Uniform doping method of SiC single crystal metal impurity
A technology of uniform doping of metal impurities, applied in the direction of single crystal growth, single crystal growth, chemical instruments and methods, etc., can solve the problem of uneven release process, achieve high repeatability and low equipment requirements
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Embodiment 1
[0035] A method for uniformly doping SiC single crystal metal impurities includes the following steps:
[0036] (1) The high-purity SiC powder and the material to be doped are uniformly mixed, the mixing method includes ball milling or stirring, and the solid solubility of the material to be doped in SiC is used as the maximum doping measurement value of the material to be doped; The material to be doped is one or more of metal, oxide, carbide or silicide, so as to avoid introducing other impurities.
[0037] (2) After mixing, fill the mixed powder with a high purity sealed graphite crucible, and put it in a heating device with a temperature of up to 2000°, and place it in a constant temperature zone; after the heating device is closed, the growth is removed after repeated pumping The residual air in the cavity, especially the nitrogen and oxygen in the air, is fed with inert gas such as argon as the background gas, and the pressure is maintained at normal pressure. Then the tempe...
Embodiment 2
[0041] A method for uniformly doping SiC single crystal metal impurities. The steps are as described in Embodiment 1, except that in step (2), after argon gas is introduced, the temperature is raised to 2500° C. for 48 hours.
Embodiment 3
[0043] A method for uniformly doping SiC single crystal metal impurities. The steps are as described in Example 1, except that in step (2), the temperature is kept for 48 hours after the temperature is raised and then the temperature is lowered to room temperature, and the temperature is lowered at a rate of 50°C / min.
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