cords in tire cavities, caused by stretching during tiremolding, and improves the qualified rate of the product.

Description

technical field [0001] The invention belongs to the technical field of tire formulas, in particular to an all-steel tire carcass formula and a preparation method thereof. Background technique [0002] When truck and bus tires are running, the dynamic frequency is close to 10Hz, and the periodic compression deformation and high load capacity require the carcass to have excellent fatigue resistance. On the one hand, the tire carcass transmits the axle load to the crown through the rim, which plays the role of bearing, buffering and transmitting stress; on the other hand, it protects the tire from external impact damage. The surface of all-steel tire carcass steel wire is usually plated with copper and zinc, which can be combined with rubber through an adhesive system. The formula of carcass rubber requires good adhesion to steel wire, low heat generation, high modulus and fatigue performance. The current carcass formula has two defects: one is the poor dynamic fatigue perfor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08L9/00C08K13/02C08K3/04C08K3/22C08K5/09C08K3/06B60C1/00
CPCB60C1/0041C08K2003/2296C08L7/00C08L9/00C08K13/02C08K3/04C08K3/22C08K5/09C08K3/06
Inventor 赵江华
Owner JIANGSU GENERAL SCI TECH
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